Thermoelectric response across the semiconductor-semimetal transition in black phosphorus

In spite of intensive studies on thermoelectricity in metals, little is known about thermoelectric response in semiconductors at low temperature. An even more fascinating and unanswered question is what happens to the Seebeck coefficient when the semiconductor turns to a metal. By precisely tuning the ground state of black phosphorus with pressure from the semiconducting to semimetallic state, we track a systematic evolution of the Seebeck coefficient. Thanks to a manifest correlation between the Seebeck coefficient and resistivity, the Seebeck response in each conduction regime, i.e., intrinsic, saturation, extrinsic, and variable range hopping (VRH) regimes, is identified. In the former two regimes, the Seebeck coefficient behaves in accordance with the present theories, whereas in the later two regimes available theories do not give a satisfactory account for its response. However, by eliminating the extrinsic sample dependence in the resistivity $\rho$ and Seebeck coefficient $S$, the Peltier conductivity $\alpha=S/\rho$ allows to unveil the intrinsic thermoelectric response, revealing vanishing fate for $\alpha$ in the VRH regime. The emerged ionized impurity scattering on entry to the semimetallic state is easily surpassed by electron-electron scattering due to squeezing of screening length accompanied by an increase of carrier density with pressure. In the low temperature limit, a small number of carriers enhances a prefactor of $T$-linear Seebeck coefficient as large as what is observed in prototypical semimetals. A crucial but largely ignored role of carrier scattering in determining the magnitude and sign of the Seebeck coefficient is indicated by the observation that a sign reversal of the $T$-linear prefactor is concomitant with a change in dominant scattering mechanism for carriers.Comment: 13 pages, 16 figure

Characterization of β-N-acetylhexosaminidase (LeHex20A), a member of glycoside hydrolase family 20, from Lentinula edodes shiitake mushroom)

We purified and cloned a β-N-acetylhexosaminidase, LeHex20A, with a molecular mass of 79 kDa from the fruiting body of Lentinula edodes (shiitake mushroom). The gene lehex20a gene had 1,659 nucleotides, encoding 553 amino acid residues. Sequence analysis indicated that LeHex20A belongs to glycoside hydrolase (GH) family 20, and homologues of lehex20a are broadly represented in the genomes of basidiomycetes. Purified LeHex20A hydrolyzed the terminal monosaccharide residues of β-N-acetylgalactosaminides and β-N-acetylglucosaminides, indicating that LeHex20A is a β-N-acetylhexosaminidase classified into EC 3.2.1.52. The maximum LeHex20A activity was observed at pH 4.0 and 50°C. The kinetic constants were estimated using chitooligosaccharides with degree of polymerization 2-6. GH20 β-N-acetylhexosaminidases generally prefer chitobiose among natural substrates. However, LeHex20A had the highest catalytic efficiency (k(cat)/K(m)) for chitotetraose, and the K(m) values for GlcNAc(6) were 3.9-fold lower than for chitobiose. Furthermore, the enzyme partially hydrolyzed amorphous chitin polymers. These results indicate that LeHex20A can produce N-acetylglucosamine from long-chain chitomaterials

The Stellar Mass, Star Formation Rate and Dark Matter Halo Properties of LAEs at z∼2z\sim2

We present average stellar population properties and dark matter halo masses of $z \sim 2$ \lya emitters (LAEs) from SED fitting and clustering analysis, respectively, using $\simeq$ $1250$ objects ($NB387\le25.5$) in four separate fields of $\simeq 1$ deg$^2$ in total. With an average stellar mass of $10.2\, \pm\, 1.8\times 10^8\ {\mathrm M_\odot}$ and star formation rate of $3.4\, \pm\, 0.4\ {\mathrm M_\odot}\ {\rm yr^{-1}}$, the LAEs lie on an extrapolation of the star-formation main sequence (MS) to low stellar mass. Their effective dark matter halo mass is estimated to be $4.0_{-2.9}^{+5.1} \times 10^{10}\ {\mathrm M_\odot}$with an effective bias of$1.22^{+0.16}_{-0.18}$which is lower than that of$z \sim 2$LAEs ($1.8\, \pm\, 0.3$), obtained by a previous study based on a three times smaller survey area, with a probability of$96\%. However, the difference in the bias values can be explained if cosmic variance is taken into account. If such a low halo mass implies a low HI gas mass, this result appears to be consistent with the observations of a high \lya escape fraction. With the low halo masses and ongoing star formation, our LAEs have a relatively high stellar-to-halo mass ratio (SHMR) and a high efficiency of converting baryons into stars. The extended Press-Schechter formalism predicts that at z=0$our LAEs are typically embedded in halos with masses similar to that of the Large Magellanic Cloud (LMC); they will also have similar SHMRs to the LMC, if their SFRs are largely suppressed after$z \sim 2$ as some previous studies have reported for the LMC itself.Comment: 34 pages, 15 figures, 6 tables. Accepted for publication in PAS

Extremely Stochastic Connectivity of Island Mangroves

Studies of mangrove population connectivity have focused primarily on global to regional scales and have suggested potential for long-distance connectivity, with archipelagos serving as stepping stones for trans-oceanic dispersal. However, the contribution of propagule dispersal to connectivity is still largely unknown, especially at local-scale. Identifying fine-scale propagule dispersal patterns unique to individual island systems is important to understand their contribution to global species distributions, and to select appropriate sizes and locations for mangrove conservation in archipelagos. Using population genetic methods and a release-recapture method employing GPS drifting buoys, we investigated the spatiotemporal scale of propagule dispersal of Rhizophora stylosa, one of the widely distributed mangrove species in the Indo-West Pacific. This study sought to quantify intra- and inter-island connectivity and to assess their contributions to oceanic scale dispersal of R. stylosa from the Ryukyu Archipelago, which spans over 545 km in southwestern Japan. Using 7 microsatellite markers, we tested 354 samples collected from 16 fringing populations on 4 islands. We identified 3 genetic populations, indicating distinct genetic structures comprising 3 distinguishable bioregions (genetic clusters). The western end of the archipelago receives relatively frequent migration (m > 0.1), but is genetically isolated from other sites. Based on genetic migration rates, we found that the central area of the archipelago serves as a stepping stone for southwestward, but not northeastward dispersal. On the other hand, with in-situ drifting buoys, we did not confirm prevailing dispersal directionality within the archipelago, instead confirming local eddies. Some buoys trapped in those eddies demonstrated potential for successful beaching from another island. A large portion of buoys were carried predominantly northeastward by the Kuroshio Current and drifted away from the coastal areas into the Pacific, contrary to local migrations. We found that the spatiotemporal scale of propagule dispersal is limited by the distance between islands (< 200km), propagule viability duration, and fecundity. Over all, recruitment does not occur frequently enough to unify the genetic structure in the archipelago, and the Ryukyu Archipelago is isolated in the center of the global mangrove distribution