Proton modified Pt zeolite fuel cell electrocatalysts

NaY Zeolite is selected as a suitable material to host 1.5 wt% Platinum (Pt) loading on zeolite using ion exchange method (a) Pt(NH3)4(NO3)2 without excess NH4NO3 nitrate and (b) Pt(NH3)4(NO3)2 with excess NH4NO3 nitrate. The structure/reactivity relationship of Pt nanoparticle has been experimentally studied via Nafion@ bound electrodes to investigate the interaction nature of Pt with zeolite and electron transfer using the extended X-ray adsorption fine structure (EXAFS) and Pt particle was predicted at 0.7 – 1.5 (nm). Pt oxides can be electrochemically reduced via a hydrogen ‘spillover’ phenomenon. A highly dispersed small Pt particle distribution can be achieved with excessive H+ ions on zeolite acidic sites

Sign Changes of Intrinsic Spin Hall Effect in Semiconductors and Simple Metals: First-Principles Calculations

First-principles calculations are applied to study spin Hall effect in semiconductors and simple metals. We found that intrinsic spin Hall conductivity (ISHC) in realistic materials shows rich sign changes, which may be used to distinguish the effect from the extrinsic one. The calculated ISHC in n-doped GaAs can be well compared with experiment, and it differs from the sign obtained from the extrinsic effect. On the other hand, the ISHC in W and Au, which shows opposite sign respectively, is robust and not sensitive to the disorder.Comment: 4 pages, 4 figure

On the Finite-Time Blowup of a 1D Model for the 3D Axisymmetric Euler Equations

In connection with the recent proposal for possible singularity formation at the boundary for solutions of 3d axi-symmetric incompressible Euler's equations (Luo and Hou, 2013), we study models for the dynamics at the boundary and show that they exhibit a finite-time blow-up from smooth data.Comment: A paragraph at the end of Section 2 and an appendix discussing kinetic energy conservation are adde