Hertz-to-terahertz dielectric response of nanoconfined water molecules

Broad-band dielectric spectroscopy, heat capacity measurements and molecular dynamic simulations are applied to study excitations of interacting electric dipoles spatially arranged in a network with an inter-dipole distance of 5-10 A. The dipoles with magnitude of 1.85 Debye are represented by single H2O molecules located in voids (0.5 nm size) formed by ions of the crystal lattice of cordierite. We discover emergence of nontrivial disordered paraelectric phase of dipolar system with signs of phase transition below 3 K.Comment: 3 pages, 4 figure

Evidence of electronic phase separation in the strongly correlated semiconductor YbB12

The studies of high-quality single-domain crystals of YbB12 were carried out by the precise x-ray diffraction technique in combination with the low temperature polarized THz - infrared spectroscopy and accurate magnetotransport measurements. It has been shown for the first time that this archetypal strongly correlated system with a metal-insulator transition to a mysterious dielectric ground state with a metal Fermi surface (Science 362, 65-69 (2018) and ibid 362, 32-33 (2018)) is actually a heterogeneous compound in the regime of electronic phase separation. Changes in the configuration of the discovered dynamic charge stripes are investigated upon cooling, as a result, a conclusion is drawn in favor of a crossover between different patterns of the filamentary electronic structure penetrating the semiconducting matrix of YbB12. We argue that the discovery of stripes in YbB12 is fundamental, elucidating the nature of exotic dielectric state in Kondo insulators.Comment: 12 pages including 4 figure

Dielectric ordering of water molecules arranged in a dipolar lattice

Despite the apparent simplicity of a H2O molecule, the mutual ferroelectric ordering of the molecules is unresolved. Here, the authors realize a macroscopic ferroelectric phase transition in a network of dipole-dipole coupled water molecules located in nanopores of gemstone

High Quality Graphene Using Boudouard Reaction

Following the game changing high pressure CO HiPco process that established the first facile route toward large scale production of single walled carbon nanotubes, CO synthesis of cm sized graphene crystals of ultra high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO CO2 mixture and maintains a high growth rate of graphene seeds reaching large scale monocrystals. Unique features of the Boudouard reaction coupled with CO driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene catalyst composite productio

The emerging landscape of single-molecule protein sequencing technologies

Single-cell profiling methods have had a profound impact on the understanding of cellular heterogeneity. While genomes and transcriptomes can be explored at the single-cell level, single-cell profiling of proteomes is not yet established. Here we describe new single-molecule protein sequencing and identification technologies alongside innovations in mass spectrometry that will eventually enable broad sequence coverage in single-cell profiling. These technologies will in turn facilitate biological discovery and open new avenues for ultrasensitive disease diagnostics.This Perspective describes new single-molecule protein sequencing and identification technologies alongside innovations in mass spectrometry that will eventually enable broad sequence coverage in single-cell proteomics