39 research outputs found

    S, N co-doped carbon nanotube-encapsulated core-shelled CoS2@Co nanoparticles: efficient and stable bifunctional catalysts for overall water splitting

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    Hydrogen, serving as a clean, sustainable energy source, may be mainly produced from electrolysis water. Herein, we report cobalt disulphide encapsulated in self-catalyzed carbon nanotubes (S, N-CNTs/CoS2@Co) serving as a bifunctional catalyst, which exhibits excellent hydrogen evolution reaction performance (10.0 mA cm−2 at 0.112 V, and low Tafel slope for 104.9 mV dec−1) and oxygen evolution reaction performance (10.0 mA cm−2 at 1.57 V, and low Tafel slope for 76.1 mV dec−1), meanwhile with a strong stability at various current densities. In-depth study reveals that the excellent catalytic properties can be mainly attributed to the increased catalytic sites induced by S, N co-doping, the improved electronic conductivity derived from the carbon nanotubes, and Mott-Schottky effect between the metal cobalt and semiconductive cobalt disulfide. Notably, when the bifunctional catalysts are applied to overall water splitting, a low potential of 1.633 V at the current density of 10.0 mA cm−2 is achieved, which can compete with the precious metal catalyst benchmarks in alkaline media, demonstrating its promising practicability in the realistic water splitting application. This work elucidates a practicable way to the design of transition metal and nano-carbon composite catalysts for a broad application in the fields of energy chemistry.Jing-Yu Wang, Ting Ouyang, Nan Li, Tianyi Ma, Zhao-Qing Li

    PSB 2019 Workshop on Text Mining and Visualization for Precision Medicine

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    Precision medicine, an approach for disease treatment and prevention that considers "individual variability in genes, environment, and lifestyle"(1) was endorsed by the National Institutes of Health, aided by the presidential Precision Medicine Initiative (PMI), in 2016. PMI provided funding for cancer research and for building a national cohort of one million or more U.S. participants, now known as the "All of Us" Research Program, which aims to expand its impact to all diseases. PMI was the catalyst to a widespread effort around precision medicine, as evidenced by the more than 1000 grants funded by different NIH institutes in just the last two years. The data being generated by these efforts is growing exponentially, and becomes both the greatest treasure and the greatest challenge for researchers. This workshop is a continuation of a similar session in PSB 2018, providing a forum for researchers with strong background in text mining or natural language processing (NLP) and/or machine learning (ML) who are actively collaborating with bench scientists and clinicians to tackle the challenges brought about by this explosion of data

    Measurement of the absolute branching fraction for Λc+→Λμ+νμ

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    We report the first measurement of the absolute branching fraction for Λc+→Λμ+νμ. This measurement is based on a sample of e+e− annihilation data produced at a center-of-mass energy s=4.6 GeV, collected with the BESIII detector at the BEPCII storage rings. The sample corresponds to an integrated luminosity of 567 pb−1. The branching fraction is determined to be B(Λc+→Λμ+νμ)=(3.49±0.46(stat)±0.27(syst))%. In addition, we calculate the ratio B(Λc+→Λμ+νμ)/B(Λc+→Λe+νe) to be 0.96±0.16(stat)±0.04(syst)
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