180 research outputs found
Ni3TeO6 - a collinear antiferromagnet with ferromagnetic honeycomb planes
We report a comprehensive study of magnetic properties of Ni3TeO6. The system
crystallizes in a noncentrosymmetric rhombohedral lattice, space group R3.
There are three differently coordinated Ni atoms in the unit cell. Two of them
form an almost planar honeycomb lattice, while the third one is placed between
the layers. Magnetization and specific heat measurements revealed a single
magnetic ordering at TN = 52 K. Below TN the susceptibility with the magnetic
field parallel to the c-axis drops towards zero while the perpendicular
susceptibility remains constant, a characteristic of antiferromagnetic
materials. Neutron diffraction confirmed that the system is antiferromagnet
below TN with ferromagnetic ab-planes stacked antiferromagnetically along the
c-axis. All Ni moments are in the S = 1 spin state and point along the c-axis.Comment: accepted for publication in Journal of Physics Condensed Matte
Incommensurate magnetic ordering in Cu2Te2O5X2 (X=Cl, Br) studied by single crystal neutron diffraction
Polarized and unpolarized neutron diffraction studies have been carried out
on single crystals of the coupled spin tetrahedra systems Cu2Te2O5X2 (X=Cl,
Br). A model of the magnetic structure associated with the propagation vectors
k'Cl ~ -0.150,0.422,1/2 and k'Br ~ -0.172,0.356,1/2 and stable below TN=18 K
for X=Cl and TN=11 K for X=Br is proposed. A feature of the model, common to
both the bromide and chloride, is a canted coplanar motif for the 4 Cu2+ spins
on each tetrahedron which rotates on a helix from cell to cell following the
propagation vector. The Cu2+magnetic moment determined for X=Br, 0.395(5)muB,
is significantly less than for X=Cl, 0.88(1)muB at 2K. The magnetic structure
of the chloride associated with the wave-vector k' differs from that determined
previously for the wave vector k~0.150,0.422,1/2 [O. Zaharko et.al. Phys. Rev.
Lett. 93, 217206 (2004)]
Evolution of magnetic states in frustrated diamond lattice antiferromagnetic Co(Al1-xCox)2O4 spinels
Using neutron powder diffraction and Monte-Carlo simulations we show that a
spin-liquid regime emerges at $all compositions in the diamond-lattice
antiferromagnets Co(Al1-xCox)2O4. This spin-liquid regime induced by
frustration due to the second-neighbour exchange coupling J2, is gradually
superseded by antiferromagnetic collinear long-range order (k=0) at low
temperatures. Upon substitution of Al3+ by Co3+ in the octahedral B-site the
temperature range occupied by the spin-liquid regime narrows and TN increases.
To explain the experimental observations we considered magnetic anisotropy D or
third-neighbour exchange coupling J3 as degeneracy-breaking perturbations. We
conclude that Co(Al1-xCox)2O4 is below the theoretical critical point
J2/J1=1/8, and that magnetic anisotropy assists in selecting a collinear
long-range ordered ground state, which becomes more stable with increasing x
due to a higher efficiency of O-Co3+-O as an interaction path compared to
O-Al3+-O
Incommensurate magnetic ordering in (X=Cl,Br) studied by neutron diffraction
We present the results of the first neutron powder and single crystal
diffraction studies of the coupled spin tetrahedra systems {\CuTeX} (X=Cl,
Br). Incommensurate antiferromagnetic order with the propagation vectors
{\bf{k}_{Cl}}\approx[0.150,0.422,\half],
{\bf{k}_{Br}}\approx[0.158,0.354,\half] sets in below =18 K for X=Cl
and 11 K for X=Br. No simple collinear antiferromagnetic or ferromagnetic
arrangements of moments within Cu tetrahedra fit these observations.
