36 research outputs found
pH-Responsively Water-Retaining Controlled-Release Fertilizer Using Humic Acid Hydrogel and Nano-Silica Aqueous Dispersion
Dispersion Characteristics and Applications of Higher Order Isosceles Triangular Meshes in the Finite Element Method
Mesh division plays an important role in applications of the finite element method (FEM). The proposed research shows that under the same order, the equilateral triangular meshes have the most uniform dispersion distribution. The isosceles triangles with equal base and height have more uniform dispersion error than the square meshes, while the maximum phase error is similar. Taking the rectangular waveguide as an example, the relative errors in the cut-off frequency are analyzed based on different meshes. The numerical results show that under the same interpolation order and node numbers, the relative error of isosceles triangles with equal base and height for TE10 mode is the smallest. The results are useful in choosing appropriate element order, node density and mesh shape when applying FEM.This article is published as Niu, Yuhua, Jinbo Liu, Wen Luo, Zengrui Li, and Jiming Song. "Dispersion Characteristics and Applications of Higher Order Isosceles Triangular Meshes in the Finite Element Method." IEEE Open Journal of Antennas and Propagation 4 (2023): 1171-1175. doi: https://doi.org/10.1109/OJAP.2023.3331217. Copyright 2023 The Authors. This is open access article licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License (https://creativecommons.org/licenses/by-nc-nd/4.0/)
Fabrication of Bifunctional TiO2/POM Microspheres Using a Layer-by-Layer Method and Photocatalytic Activity for Methyl Orange Degradation
Bifunctional films of Keggin-type polyoxometalates H3PW12O40 (PW12), H4SiW12O40 (SiW12), H3PMo12O40 (PMo12), and TiO2 were successfully built on Fe3O4@SiO2 microspheres using a layer-by-layer method. The characterization by field emission scan electronic microscopy (FESEM) and energy dispersive X-ray spectroscopy (EDX) shows that TiO2 nanoparticles and polyoxometalate (POM) anions are successfully assembled. The photodegradation of methyl orange (MO) was used to test the photocatalytic efficiency of magnetic catalysts under UV irradiation. For MO decomposition, multilayer films that combine PW12 and SiW12 with TiO2 show high efficiency, which can be attributed to the synergistic effect between POMs and TiO2. The degradation of the model contaminant was also systematically checked under different conditions such as bilayer number deposited on magnetic microspheres, catalyst concentration, inorganic oxidants, and salts. The oxidation process of MO follows an apparent first-order reaction. Furthermore, the composite catalysts deposited on Fe3O4@SiO2 magnetic microspheres can be conveniently, quickly, and efficiently separated by an external magnet from a solution
Remediation of Cd and Cu Contaminated Agricultural Soils near Oilfields by Biochar Combined with Sodium Humate-Wood Vinegar
Soil contaminations by heavy metals near oilfields have been widely reported and are causing great concern. Thus, it is highly desirable to develop cost-effective materials and methods to avoid heavy metal residues contaminating soil and food. An effective, environmentally friendly, and inexpensive remediation material for heavy metal-polluted soil was designed and prepared using biochar (BC) combined with humic acid (HA) resulting from sodium humate (NaHA) simply reacting with wood vinegar (BHW). After adding BHW, the chemical fractions of copper and cadmium in the soil undergo larger changes. Meanwhile, the availability of heavy metals decreases. The maximum adsorption capacity of copper and cadmium in the soil using the BHW is larger than that only using biochar. The adsorption kinetics ensures that the adsorption process of Cd2+ and Cu2+ ions on BHW is chemical adsorption, which is best fitted using the pseudo-second-order rate equation. The thermodynamics guarantees that the metal ions adsorb on the heterogeneous surface of BHW in multilayer, which is credited to the enhancement of oxygen-containing groups in the biochar combined with the humic acid. The remediation material BHW holds promise for the immobilization of heavy metal in the soils and could be recommended based on its economic feasibility, high efficacy, and environmental safety
