721 research outputs found

    A Priori truth in the natural world : a non-referentialist response to Benacerraf's dilemma

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    The main question that I address in my thesis is how we can best conceive the contrast between a priori and empirical truths. My response is realist and naturalist in character: I suggest that the essential feature of a priori truths is that they consist in the obtaining of some realistically understood conditions in the domain of representations within human heads, rather than in the obtaining of those conditions that they typically purport to be about. This representationist constual cannot be reconciled with the received referentialist understanding of truth. Accordingly, my thesis can be seen as a case against standard referentialism about truth. After a detailed exposition and appropriate generalisation of Benacerraf__s dilemma about mathematical truth, I argue for two major claims. First, I demonstrate that among the most striking characteristics of our paradigm a priori beliefs about causally inert entities there are some, which cannot be suitably explained from a referentialist perspective, so that perspective must be wrong. Second, I argue that if we adopt an alternative, use-theoretic notion of truth, then the suggested representationist construal of apriority can meet all major explanatory adequacy conditions, and thus qualifies as a viable characterisation of the subject.LEI Universiteit LeidenCentral European University, University of LeidenPhilosoph

    The 'one-pot' preparation of substituted benzofurans

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    A simple one-pot procedure has been elaborated for the preparation of substituted benzofurans starting from halogenated phenols, and this method has been applied successfully to the total synthesis of dehydrotremetone, a natural product of White Snakeroot

    Diffusion of Mn interstitials in (Ga,Mn)As epitaxial layers

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    Magnetic properties of thin (Ga,Mn)As layers improve during annealing by out-diffusion of interstitial Mn ions to a free surface. Out-diffused Mn atoms participate in the growth of a Mn-rich surface layer and a saturation of this layer causes an inhibition of the out-diffusion. We combine high-resolution x-ray diffraction with x-ray absorption spectroscopy and a numerical solution of the diffusion problem for the study of the out-diffusion of Mn interstitials during a sequence of annealing steps. Our data demonstrate that the out-diffusion of the interstitials is substantially affected by the internal electric field caused by an inhomogeneous distribution of charges in the (Ga,Mn)As layer.Comment: 11 pages, 5 figure

    Mn incorporation in as-grown and annealed (Ga,Mn)As layers studied by x-ray diffraction and standing-wave uorescence

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    A combination of high-resolution x-ray diffraction and a new technique of x-ray standing wave uorescence at grazing incidence is employed to study the structure of (Ga,Mn)As diluted magnetic semiconductor and its changes during post-growth annealing steps. We find that the film is formed by a uniform, single crystallographic phase epilayer covered by a thin surface layer with enhanced Mn concentration due to Mn atoms at random non-crystallographic positions. In the epilayer, Mn incorporated at interstitial position has a dominant effect on lattice expansion as compared to substitutional Mn. The expansion coeffcient of interstitial Mn estimated from our data is consistent with theory predictions. The concentration of interstitial Mn and the corresponding lattice expansion of the epilayer are reduced by annealing, accompanied by an increase of the density of randomly distributed Mn atoms in the disordered surface layer. Substitutional Mn atoms remain stable during the low-temperature annealing.Comment: 9 pages, 9 figure

    Reliability of Human Subject - Artificial System Interactions

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    Main problems related to reliability of interaction between human subject and artificial system (namely of the transportation character) are discussed. The paper consists of three mayor parts:The first one is devoted to the theoretical backgrounds of the problem from the both theory of system reliability and neurology/psychology views.Second part presents the discussion of relevant methodologies of the classification and prediction of the reliability decline. The methodology based on EEG pattern analysis is chosen as the appropriate one for the presented task. The key phenomenon of "micro-sleep" is discussed in detail.The last part presents some latest experimental results in context of presented knowledge. Proposals for the future studies are presented at the end of the presented article. The special interest should be devoted to the analysis and in-time prediction of fatal attention decreases and to the design and construction of the respective on-board applicable warning system

    Data Acquisition and Management in the Calibration Processes of the CMS Barrel Muon Alignment System

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    In order to be able to match correctly the track elements produced by a muon in the Tracker and the Muon System of the CMS experiment [1] the mutual alignment precision between the Tracker and the Barrel Muon System must be no worse than 100-400 micrometers depending on the radial distance of the muon chambers from the Tracker. To fulfill this requirement an alignment system had to be designed. This system contains subsystems for determining the positions of the barrel and endcap chambers while a third one connects these two to the Tracker. Since the Barrel muon chambers are embedded into the magnet yoke of the experiment a nonconventional alignment method had to be developed. In this paper we restrict ourselves to the Barrel Alignment System and the calibration methods of its components

    Investigation of magnetic anisotropy and heat dissipation in thin films of compensated antiferromagnet CuMnAs by pump–probe experiment

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    We recently reported on a method to determine the easy axis position in a 10 nm thick film of the fully compensated antiferromagnet CuMnAs. The film had a uniaxial magnetic anisotropy and the technique utilized a magneto-optical pump and probe experiment [Saidl et al. Nat. Photonics 11, 91 (2017)]. In this contribution, we discuss the applicability of this method for the investigation of a broader set of epitaxial CuMnAs films having different thicknesses. This work reveals that the equilibrium magnetic anisotropy can be studied only in samples, where this anisotropy is rather strong. However, in the majority of CuMnAs films, the impact of a strong pump pulse induces nano-fragmentation of the magnetic domains and, therefore, the magnetic anisotropy measured by the pump–probe technique differs substantially from that in the equilibrium conditions. We also demonstrate that the optical pump–probe experiment can be used very efficiently to study the local heating and heat dissipation in CuMnAs epitaxial layers. In particular, we determined the electron–phonon relaxation time in CuMnAs. We also observed that, for a local film heating by a focused laser, the thinner films are heated more, but the heat is dissipated considerably faster than in the case of thicker films. This illustrates that the optical pump–probe experiment is a valuable characterization tool for the heat management optimization in the CuMnAs memory devices and can be applied in a similar way to those used during the heat-assisted magnetic recording technology development for the latest generation of hard drive disks

    Efficient direct 2,2,2-trifluoroethylation of indoles via C-H functionalization

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    A novel highly C3 selective metal free trifluoroethylation of indoles using 2,2,2-trifuoroethyl(mesityl)-iodonium triflate was developed. The methodology enables the introduction of a trifluoroethyl group in a fast and efficient reaction under mild conditions with high functional group tolerance. Beyond the synthetic developments, quantum chemical calculations provide a deeper understanding of the transformation. This journal i
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