Direct Measure of Giant Magnetocaloric Entropy Contributions in Ni-Mn-In

Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe calorimetric and magnetic studies of four compositions. The results provide a direct measure of entropy changes contributions including at the first-order phase transitions, and thereby a determination of the maximum field-induced entropy change corresponding to the giant magnetocaloric effect. We find a large excess entropy change, attributed to magneto-elastic coupling, but only in compositions with no ferromagnetic order in the high-temperature austenite phase. Furthermore, a molecular field model corresponding to antiferromagnetism of the low-temperature phases is in good agreement, and nearly independent of composition, despite significant differences in overall magnetic response of these materials

A Pairwise Dataset for GUI Conversion and Retrieval between Android Phones and Tablets

With the popularity of smartphones and tablets, users have become accustomed to using different devices for different tasks, such as using their phones to play games and tablets to watch movies. To conquer the market, one app is often available on both smartphones and tablets. However, although one app has similar graphic user interfaces (GUIs) and functionalities on phone and tablet, current app developers typically start from scratch when developing a tablet-compatible version of their app, which drives up development costs and wastes existing design resources. Researchers are attempting to employ deep learning in automated GUIs development to enhance developers' productivity. Deep learning models rely heavily on high-quality datasets. There are currently several publicly accessible GUI page datasets for phones, but none for pairwise GUIs between phones and tablets. This poses a significant barrier to the employment of deep learning in automated GUI development. In this paper, we collect and make public the Papt dataset, which is a pairwise dataset for GUI conversion and retrieval between Android phones and tablets. The dataset contains 10,035 phone-tablet GUI page pairs from 5,593 phone-tablet app pairs. We illustrate the approaches of collecting pairwise data and statistical analysis of this dataset. We also illustrate the advantages of our dataset compared to other current datasets. Through preliminary experiments on this dataset, we analyse the present challenges of utilising deep learning in automated GUI development and find that our dataset can assist the application of some deep learning models to tasks involving automatic GUI development.Comment: 10 pages, 9 figure

Calorimetric and magnetic study for Ni50_{50}Mn36_{36}In14_{14} and relative cooling power in paramagnetic inverse magnetocaloric systems

The non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{36}$In$_{14}$ undergoes a martensitic phase transformation in the vicinity of 345 K, with the high temperature austenite phase exhibiting paramagnetic rather than ferromagnetic behavior, as shown in similar alloys with lower-temperature transformations. Suitably prepared samples are shown to exhibit a sharp transformation, a relatively small thermal hysteresis, and a large field-induced entropy change. We analyzed the magnetocaloric behavior both through magnetization and direct field-dependent calorimetry measurements. For measurements passing through the first-order transformation, an improved method for heat-pulse relaxation calorimetry was designed. The results provide a firm basis for the analytic evaluation of field-induced entropy changes in related materials. An analysis of the relative cooling power (RCP), based on the integrated field-induced entropy change and magnetizing behavior of the Mn spin system with ferromagnetic correlations, shows that a significant RCP may be obtained in these materials by tuning the magnetic and structural transformation temperatures through minor compositional changes or local order changes

Red teaming ChatGPT via Jailbreaking: Bias, Robustness, Reliability and Toxicity

Recent breakthroughs in natural language processing (NLP) have permitted the synthesis and comprehension of coherent text in an open-ended way, therefore translating the theoretical algorithms into practical applications. The large language models (LLMs) have significantly impacted businesses such as report summarization software and copywriters. Observations indicate, however, that LLMs may exhibit social prejudice and toxicity, posing ethical and societal dangers of consequences resulting from irresponsibility. Large-scale benchmarks for accountable LLMs should consequently be developed. Although several empirical investigations reveal the existence of a few ethical difficulties in advanced LLMs, there is little systematic examination and user study of the risks and harmful behaviors of current LLM usage. To further educate future efforts on constructing ethical LLMs responsibly, we perform a qualitative research method called ``red teaming'' on OpenAI's ChatGPT\footnote{In this paper, ChatGPT refers to the version released on Dec 15th.} to better understand the practical features of ethical dangers in recent LLMs. We analyze ChatGPT comprehensively from four perspectives: 1) \textit{Bias} 2) \textit{Reliability} 3) \textit{Robustness} 4) \textit{Toxicity}. In accordance with our stated viewpoints, we empirically benchmark ChatGPT on multiple sample datasets. We find that a significant number of ethical risks cannot be addressed by existing benchmarks, and hence illustrate them via additional case studies. In addition, we examine the implications of our findings on AI ethics and harmal behaviors of ChatGPT, as well as future problems and practical design considerations for responsible LLMs. We believe that our findings may give light on future efforts to determine and mitigate the ethical hazards posed by machines in LLM applications.Comment: Technical Repor

