Spectral Line Survey toward Spiral Arm of M51 in the 3 mm and 2 mm Bands

We have conducted a spectral line survey in the 3 mm and 2 mm bands toward two positions in a spiral arm of M51 (NGC 5194) with the IRAM 30 m telescope. In this survey, we have identified 13 molecular species, including CN, CCH, N2H+, HNCO, and CH3OH. Furthermore, 6 isotopologues of the major species have been detected. On the other hand, SiO, HC3N, CH3CN, and the deuterated species such as DCN and DCO+ are not detected. The deuterium fractionation ratios are evaluated to be less than 0.8 % and 1.2 % for DCN/HCN and DCO+/HCO+, respectively. By comparing the results of the two positions with different star formation activities, we have found that the observed chemical compositions do not strongly depend on star formation activities. They seem to reflect a chemical composition averaged over the 1-kpc scale region including many giant molecular clouds. Among the detected molecules CN, CCH, and CH3OH are found to be abundant. High abundances of CN, and CCH are consistent with the above picture of a wide spread distribution of molecules, because they can be produced by photodissociation. On the other hand, it seems likely that CH3OH is liberated into the gas phase by shocks associated with large scale phenomena such as cloud-cloud collisions and/or by non-thermal desorption processes such as photoevaporation due to cosmic-ray induced UV photons. The present result demonstrates a characteristic chemical composition of a giant molecular cloud complex in the spiral arm, which can be used as a standard reference for studying chemistry in AGNs and starbursts.Comment: 45 pages, 12 figures, accepted for publication in Ap

Molecular Distribution in the Spiral Arm of M51

Molecular line images of 13CO, C18O, CN, CS, CH3OH, and HNCO are obtained toward the spiral arm of M51 at a 7" times 6" resolution with the Combined Array for Research in Millimeter-wave Astronomy (CARMA). Distributions of the molecules averaged over a 300 pc scale are found to be almost similar to one another and to essentially trace the spiral arm. However, the principal component analysis shows a slight difference of distributions among molecular species particularly for CH3OH and HNCO. These two species do not correlate well with star-formation rate, implying that they are not enhanced by local star-formation activities but by galactic-scale phenomena such as spiral shocks. Furthermore, the distribution of HNCO and CH3OH are found to be slightly different, whose origin deserves further investigation. The present results provide us with an important clue to understanding the 300 pc scale chemical composition in the spiral arm and its relation to galactic-scale dynamics.Comment: 20 pages, 9 figures, 8 tables, accepted for publication in Ap

An unbiased spectral line survey observation toward the low-mass star-forming region L1527

An unbiased spectral line survey toward a solar-type Class 0/I protostar, IRAS04368+2557, in L1527 has been carried out in the 3 mm band with the Nobeyama 45 m telescope. L1527 is known as a warm carbon-chain chemistry (WCCC) source, which harbors abundant unsaturated organic species such as C$_n$H ($n = 3,\ 4,\ 5,\ldots$) in a warm and dense region near the protostar. The observation covers the frequency range from 80 to 116 GHz. A supplementary observation has also been conducted in the 70 GHz band to observe fundamental transitions of deuterated species. In total, 69 molecular species are identified, among which 27 species are carbon-chain species and their isomers, including their minor isotopologues. This spectral line survey provides us with a good template of the chemical composition of the WCCC source.Comment: published online in PAS

A 3 mm Spectral Line Survey toward the Barred Spiral Galaxy NGC 3627

We conduct spectral line survey observations in the 3 mm band toward a spiral arm, a bar-end, and a nuclear region of the nearby barred spiral galaxy NGC 3627 with the IRAM 30 m telescope and the Nobeyama 45 m telescope. Additional observations are performed toward the spiral arm and the bar-end in the 2 mm band. We detect 8, 11, and 9 molecular species in the spiral arm, the bar-end, and the nuclear region, respectively. Star-formation activities are different among the three regions, and in particular, the nucleus of NGC 3627 is known as a LINER/Seyfert 2 type nucleus. In spite of these physical differences, the chemical composition shows impressive similarities among the three regions. This result means that the characteristic chemical composition associated with these regions is insensitive to the local physical conditions such as star formation rate, because such local effects are smeared out by extended quiescent molecular gas on scales of 1 kpc. Moreover, the observed chemical compositions are also found to be similar to those of molecular clouds in our Galaxy and the spiral arm of M51, whose elemental abundances are close to those in NGC 3627. Therefore, this study provides us with a standard template of the chemical composition of extended molecular clouds with the solar metalicity in nearby galaxies.Comment: Accepted for publication in The Astrophysical Journal Supplement Series, 10 figures, 10 table

