The emergence of global phase coherence from local pairing in underdoped cuprates

In conventional metal superconductors such as aluminum, the large number of weakly bounded Cooper pairs become phase coherent as soon as they start to form. The cuprate high critical temperature ($T_c$) superconductors, in contrast, belong to a distinctively different category. To account for the high $T_c$, the attractive pairing interaction is expected to be strong and the coherence length is short. Being doped Mott insulators, the cuprates are known to have low superfluid density, thus are susceptible to phase fluctuations. It has been proposed that pairing and phase coherence may occur separately in cuprates, and $T_c$ corresponds to the phase coherence temperature controlled by the superfluid density. To elucidate the microscopic processes of pairing and phase ordering in cuprates, here we use scanning tunneling microscopy to image the evolution of electronic states in underdoped $\rm Bi_2La_xSr_{2-x}CuO_{6+{\delta}}$. Even in the insulating sample, we observe a smooth crossover from the Mott insulator to superconductor-type spectra on small islands with chequerboard order and emerging quasiparticle interference patterns following the octet model. Each chequerboard plaquette contains approximately two holes, and exhibits a stripy internal structure that has strong influence on the superconducting features. Across the insulator to superconductor boundary, the local spectra remain qualitatively the same while the quasiparticle interferences become long-ranged. These results suggest that the chequerboard plaquette with internal stripes plays a crucial role on local pairing in cuprates, and the global phase coherence is established once its spatial occupation exceeds a threshold

Rapid post-disaster infrastructure damage characterisation enabled by remote sensing and deep learning technologies -- a tiered approach

Critical infrastructure, such as transport networks and bridges, are systematically targeted during wars and suffer damage during extensive natural disasters because it is vital for enabling connectivity and transportation of people and goods, and hence, underpins national and international economic growth. Mass destruction of transport assets, in conjunction with minimal or no accessibility in the wake of natural and anthropogenic disasters, prevents us from delivering rapid recovery and adaptation. As a result, systemic operability is drastically reduced, leading to low levels of resilience. Thus, there is a need for rapid assessment of its condition to allow for informed decision-making for restoration prioritisation. A solution to this challenge is to use technology that enables stand-off observations. Nevertheless, no methods exist for automated characterisation of damage at multiple scales, i.e. regional (e.g., network), asset (e.g., bridges), and structural (e.g., road pavement) scales. We propose a methodology based on an integrated, multi-scale tiered approach to fill this capability gap. In doing so, we demonstrate how automated damage characterisation can be enabled by fit-for-purpose digital technologies. Next, the methodology is applied and validated to a case study in Ukraine that includes 17 bridges, damaged by human targeted interventions. From regional to component scale, we deploy technology to integrate assessments using Sentinel-1 SAR images, crowdsourced information, and high-resolution images for deep learning to facilitate automatic damage detection and characterisation. For the first time, the interferometric coherence difference and semantic segmentation of images were deployed in a tiered multi-scale approach to improve the reliability of damage characterisations at different scales

Visualizing the Zhang-Rice singlet, molecular orbitals and pair formation in cuprate

The parent compound of cuprates is a charge-transfer-type Mott insulator with strong hybridization between the Cu $3d_{\mathrm x^2-y^2}$ and O $2p$ orbitals. A key question concerning the pairing mechanism is the behavior of doped holes in the antiferromagnetic (AF) Mott insulator background, which is a prototypical quantum many-body problem. It was proposed that doped hole on the O site tends to form a singlet, known as Zhang-Rice singlet (ZRS), with the unpaired Cu spin. But experimentally little is known about the properties of a single hole and the interplay between them that leads to superconductivity. Here we use scanning tunneling microscopy to visualize the electronic states in hole-doped $\mathrm{Ca_2CuO_2Cl_2}$, aiming to establish the atomic-scale local basis for pair formation. A single doped hole is shown to have an in-gap state and a clover-shaped spatial distribution that can be attributed to a localized ZRS. When the dopants are close enough, they develop delocalized molecular orbitals with characteristic stripe- and ladder-shaped patterns, accompanied by the opening of a small gap around the Fermi level ($E_{\mathrm F}$). With increasing doping, the molecular orbitals proliferate in space and gradually form densely packed plaquettes, but the stripe and ladder patterns remain nearly the same. The low-energy electronic states of the molecular orbitals are intimately related to the local pairing properties, thus play a vitally important role in the emergence of superconductivity. We propose that the Cooper pair is formed by two holes occupying the stripe-like molecular orbital, while the attractive interaction is mediated by the AF spin background

Molecular Bubble and Outflow in S Mon Revealed by Multiband Datasets

We identify a molecular bubble, and study the star formation and its feedback in the S Mon region, using multiple molecular lines, young stellar objects (YSOs), and infrared data. We revisit the distance to S Mon, ~722+/-9 pc, using Gaia Data Release 3 parallaxes of the associated Class II YSOs. The bubble may be mainly driven by a massive binary system (namely 15 Mon), the primary of which is an O7V-type star. An outflow is detected in the shell of the bubble, suggesting ongoing star formation activities in the vicinity of the bubble. The total wind energy of the massive binary star is three orders of magnitude higher than the sum of the observed turbulent energy in the molecular gas and the kinetic energy of the bubble, indicating that stellar winds help to maintain the turbulence in the S Mon region and drive the bubble. We conclude that the stellar winds of massive stars have an impact on their surrounding environment.Comment: 34 pages,19 figures, 5 tables, Accepted for publication in Ap

