High energy Millihertz quasi-periodic oscillations in 1A 0535+262 with Insight-HXMT challenge current models

We studied the millihertz quasi-periodic oscillation (mHz QPO) in the 2020 outburst of the Be/X-ray binary 1A 0535+262 using Insight-HXMT data over a broad energy band. The mHz QPO is detected in the 27-120 keV energy band. The QPO centroid frequency is correlated with the source flux, and evolves in the 35-95 mHz range during the outburst. The QPO is most significant in the 50-65 keV band, with a significance of ~ 8 sigma, but is hardly detectable (<2 sigma) in the lowest (1-27 keV) and highest (>120 keV) energy bands. Notably, the detection of mHz QPO above 80 keV is the highest energy at which mHz QPOs have been detected so far. The fractional rms of the mHz QPO first increases and then decreases with energy, reaching the maximum amplitude at 50-65 keV. In addition, at the peak of the outburst, the mHz QPO shows a double-peak structure, with the difference between the two peaks being constant at ~0.02 Hz, twice the spin frequency of the neutron star in this system. We discuss different scenarios explaining the generation of the mHz QPO, including the beat frequency model, the Keplerian frequency model, the model of two jets in opposite directions, and the precession of the neutron star, but find that none of them can explain the origin of the QPO well. We conclude that the variability of non-thermal radiation may account for the mHz QPO, but further theoretical studies are needed to reveal the physical mechanism.Comment: 13 pages, 7 figures. Accepted for publication in MNRA

A Variable Ionized Disk Wind in the Black Hole Candidate EXO 1846–031

After 34 yr, the black hole candidate EXO 1846–031 went into outburst again in 2019. We investigate its spectral properties in the hard intermediate and the soft states with NuSTAR and Insight-HXMT. A reflection component has been detected in the two spectral states but possibly originating from different illumination spectra: in the intermediate state, the illuminating source is attributed to a hard coronal component, which has been commonly observed in other X-ray binaries, whereas in the soft state, the reflection is probably produced by disk self-irradiation. Both cases support EXO 1846–031 as a low-inclination system of ~40°. An absorption line is clearly detected at ~7.2 keV in the hard intermediate state, corresponding to a highly ionized disk wind (log} ξ > 6.1) with a velocity of up to 0.06c. Meanwhile, quasi-simultaneous radio emissions have been detected before and after the X-rays, implying the coexistence of disk winds and jets in this system. If only the high-flux segment of the NuSTAR observation is considered, the observed wind appears to be magnetically driven. The absorption line disappeared in the soft state and a narrow emission line appeared at ~6.7 keV on top of the reflection component, which may be evidence for disk winds, but data with higher spectral resolution are required to examine this

A variable ionized disk wind in the black hole candidate EXO 1846-031

After 34 yr, the black hole candidate EXO 1846-031 went into outburst again in 2019. We investigate its spectral properties in the hard intermediate and the soft states with NuSTAR and Insight-HXMT. A reflection component has been detected in the two spectral states but possibly originating from different illumination spectra: in the intermediate state, the illuminating source is attributed to a hard coronal component, which has been commonly observed in other X-ray binaries, whereas in the soft state, the reflection is probably produced by disk self-irradiation. Both cases support EXO 1846-031 as a low-inclination system of ∼ 40. An absorption line is clearly detected at ∼7.2 keV in the hard intermediate state, corresponding to a highly ionized disk wind (log, ξ > 6.1) with a velocity of up to 0.06c. Meanwhile, quasi-simultaneous radio emissions have been detected before and after the X-rays, implying the coexistence of disk winds and jets in this system. If only the high-flux segment of the NuSTAR observation is considered, the observed wind appears to be magnetically driven. The absorption line disappeared in the soft state and a narrow emission line appeared at ∼6.7 keV on top of the reflection component, which may be evidence for disk winds, but data with higher spectral resolution are required to examine this

Empirical Study on Human Capital, Economic Growth and Sustainable Development: Taking Shandong Province as an Example

This study aims to explore the sustainable development of the regional economy from the perspective of human capital. Based on the panel data from 2005 to 2019 in Shandong Province, China, this study first analyzes the interactive coupling mechanism between human capital and sustainable economic growth, and then constructs the evaluation model of coupling coordination degree. Results reveal that Shandong Province&rsquo;s human capital and sustainable economic growth gradually increased; the coupling coordination degree of human capital and sustainable economic growth changed from a state of mild imbalance to slight coordination; sustainable economic growth lagged human capital development; education scale, innovation capacity, growth level, economic openness, and investment and consumption level are the key factors affecting sustainable economic development. Through the above research, the study puts forward policy suggestions conducive to sustainable development in China

