Green extraction method of cellulose fibers from oil palm empty fruit bunches

Oil palm empty fruit bunches (OPEFB) is one of the major biomass wastes produced from palm oil extraction process. Due to high cellulose content in OPEFB, the cellulose fibers in OPEFB can be extracted and utilized in versatile applications as a sustainable process technology development. Among multiple pre-treatment processes, chemical pre-treatment is most efficient for the removal of hemicellulose and lignin in extracting high purity cellulose from lignocellulosic biomass. With the undisputed importance of green technology for the progress of our society, it is vital to engage and leverage on green technology in chemical pre-treatment method for extracting cellulose from OPEFB. The objective of this study is to explore a green extraction method for cellulose from OPEFB using low concentration and eco-friendly chemicals. Fourier transform infrared spectroscopy and field emission scanning electron microscope was used to detect the functional groups and to observe the surface morphology of OPEFB, de-waxed OPEFB fibers, delignified OPEFB fibers, acid hydrolyzed OPEFB fibers, and OPEFB extracted cellulose fibers at different stages in confirming the removal of wax, lignin, and hemicellulose from OPEFB extracted cellulose at the end of the extraction process. Crystallinity index increased from 28% for OPEFB to 72% for the OPEFB extracted cellulose, affirms the degradation of OPEFB’s amorphous structure and transforms into higher crystallinity structure. This work has successfully developed a green extraction method for OPEFB cellulose fibers as part of sustainable process technology which would promote the utilization of lignocellulosic agricultural waste from palm oil industry in various applications

Synthesis and characterization of ZnO-decorated GO nanocomposite material with different ZnO loading through sol-gel method

This work aimed is to synthesis a well dispersed zinc oxide (ZnO) nanoparticles (NPs) decorated on graphene oxide (GO) nanosheet with a practical way by using sol-gel technique. Zinc acetate dehydrate (Zn(CH3COO) 2·2H2O) was used as precursor of ZnO and absolute ethanol as solvent. 1 weight percent (wt%), 5 wt%, 10 wt%, and 20 wt% of ZnO was decorated on GO nanosheet. A series of analysis was carried out to characterize the synthesized ZnO-decorated GO nanocomposite material. The results of XRD analysis show some long area of peak at 25° to 80° allocate for ZnO in the ZnO-decorated GO nanocomposite material. By performing zeta potential analysis, the findings show that there was increment of negative surface charge on ZnO-decorated GO nanocomposite material. The experiment result also found that the hydrodynamic particle size of ZnO-decorated GO nanocomposite material become larger when high ZnO loaded. FESEM micrographs demonstrated that spherical-shaped of ZnO NPs appeared on the GO nanosheet with further proved by EDX where the content of ZnO-decorated GO nanocomposite material was composed by 71.3 wt% of C, 17 wt% of O, and additional element of 11.7 wt% of Zn. Thus, it can summarize that the synthesized ZnO-decorated GO nanocomposite material was high in purity. The findings in this study proved that ZnO NPs loading in ZnO-decorated GO nanocomposite material were successfully synthesized by sol-gel method. A ZnO-decorated GO nanocomposite material with layering ZnO NPs on GO nanosheet was produced

The effect of ZnO loading for the enhancement of PSF/ZnO-GO mixed matrix membrane performance

This study was aimed to investigate the effect of ZnO-decorated GO nanocomposite material loaded with different weight percent of ZnO toward polysulfone (PSF) mixed-matrix membrane (MMM) performance enhancement. ZnO-decorated GO nanocomposite material was loaded with 1, 5, 10 and 20 wt. % ZnO was blended with PSF polymer and fabricated through phase inversion process. The performance of the fabricated MMMs were evaluated by measuring membrane permeability, bovine serum albumin rejection (BSA) and flux recovery ratio (FRR). Experiment results demonstrated that the PSF/ZnO-GO MMM performances were greatly improved where 10 wt. % ZnO loaded into ZnO-decorated GO nanomaterial exhibited the highest permeability (5.35 L/m2·h·bar) and BSA retention at all pH state among all fabricated mixed-matrix membranes. Additionally, FRR was also dramatically improved attributed to the smoother membrane surface. This work has shown that a well distribution of ZnO with the help of GO nanosheet as a dispersing agent blended with PSF polymer to form PSF/ZnO-GO MMM was a promising approach in creating better ultrafiltration (UF) membrane with a better hydrophilicity, permeability, and cleaning efficiency for the used in food industry in future