PHRIT: Parametric Hand Representation with Implicit Template

We propose PHRIT, a novel approach for parametric hand mesh modeling with an implicit template that combines the advantages of both parametric meshes and implicit representations. Our method represents deformable hand shapes using signed distance fields (SDFs) with part-based shape priors, utilizing a deformation field to execute the deformation. The model offers efficient high-fidelity hand reconstruction by deforming the canonical template at infinite resolution. Additionally, it is fully differentiable and can be easily used in hand modeling since it can be driven by the skeleton and shape latent codes. We evaluate PHRIT on multiple downstream tasks, including skeleton-driven hand reconstruction, shapes from point clouds, and single-view 3D reconstruction, demonstrating that our approach achieves realistic and immersive hand modeling with state-of-the-art performance.Comment: Accepted by ICCV202

SSR-2D: Semantic 3D Scene Reconstruction from 2D Images

Most deep learning approaches to comprehensive semantic modeling of 3D indoor spaces require costly dense annotations in the 3D domain. In this work, we explore a central 3D scene modeling task, namely, semantic scene reconstruction without using any 3D annotations. The key idea of our approach is to design a trainable model that employs both incomplete 3D reconstructions and their corresponding source RGB-D images, fusing cross-domain features into volumetric embeddings to predict complete 3D geometry, color, and semantics with only 2D labeling which can be either manual or machine-generated. Our key technical innovation is to leverage differentiable rendering of color and semantics to bridge 2D observations and unknown 3D space, using the observed RGB images and 2D semantics as supervision, respectively. We additionally develop a learning pipeline and corresponding method to enable learning from imperfect predicted 2D labels, which could be additionally acquired by synthesizing in an augmented set of virtual training views complementing the original real captures, enabling more efficient self-supervision loop for semantics. In this work, we propose an end-to-end trainable solution jointly addressing geometry completion, colorization, and semantic mapping from limited RGB-D images, without relying on any 3D ground-truth information. Our method achieves state-of-the-art performance of semantic scene reconstruction on two large-scale benchmark datasets MatterPort3D and ScanNet, surpasses baselines even with costly 3D annotations. To our knowledge, our method is also the first 2D-driven method addressing completion and semantic segmentation of real-world 3D scans

A femtosecond time resolved view of vibrationally assisted electron transfer across the metal/aqueous interface

Understanding heterogeneous charge transfer is crucial if we are to build the best electrolyzers, fuel cells and photoelectrochemical water splitting devices that chemistry allows. Because the elementary processes involved have timescales ranging from femto- to milliseconds, direct simulation is not generally possible. Model Hamiltonian approaches thus have a crucial role in gaining mechanistic insight. Current generations of such theories describe a reactant(s) or product(s) that interacts with electrolyte via a single effective interaction. Such approaches thus obscure the extent to which particular solvent fluctuations influence charge transfer. Here we demonstrate experimentally that for a prototypical system, a ferrocene terminated alkane thiol self-assembled monolayer (SAM) on gold in contact with aqueous electrolyte, charge transfer from the Au to the ferrocene can be induced by vibrational excitation of the ferrocene aromatic CH. Intriguingly the energy of the aromatic CH vibration, 0.38 eV, is a large fraction of the effective solvent interaction strength inferred for the ferrocene/ferrocenium system in prior electrochemical studies: 0.85 eV. Our results thus demonstrate the coupling of charge transfer to a specific solvent motion and more generally imply that solvent may affect reduction/oxidation rates in electrocatalysis by coupling to a few distinct solvent motions. Identifying these motions is crucial in rationalizing trends in reactivity with change in electrolyte and thus in pursuing electrolyte engineering from first principles.Comment: 18 pages, 6 figure