1,5-Dimethyl-4-{[1-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)ethyl]amino}-2-phenyl-1H-pyrazol-3(2H)-one

In the title compound, C23H23N5O2, an intramolecular N&amp;#8212;H...O hydrogen bond generates an S(6) ring, and the dihedral angle between the pyrazole rings is 48.42&amp;#8197;(8)&amp;#176;. The dihedral angles between the pyrazole rings and their attached phenyl rings are 10.06&amp;#8197;(8) and 47.53&amp;#8197;(8)&amp;#176;

Preparation of nano-TiO

Chitosan-TiO2 photocatalytic composite was prepared using anatase nano-TiO2 and edible chitosan. Fourier Transform Infrared Spectroscopy (FT-IR), ultraviolet visible (UV-vis) and scanning electron microscopy (SEM) was used to characterize the structure of the composites. The photocatalytic degradation performance of the composites was studied by constructing a simulation system. The stability of the combination between chitosan and TiO2 in the composite can be confirmed by the results of FT-IR, UV-vis and SEM. The composite had a good photocatalytic degradation effect. When the addition amount of chitosan-TiO2 was 0.4%, the degradation efficiency of heptanal, octanal, (E)-2-heptenal and (E)-2-octenal reached the highest values of 83.82%, 81.73%, 96.33% and 93.36%, respectively

Construction and Evaluation of Alginate Dialdehyde Grafted RGD Derivatives/Polyvinyl Alcohol/Cellulose Nanocrystals IPN Composite Hydrogels

To enhance the mechanical strength and cell adhesion of alginate hydrogel, making it satisfy the requirements of an ideal tissue engineering scaffold, the grafting of Arg-Gly-Asp (RGD) polypeptide sequence onto the alginate molecular chain was conducted by oxidation of sodium periodate and subsequent reduction amination of 2-methylpyridine borane complex (2-PBC) to synthesize alginate dialdehyde grafted RGD derivatives (ADA-RGD) with good cellular affinity. The interpenetrating network (IPN) composite hydrogels of alginate/polyvinyl alcohol/cellulose nanocrystals (ALG/PVA/CNCs) were fabricated through a physical mixture of ion cross-linking of sodium alginate (SA) with hydroxyapatite/D-glucono-δ-lactone (HAP/GDL), and physical cross-linking of polyvinyl alcohol (PVA) by a freezing/thawing method, using cellulose nanocrystals (CNCs) as the reinforcement agent. The effects of the addition of CNCs and different contents of PVA on the morphology, thermal stability, mechanical properties, swelling, biodegradability, and cell compatibility of the IPN composite hydrogels were investigated, and the effect of RGD grafting on the biological properties of the IPN composite hydrogels was also studied. The resultant IPN ALG/PVA/CNCs composite hydrogels exhibited good pore structure and regular 3D morphology, whose pore size and porosity could be regulated by adjusting PVA content and the addition of CNCs. By increasing the PVA content, the number of physical cross-linking points in PVA increased, resulting in greater stress support for the IPN composite hydrogels of ALG/PVA/CNCs and consequently improving their mechanical characteristics. The creation of the IPN ALG/PVA/CNCs composite hydrogels’ physical cross-linking network through intramolecular or intermolecular hydrogen bonding led to improved thermal resistance and reduced swelling and biodegradation rate. Conversely, the ADA-RGD/PVA/CNCs IPN composite hydrogels exhibited a quicker degradation rate, attributed to the elimination of ADA-RGD by alkali. The results of the in vitro cytocompatibility showed that ALG/0.5PVA/0.3%CNCs and ADA-RGD/PVA/0.3%CNCs composite hydrogels showed better proliferative activity in comparison with other composite hydrogels, while ALG/PVA/0.3%CNCs and ADA-RGD/PVA/0.3%CNCs composite hydrogels displayed obvious proliferation effects, indicating that PVA, CNCs, and ADA-RGD with good biocompatibility were conducive to cell proliferation and differentiation for the IPN composite hydrogels