33 research outputs found
Influence of Charge Order on the Ground States of TMTTF Molecular Salts
(TMTTF)2AsF6 and (TMTTF)2SbF6 are both known to undergo a charge ordering
phase transition, though their ground states are different. The ground state of
the first is Spin-Peierls, and the second is an antiferromagnet. We study the
effect of pressure on the ground states and the charge-ordering using 13C NMR
spectroscopy. The experiments demonstrate that the the CO and SP order
parameters are repulsive, and consequently the AF state is stabilized when the
CO order parameter is large, as it is for (TMTTF)2SbF6. An extension of the
well-known temperature/pressure phase diagram is proposed.Comment: 5pages, 5 figures, Proceeding of ISCOM2003, to appear in Journal de
Physique I
NMR evidence for very slow carrier density fluctuations in the organic metal (TMTSF)ClO
We have investigated the origin of the large increase in spin-echo decay
rates for the Se nuclear spins at temperatures near to in the
organic superconductor (TMTSF)ClO. The measured angular dependence of
demonstrates that the source of the spin-echo decays lies with
carrier density fluctuations rather than fluctuations in TMTSF molecular
orientation. The very long time scales are directly associated with the
dynamics of the anion ordering occurring at , and the inhomogeneously
broadened spectra at lower temperatures result from finite domain sizes. Our
results are similar to observations of line-broadening effects associated with
charge-ordering transitions in quasi-two dimensional organic conductors.Comment: 5 pages, 4 figure
Electron-lattice coupling and the broken symmetries of the molecular salt (TMTTF)SbF
(TMTTF)SbF is known to undergo a charge ordering (CO) phase
transition at and another transition to an
antiferromagnetic (AF) state at . Applied pressure causes a
decrease in both and . When , the CO is largely
supressed, and there is no remaining signature of AF order. Instead, the ground
state is a singlet. In addition to establishing an expanded, general phase
diagram for the physics of TMTTF salts, we establish the role of
electron-lattice coupling in determining how the system evolves with pressure.Comment: 4 pages, 5 figure
Competition and coexistence of bond and charge orders in (TMTTF)2AsF6
(TMTTF)2AsF6 undergoes two phase transitions upon cooling from 300 K. At
Tco=103 K a charge-ordering (CO) occurs, and at Tsp(B=9 T)=11 K the material
undergoes a spin-Peierls (SP) transition. Within the intermediate, CO phase,
the charge disproportionation ratio is found to be at least 3:1 from carbon-13
NMR 1/T1 measurements on spin-labeled samples. Above Tsp, up to about 3Tsp,
1/T1 is independent of temperature, indicative of low-dimensional magnetic
correlations. With the application of about 0.15 GPa pressure, Tsp increases
substantially, while Tco is rapidly suppressed, demonstrating that the two
orders are competing. The experiments are compared to results obtained from
calculations on the 1D extended Peierls-Hubbard model.Comment: 4 pages, 5 figure
Phase Inhomogeneity of the Itinerant Ferromagnet MnSi at High Pressures
The pressure induced quantum phase transition of the weakly itinerant
ferromagnet MnSi is studied using zero-field NMR spectroscopy and
relaxation. Below , the intensity of the signal and the
nuclear spin-lattice relaxation is independent of pressure, even though the
amplitude of the magnetization drops by 20% from the ambient pressure
amplitude. For , the decreasing intensity within the experimentally
detectable bandwidth signals the onset of an inhomogeneous phase that persists
to the highest pressure measured, , which is well beyond the
known critical pressure . Implications for the non-Fermi Liquid
behavior observed for are discussed.Comment: 4 pages, 4 figure
Inhomogeneous electronic structure probed by spin-echo experiments in the electron doped high-Tc superconductor Pr_{1.85}Ce_{0.15}CuO_{4-y}
63Cu nuclear magnetic resonance (NMR) spin-echo decay rate (T_2^{-1})
measurements are reported for the normal and superconducting states of a single
crystal of Pr_{1.85}Ce_{0.15}CuO_{4-y} (PCCO) in a magnetic field B_0=9T over
the temperature range 2K<T<200K. The spin-echo decay rate is
temperature-dependent for T<55K, and has a substantial dependence on the radio
frequency (rf) pulse parameters below T~25K. This dependence indicates that
T_2^{-1} is strongly effected by a local magnetic field distribution that can
be modified by the rf pulses, including ones that are not at the nuclear Larmor
frequency. The low-temperature results are consistent with the formation of a
static inhomogeneous electronic structure that couples to the rf fields of the
pulses.Comment: 4 pages, 4 figure
Competition of Dimerization and Charge Ordering in the Spin-Peierls State of Organic Conductors
The effect of the charge ordering on the spin-Peierls (SP) state has been
examined by using a Peierls-Hubbard model at quarter-filling with dimerization,
on-site and nearest-neighbor repulsive interactions. By taking account of the
presence of dimerization, a bond distortion is calculated variationally with
the renormalization group method based on bosonization. When the charge
ordering appears at V=V_c with increasing the nearest-neighbor interaction (V),
the distortion exhibits a maximum due to competition between the dimerization
and the charge ordering. It is shown that the second-order phase transition
occurs from the SP state with the bond alternation to a mixed state with an
additional component of the site alternationat V = V_c.Comment: 11 pages, 13 figures, to be published in J. Phys. Soc. Jpn. 72 No.6
(2003
Finite-Temperature Phase Diagram of Quasi-One-Dimensional Molecular Conductors: Quantum Monte Carlo Study
Finite-temperature phase transitions in quasi-one-dimensional quarter-filled
systems are investigated by the extended Hubbard model with electron-lattice
coupling. Using a quantum Monte Carlo method combined with the inter-chain
mean-field approximation, we clarify competing and coexisting behaviors among
charge ordering, dimer Mott, and spin-Peierls states. It is pointed out that an
anharmonicity of lattice distortions plays an important role in multi-critical
behaviors. The results are compared with experimental data for
quasi-one-dimensional molecular conductors such as DCNQI and TMTTF compounds.Comment: Corrected typo