Potential of membrane technology for treatment and reuse of water from old mining lakes

The El-Nino phenomenon in early 2014 contributed to the lack of water supply in most Southeast Asian countries. Suggestions have since been made to ensure the continuity of water supply, one of which involves membrane technology to treat mine water so that it is compatible for citizens’ use. Accordingly, the objective of this research was to study the efficiency of membrane technology in treating mine water. Our elucidation of all the parameters has showed that the best attainable classification is at Class IV. Although it was still regarded as polluted, the treated mine water can be used as water supply reservoir. For the membranes tested such as ultrafiltration 10 kDa, 5 kDa and reverse osmosis, the percentage of rejection for chemical oxygen demand is 21-72%, 40-96% for total suspended solids and 21-72% for ammonia nitrogen. The pH also gradually shifted to almost neutral after the filtration

Application of membrane technology towards the reusability of lake water, mine water, and tube well water

Severe water shortage caused by El-Nino has caused life-threatening drought conditions globally. This natural disaster has put millions of lives at risk and forcing the people to search for waster. However, the water scarcity problem was not just limited to the countries that were strike by El-Nino. Poor water management and climate change were bringing droughts to Asia and the Pacific. The water scarcity worldwide has recently reached the alarming rate and received the greatest attention among the people. Membrane technology is an innovative technology which has proven to be effective and efficient for water and wastewater treatment. Therefore, membrane technology has high potential to be employed for the treatment of lake water, mine water, and tube well water in increasing the fresh water production for reuse purpose. The objective of this work is to investigate the potential of membrane technology for treating the lake water, mine water, and tube well water. A laboratory bench-scale dead-end test rig was used in this study to evaluate the performance of commercial flat-sheet nanofiltration (NF) - NF270 and reverse osmosis (RO) - BW30 membranes. Both source water and treated water were analysed based on chemical oxygen demand (COD), ammonia nitrogen (NH3-N), colour, total suspended solid (TSS), pH, and temperature. In order to prove the reuse concept of membrane technology, the permeate water quality after the membrane filtration process was compared with National Water Quality Standard (NWQS) of Malaysia. The results from this study shown that the permeate water filtered by NF270 and BW30 membranes were able to meet the NWQS Class III, which was suitable to recycled for livestock drinking and irrigation purposes

Investigation of Anti-fouling and UV-Cleaning Properties of PVDF/TiO2 Mixed-Matrix Membrane for Humic Acid Removal

Natural organic matters (NOMs) have been found to be the major foulant in the application of ultrafiltration (UF) for treating surface water. Against this background, although hydrophilicity has been demonstrated to aid fouling mitigation, other parameters such as membrane surface morphology may contribute equally to improved fouling resistance. In this work, with humic acid solution as the model substance, the effects of titanium dioxides (TiO2) types (PC-20, P25, and X500) on membrane anti-fouling and defouling properties were comparatively analysed. The aims are (1) to determine the correlation between membrane surface morphology and membrane fouling and (2) to investigate the anti-fouling and UV-cleaning abilities of PVDF/TiO2 mixed-matrix membranes with different membrane topographies and surface energy conditions. The mixed-matrix membrane with P25 TiO2 exhibited the most significant UV-defouling ability, with a high irreversible flux recovery ratio (IFRR(UV)) of 16.56 after 6 h of UV irradiation, whereas that with X500 TiO2 exhibited both superior anti-fouling and defouling properties due to its smoother surface and its highly reactive surface layer

Green Synthesis of Thermo-Responsive Hydrogel from Oil Palm Empty Fruit Bunches Cellulose for Sustained Drug Delivery