Fitting the diffraction data to more complex but physically reasonable models
with multiple helices leads to a moment of 0.67(1)/Cu at 1.5 K
for the Cl-compound. The reason for such a complex ground state may be
geometrical frustration of the spins due to the intra- and inter-tetrahedral
couplings having similar strengths. The magnetic moment in the Br- compound,
calculated assuming it has the same magnetic structure as the Cl compound, is
only 0.51(5)/Cu at 1.5 K. In neither compound has any evidence
for a structural transition accompanying the magnetic ordering been found
Spin-stripe phase in a frustrated zigzag spin-1/2 chain
Motifs of periodic modulations are encountered in a variety of natural
systems, where at least two rival states are present. In strongly correlated
electron systems such behaviour has typically been associated with competition
between short- and long-range interactions, e.g., between exchange and
dipole-dipole interactions in the case of ferromagnetic thin films. Here we
show that spin-stripe textures may develop also in antiferromagnets, where
long-range dipole-dipole magnetic interactions are absent. A comprehensive
analysis of magnetic susceptibility, high-field magnetization, specific heat,
and neutron diffraction measurements unveils -TeVO as a nearly
perfect realization of a frustrated (zigzag) ferromagnetic spin-1/2 chain.
Strikingly, a narrow spin stripe phase develops at elevated magnetic fields due
to weak frustrated short-range interchain exchange interactions possibly
assisted by the symmetry allowed electric polarization. This concept provides
an alternative route for the stripe formation in strongly correlated electron
systems and may help understanding other widespread, yet still elusive,
stripe-related phenomena.Comment: accapted in Nature Communication
Persistent spin dynamics intrinsic to amplitude-modulated long-range magnetic order
An incommensurate elliptical helical magnetic structure in the frustrated
coupled-spin-chain system FeTe2O5Br is surprisingly found to persist down to
53(3) mK (T/T_N ~ 1/200), according to neutron scattering and muon spin
relaxation. In this state, finite spin fluctuations at T -> 0 are evidenced by
muon depolarization, which is in agreement with specific-heat data indicating
the presence of both gapless and gapped excitations. We thus show that the
amplitude-modulated magnetic order intrinsically accommodates contradictory
persistent spin dynamics and long-range order and can serve as a model
structure to investigate their coexistence.Comment: 5 pages + supplementar
Evolution of magnetic and crystal structures in the multiferroic FeTe2O5Br
Neutron diffraction and nuclear quadrupole resonance (NQR) measurements were
employed to investigate magnetic order in the non-ferroelectric phase preceding
the low-temperature multiferroic state in FeTe2O5Br. Refnement of the neutron
diffraction data and simulations of 79,81Br NQR spectra reveal that the
incommensurate magnetic ordering in the non-ferroelectric state comprises
amplitude-modulated magnetic moments, similarly as in the multiferroic state.
The two ordered states differ in the orientation of the magnetic moments and
phase shifts between modulation waves. Surprisingly, all symmetry restrictions
for the electric polarization are absent in both states. The different
ferroelectric responses of the two states are thus argued to arise from the
differences in the phase shifts between certain modulation waves, which cancel
out in the non-ferrolectric state.Comment: 9 pages, 8 figures including appendix, published in PR
Anomalous Magnetic Excitations of Cooperative Tetrahedral Spin Clusters
An inelastic neutron scattering study of Cu2Te2O5X2 (X=Cl, Br) shows strong dispersive modes with large energy gaps persisting far above T-N, notably in Cu2Te2O5Br2. The anomalous features: a coexisting unusually weak Goldstone-like mode observed in Cu2Te2O5Cl2 and the size of the energy gaps cannot be explained by existing theories, such as our mean-field or random-phase approximation. We argue that our findings represent a new general type of behavior due to intercluster quantum fluctuations and call for development of a new theoretical approach
Magnetic phase diagram of the quantum spin chain compound SrCoVO: a single-crystal neutron diffraction study in magnetic field
We explore the spin states in the quantum spin chain compound
SrCoVO up to 14.9 T and down to 50 mK, using single-crystal
neutron diffraction. Upon cooling in zero-field, antiferromagnetic (AFM) order
of N\'eel type develops at 5.0 K. Applying an
external magnetic field ( -axis) destabilizes the N\'eel
order, leading to an order-disorder transition when applying a field between
and 1.5 K. Below 1.5 K, we observe a N\'eel to
longitudinal spin density wave (LSDW) order transition at 3.9 T, and a LSDW to
emergent AFM order transition at 7.0 T. Our results also reveal several unique
signatures for the states of the spins that are not present in the
isostructural counterpart BaCoVO.Comment: 9 pages, 9 figures. Accepted manuscrip
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