RePair in Compressed Space and Time

Given a string $T$ of length $N$, the goal of grammar compression is to construct a small context-free grammar generating only $T$. Among existing grammar compression methods, RePair (recursive paring) [Larsson and Moffat, 1999] is notable for achieving good compression ratios in practice. Although the original paper already achieved a time-optimal algorithm to compute the RePair grammar RePair($T$) in expected $O(N)$ time, the study to reduce its working space is still active so that it is applicable to large-scale data. In this paper, we propose the first RePair algorithm working in compressed space, i.e., potentially $o(N)$ space for highly compressible texts. The key idea is to give a new way to restructure an arbitrary grammar $S$ for $T$ into RePair($T$) in compressed space and time. Based on the recompression technique, we propose an algorithm for RePair($T$) in $O(\min(N, nm \log N))$ space and expected $O(\min(N, nm \log N) m)$ time or $O(\min(N, nm \log N) \log \log N)$ time, where $n$ is the size of $S$ and $m$ is the number of variables in RePair($T$). We implemented our algorithm running in $O(\min(N, nm \log N) m)$ time and show it can actually run in compressed space. We also present a new approach to reduce the peak memory usage of existing RePair algorithms combining with our algorithms, and show that the new approach outperforms, both in computation time and space, the most space efficient linear-time RePair implementation to date

The role of SiO as a tracer of past star-formation events: The case of the high-mass protocluster NGC 2264-C

NGC 2264-C is a high-mass protocluster where several star-formation events are known to have occurred. To investigate whether past protostellar activity has left a chemical imprint in this region, we mapped it in SiO($J = 2-1$), a shock tracer, and several other molecular lines with the Nobeyama 45 m telescope. Our observations show the presence of a complex network of protostellar outflows. The strongest SiO emission lies beyond a radius of $\sim 0.1$ pc with respect to the center of the clump, and is characterized by broad ($> 10$ km s$^{-1}$) lines and abundances of $\sim 1.4 \times 10^{-8}$ with respect to H$_2$. Interestingly, SiO appears relatively depleted ($\chi_\mathrm{SiO} \sim 4 \times 10^{-9}$) within this radius, despite it being affected by molecular outflow activity. We attribute this to fast condensation of SiO back onto dust grains and/or rapid gas-phase destruction of SiO, favored by the high density present in this area ($> 10^6$ cm$^{-3}$). Finally, we identify a peripheral, narrow-line ($\sim 2$ km s$^{-1}$) component, where SiO has an abundance of a few times 10$^{-11}$. After considering different options, we conclude that this weak emission may be tracing protostellar shocks from the star formation episode that preceded the current one, which have decelerated over time and eventually resulted in SiO being largely depleted/destroyed. Alternatively, a population of unresolved low-mass protostars may be responsible for the narrow SiO emission. High-angular resolution observations are necessary to distinguish between these two possibilities and thus understand the role of SiO as a chemical tracer of past star-formation episodes in massive protoclusters.Comment: 33 pages, 5 figure

Discovery of Striking Difference of Molecular-Emission-Line Richness in the Potential Proto-Binary System NGC 2264 CMM3

We have conducted an interferometric line survey in the 0.8 mm band toward the young high-mass protostar candidate NGC 2264 CMM3 with ALMA. CMM3 is resolved into the two continuum peaks, CMM3A and CMM3B, at an angular separation of 0.9". Thus, CMM3 is found to be a binary system candidate. We have detected molecular outflows associated with CMM3A and CMM3B each, indicating active star formation. In addition to the two peaks, six faint continuum peaks are detected around CMM3A and CMM3B, most of which are thought to be evolved low-mass protostars. CMM3A is found to be rich in molecular line emission including complex organic molecules such as HCOOCH3 and CH3OCH3. The emission of complex organic molecules is distributed within a compact region around the continuum peak of CMM3A. Hence, CMM3A apparently harbors a hot core. On the other hand, CMM3B is deficient in molecular line emission, although its continuum flux is almost comparable to that of CMM3A. Possible origins of the striking difference between CMM3A and CMM3B are discussed.Comment: Accepted for publication in ApJ, 7 figures, 2 table

Molecular-Cloud-Scale Chemical Composition III: Constraints of Average Physical Properties through Chemical Models