Drug delivery is a difficult task in the field of dermal therapeutics, particularly in the treatment of burns, wounds, and skin diseases. Conventional drug delivery mediums have some limitations, including poor retention on skin/wound, inconvenience in administration, and uncontrolled drug release profile. Hydrogels able to absorb large amount of water and give a spontaneous response to stimuli imposed on them are an attractive solution to overcome the limitations of conventional drug delivery media. The objective of this study is to explore a green synthesis method for the development of thermo-responsive cellulose hydrogel using cellulose extracted from oil palm empty fruit bunches (OPEFB). A cold method was employed to prepare thermo-responsive cellulose hydrogels by incorporating OPEFB-extracted cellulose and Pluronic F127 (PF127) polymer. The performance of the synthesized thermo-responsive cellulose hydrogels were evaluated in terms of their swelling ratio, percentage of degradation, and in-vitro silver sulfadiazine (SSD) drug release. H8 thermo-responsive cellulose hydrogel with 20 w/v% PF127 and 3 w/v% OPEFB extracted cellulose content was the best formulation, given its high storage modulus and complex viscosity (81 kPa and 9.6 kPa.s, respectively), high swelling ratio (4.22 ± 0.70), and low degradation rate (31.3 ± 5.9%), in addition to high t50% value of 24 h in SSD in-vitro drug release to accomplish sustained drug release. The exploration of thermo-responsive cellulose hydrogel from OPEFB would promote cost-effective and sustainable drug delivery system with using abundantly available agricultural biomass

Performance and resilience of the PolyCera® Titan membrane for industrial wastewater treatment

This research aims to evaluate the performance of PolyCera® Titan membrane for different wastewater treatment. Membrane filtration of several cycles was conducted in understanding the fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan which had not been studied by any other researcher before. The PolyCera® Titan membrane is effective for the treatment of textile industry wastewater, palm oil mill effluent (POME), leachate, and semiconductor-industry wastewater. Rejection of methylene blue (MB) and Congo red (CR) was in the range of 78.76–86.04% and 88.89–93.71%, respectively; 94.72–96.50% NaCl, 96.07–97.62% kaolin, and 97.26–97.73% glucose were rejected from synthetic leachate indicating the removal of TDS, TSS, and COD from the leachate, respectively. Standard blocking and complete model were the best models used to explain the PolyCera® Titan membrane fouling mechanism in all types of wastewater treatment processes with a high R2 value. Physical cleaning with the use of distilled water was able to recover the permeate flux with the flux recovery ratio (FRR) value in the range of 79.2–95.22% in the first cycle, 81.20–98.16% in the second cycle, and 86.09–95.96% in the third cycle. HIGHLIGHTS Performance of PolyCera® Titan membrane for synthetic textile industry wastewater, POME, synthetic leachate, and semiconductor-industry wastewater treatment.; Understanding on fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan membrane.

An Overview of the Modification Strategies in Developing Antifouling Nanofiltration Membranes

Freshwater deficiency has become a significant issue affecting many nations’ social and economic development because of the fast-growing demand for water resources. Nanofiltration (NF) is one of the promising technologies for water reclamation application, particularly in desalination, water, and wastewater treatment fields. Nevertheless, membrane fouling remains a significant concern since it can reduce the NF membrane performance and increase operating expenses. Consequently, numerous studies have focused on improving the NF membrane’s resistance to fouling. This review highlights the recent progress in NF modification strategies using three types of antifouling modifiers, i.e., nanoparticles, polymers, and composite polymer/nanoparticles. The correlation between antifouling performance and membrane properties such as hydrophilicity, surface chemistry, surface charge, and morphology are discussed. The challenges and perspectives regarding antifouling modifiers and modification strategies conclude this review

Fouling assessment of tertiary palm oil mill effluent (POME) membrane treatment for water reclamation

In order to minimize the adverse impacts of palm oil mill effluent (POME) towards the environment and to cope with the stress associated with water scarcity, membrane technology has been employed to reclaim water from POME. This study investigated the performance and fouling propensity of membranes in treating tertiary POME with the aim to recycle and reuse the reclaimed water as boiler feed water. Three types of membranes (NF270, BW30, and XLE) were used and their performances were evaluated based on the removal of chemical oxygen demand (COD), color, turbidity, total dissolved solids, phosphorus, and conductivity. All parameters were significantly reduced through XLE and BW30 membrane filtration processes in which the permeate was complied with the boiler feed water standard, except NF270 membrane where the COD value exceeded the allowable limit. High permeation drag of NF270 and rougher surface of XLE membranes resulted in the accumulation of foulant on the membrane surfaces which eventually reduced the permeate flux, whereas BW30 membrane was encountered for lower fouling propensity due to its low permeation rate. Hence, BW30 was deemed as the best candidate for water reclamation due to its low fouling propensity and because the production of permeate complied with boiler feed water standard