An Efficient Synthesis and Photoelectric Properties of Green Carbon Quantum Dots with High Fluorescent Quantum Yield

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/)To greatly improve the production quality and efficiency of carbon quantum dots (CQDs), and provide a new approach for the large-scale production of high-quality CQDs, green carbon quantum dots (g-CQDs) with high product yield (PY) and high fluorescent quantum yield (QY) were synthesized by an efficient one-step solvothermal method with 2,7-dihydroxynaphthalene as the carbon source and ethylenediamine as the nitrogen dopant in this study. The PY and QY of g-CQDs were optimised by adjusting reaction parameters such as an amount of added ethylenediamine, reaction temperature, and reaction duration. The results showed that the maximum PY and QY values of g-CQDs were achieved, which were 70.90% and 62.98%, respectively when the amount of added ethylenediamine, reaction temperature, and reaction duration were 4 mL, 180 °C, and 12 h, respectively. With the optimised QY value of g-CQDs, white light emitting diodes (white LEDs) were prepared by combining g-CQDs and blue chip. The colour rendering index of white LEDs reached 87, and the correlated colour temperature was 2520 K, which belongs to the warm white light area and is suitable for indoor lighting. These results indicate that g-CQDs have potential and wide application prospects in the field of white LEDs.Peer reviewedFinal Published versio

Two types of spectral volume methods for 1-D linear hyperbolic equations with degenerate variable coefficients

In this paper, we analyze two classes of spectral volume (SV) methods for one-dimensional hyperbolic equations with degenerate variable coefficients. The two classes of SV methods are constructed by letting a piecewise $k$-th order ($k\ge 1$ is an arbitrary integer) polynomial function satisfy the local conservation law in each {\it control volume} obtained by dividing the interval element of the underlying mesh with $k$ Gauss-Legendre points (LSV) or Radaus points (RSV). The $L^2$-norm stability and optimal order convergence properties for both methods are rigorously proved for general non-uniform meshes. The superconvergence behaviors of the two SV schemes have been also investigated: it is proved that under the $L^2$ norm, the SV flux function approximates the exact flux with $(k+2)$-th order and the SV solution approximates the exact solution with $(k+\frac32)$-th order; some superconvergence behaviors at certain special points and for element averages have been also discovered and proved. Our theoretical findings are verified by several numerical experiments

Measurement and spatiotemporal patterns of China's digital economy efficiency

The digital economy has deeply integrated into various sectors, becoming a significant driving force for economic transformation and development, as new generation information technology continues to advance and mature. This paper builds upon theoretical analysis and employs the global Data Envelopment Analysis (DEA) method, along with relevant data from China's information transmission, software and information services industry spanning the years 2003 to 2020, to dynamically measure the output efficiency of China's digital economy. Based on this, the paper examines the overall characteristics of efficiency changes in the digital economy using distribution dynamics. Additionally, common descriptive statistics and data mapping techniques are utilized to reveal the spatiotemporal patterns of efficiency changes. The findings of the study are as follows: (1) The efficiency of the digital economy in the 31 provincial regions of China remains stable, but the factors influencing this efficiency vary both over time and among specific provinces. (2) From a temporal perspective, the digital economy in China demonstrates an overall positive increase in efficiency, with its volatility and differentiation largely shaped by the shifting factors of technological advancements and technological efficiency. (3) From a spatial perspective, there exists a distinct pattern of spatial disparities in China's digital economy efficiency, with higher efficiency observed in the eastern regions and lower efficiency in the western regions

Phase Coupled Firing of Prefrontal Parvalbumin Interneuron With High Frequency Oscillations

The prefrontal cortex (PFC) plays a central role in executive functions and inhibitory control over many cognitive behaviors. Dynamic changes in local field potentials (LFPs), such as gamma oscillation, have been hypothesized to be important for attentive behaviors and modulated by local interneurons such as parvalbumin (PV) cells. However, the precise relationships between the firing patterns of PV interneurons and temporal dynamics of PFC activities remains elusive. In this study, by combining in vivo electrophysiological recordings with optogenetics, we investigated the activities of prefrontal PV interneurons and categorized them into three subtypes based on their distinct firing rates under different behavioral states. Interestingly, all the three subtypes of interneurons showed strong phase-locked firing to cortical high frequency oscillations (HFOs), but not to theta or gamma oscillations, despite of behavior states. Moreover, we showed that sustained optogenetic stimulation (over a period of 10 s) of PV interneurons can consequently modulate the activities of local pyramidal neurons. Interestingly, such optogenetic manipulations only showed moderate effects on LFPs in the PFC. We conclude that prefrontal PV interneurons are consist of several subclasses of cells with distinct state-dependent modulation of firing rates, selectively coupled to HFOs