Immobilization properties and adsorption mechanism of nickel(II) in soil by biochar combined with humic acid-wood vinegar
Biochar (BC) combined with humic acid (HA) and wood vinegar (WV) was designed and prepared as an inexpensive, effective, and environmentally friendly immobilization material (BHW) for metal-polluted soil. The influences of the wood vinegar and humic acid on the immobilization properties and adsorption mechanism of this new material were also investigated. The remediation performance was evaluated using a laboratory-made, nickel-contaminated soil with a Ni2+ concentration of 200 mg per kg surface soil (top 20 cm from agricultural land). The results indicated that the immobilization ratio sequence of nickel (II) in the soil was BC< BH< BHW. The maximum adsorption capacity increased in the same order: BC< BH< BHW. All three adsorption isotherms were better fitted by the Freundlich model, which were consistent with the surface heterogeneity of the remediation materials. The cause of this surface heterogeneous migration may be due to the increase in oxygen-containing groups in the BC introduced by the HA and WV. The WV can increase the number of the oxygen-containing groups in the BC combined with HA, which enhanced the adsorption and immobilization of Ni2+ ions. The results suggested that BHW is recommended for the remediation of metal-contaminated soils, because of its high efficacy, economic feasibility, environmental and food safety
Sliding and Fretting Wear Behavior of Biomedical Ultrafine-Grained TiNbZrTaFe/Si Alloys in Simulated Physiological Solution
This work investigated the wear behavior of ultrafine-grained Ti65Nb23.33Zr5Ta1.67Fe5 (at.%, TNZTF) and Ti65Nb23.33Zr5Ta1.67Si5 (at.%, TNZTS) alloys fabricated by high-energy ball milling and spark plasma sintering. Wear tests were conducted in a simulated physiological solution under both reciprocating sliding and fretting wear conditions with different loads, frequencies, and stroke lengths. The microstructures, mechanical properties, and anti-wear properties of the investigated alloys were characterized. The results showed that the TNZTF and TNZTS alloys had much less wear volume than the commonly used Ti-6Al-4V (TC4) alloy and commercially pure titanium (CP-Ti). The TNZTF and TNZTS alloys exhibited much more smooth wear surfaces and shallower wear scars compared with TC4 and CP-Ti. The investigated alloys exhibited different wear mechanisms under the reciprocating sliding wear conditions, while they were similar under the fretting wear conditions. Compared with TC4 and CP-Ti, the fabricated TNZTF and TNZTS alloys showed a substantially higher wear resistance, owing to their ultrafine-grained microstructure and superior hardness. Additionally, the addition of Nb and Zr further enhanced the wear resistance by forming a protective Nb2O5 and ZrO2 oxide film. This work provides guidance for designing new biomedical titanium alloys with excellent wear resistance
Improvement of color purity in blue-emitting polyfluorene by copolymerization with dibenzothiophene
SOX2 Reprograms Resident Astrocytes into Neural Progenitors in the Adult Brain
Glial cells can be in vivo reprogrammed into functional neurons in the adult CNS; however, the process by which this reprogramming occurs is unclear. Here, we show that a distinct cellular sequence is involved in SOX2-driven in situ conversion of adult astrocytes to neurons. This includes ASCL1+ neural progenitors and DCX+ adult neuroblasts (iANBs) as intermediates. Importantly, ASCL1 is required, but not sufficient, for the robust generation of iANBs in the adult striatum. These progenitor-derived iANBs predominantly give rise to calretinin+ interneurons when supplied with neurotrophic factors or the small-molecule valproic acid. Patch-clamp recordings from the induced neurons reveal subtype heterogeneity, though all are functionally mature, fire repetitive action potentials, and receive synaptic inputs. Together, these results show that SOX2-mediated in vivo reprogramming of astrocytes to neurons passes through proliferative intermediate progenitors, which may be exploited for regenerative medicine