It is important to understand the origin of molecular line intensities and chemical composition in the molecular-cloud scale in the Galactic sources because it serves as a benchmark to compare with the chemical compositions of extragalactic sources. Recent observations of the 3-mm spectra averaged over the 10-pc scale show similar spectral pattern among sources for molecular lines HCN, HCO$^+$, CCH, HNC, HNCO, c-C$_3$H$_2$, CS, SO, N$_2$H$^+$, and CN. To constrain the average physical property emitting such spectral pattern, we model molecular spectra using a time-dependent gas-grain chemical model followed by a radiative transfer calculation. We use a grid of physical parameters such as the density $n=3 \times 10^2 - 3\times 10^4$ cm$^{-3}$, the temperature, $T=10-30$ K, the visual extinction $A_{\rm V} = 2,4,10$ mag, the cosmic-ray ionization rate $\zeta = 10^{-17} - 10^{-16}$ s$^{-1}$, and the sulfur elemental abundance $S/H = 8\times 10^{-8} - 8\times 10^{-7}$. Comparison with the observed spectra indicates that spectra are well reproduced with the relatively low density of $n=(1-3) \times 10^3\,$cm$^{-3}$, $T=10\,$K, $\zeta = 10^{-17}$ s$^{-1}$, and the short chemistry timescale of $10^5$ yrs. This short chemistry timescale may indicate that molecular clouds are constantly affected by the turbulence, and exposed to low-density, low $A_{\rm V}$ regions that "refreshes" the chemical clock by UV radiation. The relatively low density obtained is orders of magnitude lower than the commonly-quoted critical density in the optically thin case. Meanwhile, this range of density is consistent with results from recent observational analysis of molecular-cloud-scale mapping.Comment: 30 pages, 21 figures, accepted for publication in The Astrophysical Journa

Spectral Line Survey toward Molecular Clouds in the Large Magellanic Cloud

Spectral line survey observations of 7 molecular clouds in the Large Magellanic Cloud (LMC) have been conducted in the 3 mm band with the Mopra 22 m telescope to reveal chemical compositions in low metallicity conditions. Spectral lines of fundamental species such as CS, SO, CCH, HCN, HCO+, and HNC are detected in addition to those of CO and 13CO, while CH3OH is not detected in any source and N2H+ is marginally detected in two sources. The molecular-cloud scale (10 pc scale) chemical composition is found to be similar among the 7 sources regardless of different star formation activities, and hence, it represents the chemical composition characteristic to the LMC without influences of star formation activities. In comparison with chemical compositions of Galactic sources, the characteristic features are (1) deficient N-bearing molecules, (2) abundant CCH, and (3) deficient CH3OH. The feature (1) is due to a lower elemental abundance of nitrogen in the LMC, whereas the features (2) and (3) seem to originate from extended photodissociation regions and warmer temperature in cloud peripheries due to a lower abundance of dust grains in the low metallicity condition. In spite of general resemblance of chemical abundances among the seven sources, the CS/HCO+ and SO/HCO+ ratios are found to be slightly higher in a quiescent molecular cloud. An origin of this trend is discussed in relation to possible depletion of sulfur along molecular cloud formation.Comment: 45 pages, 7 figures, 7 tables, accepted for publication in Ap

Spectrometer Using superconductor MIxer Receiver (SUMIRE) for Laboratory Submillimeter Spectroscopy

Recent spectroscopic observations by sensitive radio telescopes require accurate molecular spectral line frequencies to identify molecular species in a forest of lines detected. To measure rest frequencies of molecular spectral lines in the laboratory, an emission-type millimeter and submillimeter-wave spectrometer utilizing state-of-the-art radio-astronomical technologies is developed. The spectrometer is equipped with a 200 cm glass cylinder cell, a two sideband (2SB) Superconductor-Insulator-Superconductor (SIS) receiver in the 230 GHz band, and wide-band auto-correlation digital spectrometers. By using the four 2.5 GHz digital spectrometers, a total instantaneous bandwidth of the 2SB SIS receiver of 8 GHz can be covered with a frequency resolution of 88.5 kHz. Spectroscopic measurements of CH$_3$CN and HDO are carried out in the 230 GHz band so as to examine frequency accuracy, stability, sensitivity, as well as intensity calibration accuracy of our system. As for the result of CH$_3$CN, we confirm that the frequency accuracy for lines detected with sufficient signal to noise ratio is better than 1 kHz, when the high resolution spectrometer having a channel resolution of 17.7 kHz is used. In addition, we demonstrate the capability of this system by spectral scan measurement of CH$_3$OH from 216 GHz to 264 GHz. We assign 242 transitions of CH$_3$OH, 51 transitions of $^{13}$CH$_3$OH, and 21 unidentified emission lines for 295 detected lines. Consequently, our spectrometer demonstrates sufficient sensitivity, spectral resolution, and frequency accuracy for in-situ experimental-based rest frequency measurements of spectral lines on various molecular species.Comment: Accepted for publication in Publications of the Astronomical Society of Japan (PASJ) , 15 figures, 4 tables, typos correcte