766 research outputs found
Gas-induced segregation in Pt-Rh alloy nanoparticles observed by in-situ Bragg coherent diffraction imaging
Bimetallic catalysts can undergo segregation or redistribution of the metals
driven by oxidizing and reducing environments. Bragg coherent diffraction
imaging (BCDI) was used to relate displacement fields to compositional
distributions in crystalline Pt-Rh alloy nanoparticles. 3D images of internal
composition showed that the radial distribution of compositions reverses
partially between the surface shell and the core when gas flow changes between
O2 and H2. Our observation suggests that the elemental segregation of
nanoparticle catalysts should be highly active during heterogeneous catalysis
and can be a controlling factor in synthesis of electrocatalysts. In addition,
our study exemplifies applications of BCDI for in situ 3D imaging of internal
equilibrium compositions in other bimetallic alloy nanoparticles
Osmotically Delaminated Silicate Nanosheet-Coated NCM for Ultra-Stable Li⁺ Storage and Chemical Stability Toward Long-Term Air Exposure
Melting of two dimensional solids on disordered substrate
We study 2D solids with weak substrate disorder, using Coulomb gas
renormalisation. The melting transition is found to be replaced by a sharp
crossover between a high liquid with thermally induced dislocations, and a
low glassy regime with disorder induced dislocations at scales larger than
which we compute (, the Larkin and
translational correlation lengths). We discuss experimental consequences,
reminiscent of melting, such as size effects in vortex flow and AC response in
superconducting films.Comment: 4 pages, uses RevTeX, Amssymb, multicol,eps
Crystallization of a classical two-dimensional electron system: Positional and orientational orders
Crystallization of a classical two-dimensional one-component plasma
(electrons interacting with the Coulomb repulsion in a uniform neutralizing
positive background) is investigated with a molecular dynamics simulation. The
positional and the orientational correlation functions are calculated for the
first time. We have found an indication that the solid phase has a
quasi-long-range (power-law) positional order along with a long-range
orientational order. This indicates that, although the long-range Coulomb
interaction is outside the scope of Mermin's theorem, the absence of ordinary
crystalline order at finite temperatures applies to the electron system as
well. The `hexatic' phase, which is predicted between the liquid and the solid
phases by the Kosterlitz-Thouless-Halperin-Nelson-Young theory, is also
discussed.Comment: 3 pages, 4 figures; Corrected typos; Double columne
Floating Hem-o-Lok Clips in the Bladder without Stone Formation after Robot-Assisted Laparoscopic Radical Prostatectomy
Hem-o-Lok clips (Weck Surgical Instruments, Teleflex Medical, Durham, NC, USA) are widely used in robot-assisted laparoscopic radical prostatectomy because of their easy application and secure clamping. To date, there have been some reports of intravesical migration of these clips causing urethral erosion, bladder neck contractures, and subsequent calculus formation. We report the first case of bladder migration of Hem-o-Lok clips without stone formation after robot-assisted laparoscopic radical prostatectomy. The Hem-o-Lok clips were found during urethral dilation with a guide wire for bladder neck contracture under cystourethroscopy. The Hem-o-Lok clips were floating in the bladder without stone formation and were removed by a cystoscopic procedure
Melting of the classical bilayer Wigner crystal: influence of the lattice symmetry
The melting transition of the five different lattices of a bilayer crystal is
studied using the Monte-Carlo technique. We found the surprising result that
the square lattice has a substantial larger melting temperature as compared to
the other lattice structures, which is a consequence of the specific topology
of the temperature induced defects. A new melting criterion is formulated which
we show to be universal for bilayers as well as for single layer crystals.Comment: 4 pages, 5 figures (postscript files). Accepted in Physical Review
Letter
- …