Distributions and Physical Properties of Molecular Clouds in the Third Galactic Quadrant: ll = [219.75, 229.75]∘^\circ and bb = [-5.25, 5.25]∘^\circ

We present the results of an unbiased $^{12}$CO/$^{13}$CO/C$^{18}$O ($J$ = 1-0) survey in a portion of the third Galactic quadrant (TGQ): $l$ = [219.75, 229.75]$^\circ$ and $b$ = [-5.25, 5.25]$^\circ$. The high-resolution and high-sensitivity data sets help to unravel the distributions and physical properties of the molecular clouds (MCs) in the mapped area. In the LSR velocity range from -1 to 85 km/s, the molecular material successfully traces the Local, Perseus, and Outer arms. In the TGQ, the Outer arm appears to be more prominent than that in the second Galactic quadrant (SGQ), but the Perseus arm is not as conspicuous as that in the SGQ. A total of 1,502 $^{12}$CO, 570 $^{13}$CO, and 53 C$^{18}$O molecular structures are identified, spanning over $\sim2$ and $\sim6$ orders of magnitude in size and mass, respectively. Tight mass-radius correlations and virial parameter-mass anticorrelations are observable. Yet, it seems that no clear correlations between velocity dispersion and effective radius can be found over the full dynamic range. The vertical distribution of the MCs renders evident pictures of the Galactic warp and flare.Comment: 22 pages, 13 figures, 7 tables (with machine-readable versions), published in ApJ

Si-Ni-San alleviates early life stress-induced depression-like behaviors in adolescence via modulating Rac1 activity and associated spine plasticity in the nucleus accumbens

Background: Early life stress (ELS) is a major risk factor for depression in adolescents. The nucleus accumbens (NAc) is a key center of the reward system, and spine remodeling in the NAc contributes to the development of depression. The Si-Ni-San formula (SNS) is a fundamental prescription for treating depression in traditional Chinese medicine. However, little is known about the effects of SNS on behavioral abnormalities and spine plasticity in the NAc induced by ELS.Purpose: This study aimed to investigate the therapeutic effect and the modulatory mechanism of SNS on abnormal behaviors and spine plasticity in the NAc caused by ELS.Methods: We utilized a model of ELS that involved maternal separation with early weaning to explore the protective effects of SNS on adolescent depression. Depressive-like behaviors were evaluated by the sucrose preference test, the tail suspension test, and the forced swimming test; anxiety-like behaviors were monitored by the open field test and the elevated plus maze. A laser scanning confocal microscope was used to analyze dendritic spine remodeling in the NAc. The activity of Rac1 was detected by pull-down and Western blot tests. Viral-mediated gene transfer of Rac1 was used to investigate its role in ELS-induced depression-like behaviors in adolescence.Results: ELS induced depression-like behaviors but not anxiety-like behaviors in adolescent mice, accompanied by an increase in stubby spine density, a decrease in mushroom spine density, and decreased Rac1 activity in the NAc. Overexpression of constitutively active Rac1 in the NAc reversed depression-related behaviors, leading to a decrease in stubby spine density and an increase in mushroom spine density. Moreover, SNS attenuated depression-like behavior in adolescent mice and counteracted the spine abnormalities in the NAc induced by ELS. Additionally, SNS increased NAc Rac1 activity, and the inhibition of Rac1 activity weakened the antidepressant effect of SNS.Conclusion: These results suggest that SNS may exert its antidepressant effects by modulating Rac1 activity and associated spine plasticity in the NAc

Assessment of Rain Garden Effects for the Management of Urban Storm Runoff in Japan

Storm runoff is a growing concern against a background of increasing urban densification, land-use adaptation and climate change. In this study, a storm water management model was used to analyze the hydrological and water-quality effects of rain gardens (also known as bioretention cells) as nonpoint source control solutions in low-impact development (LID) practices for an urban catchment in the Nakagyo Ward area of Kyoto in Japan. The results of simulations with input involving Chicago hyetographs derived for different rainfall return periods (referred to as 3 a, 5 a, 10 a, 30 a, 50 a and 100 a) indicated the effectiveness of this arrangement, in particular for rainstorm 3 a, which exhibited the maximum contaminant reduction ratio (Total Suspended Solids (TSS) 15.50%, Chemical Oxygen Demand (COD) 16.17%, Total Nitrogen (TN) 17.34%, Total Phosphorus (TP) 19.07%) and a total runoff reduction volume of 46.56 × 106 L. With 5 a, the maximum number of flooding nodes was reduced to 87, demonstrating that rain gardens handle rainfall effectively over a five-year return period. There was a one-minute delay for 100 a, which again indicates that rain gardens support control of urban runoff and mitigate flooding. Such gardens were associated with reduced stormwater hazards and enhanced resistance to short-term rainstorms at the research site, and should be considered for urban planning in Kyoto and other cities all over the world