219 research outputs found
Relaxation, Crystallization and Consolidation of an Amorphous Pd_<48>Ni_<32>P_<20> Alloy Powder
The influence of applied pressure on the structure relaxation, glass transition, crystallization and consolidation for an amorphous phase was examined by using a typical glassy Pd_Ni_P_ alloy in a spherical powder or a ribbon form. The Pd-Ni-P alloy was chosen because of the existence of a wide supercooled liquid region in the temperature range below crystallization temperature (T_x). The relaxation and crystallization are significantly suppressed by the application of compressive load, presumably because of the increase in viscosity and the decrease in diffusivity. As a result, the pressing at a high temperature of 0.97T_x is required to produce an amorphous bulk with high relative density. Furthermore, an intermediate annealing between pressings was found to be effective for the reduction of the enhanced viscosity. The multistage pressing treatment consisting of pressing and annealing enabled to produce a highly dense amorphous bulk even at a relatively low temperature near T_g
Theory of Non-Hermitian Fermionic Superfluidity on a Honeycomb Lattice: Interplay between Exceptional Manifolds and Van Hove Singularity
We study the non-Hermitian fermionic superfluidity subject to dissipation of
Cooper pairs on a honeycomb lattice, for which we analyze the attractive
Hubbard model with a complex-valued interaction. Remarkably, we demonstrate the
emergence of the dissipation-induced superfluid phase that is anomalously
enlarged by a cusp on the phase boundary. We find that this unconventional
phase transition originates from the interplay between exceptional lines and
van Hove singularity, which has no counterpart in equilibrium. Moreover, we
demonstrate that the infinitesimal dissipation induces the nontrivial
superfluid solution at the critical point. Our results can be tested in
ultracold atoms with photoassociation techniques by postselcting special
measurement outcomes with the use of quantum-gas microscopy and pave the way
for understanding non-Hermitian many-body physics triggered by exceptional
manifolds in open quantum systems.Comment: 7+5 pages, 4+3 figure
Ion-specific nanoscale compaction of cysteine-modified poly(acrylic acid) brushes revealed by 3D scanning force microscopy with frequency modulation detection
Stimuli-responsive polyelectrolyte brushes adapt their physico-chemical properties according to pH and ion concentrations of the solution in contact. We synthesized a poly(acrylic acid) bearing cysteine residues at side chains and a lipid head group at the terminal, and incorporated them into a phospholipid monolayer deposited on a hydrophobic silane monolayer. The ion-specific, nanoscale response of polyelectrolyte brushes was detected by using three-dimensional scanning force microscopy (3D-SFM) combined with frequency modulation detection. The obtained topographic and mechanical landscapes indicated that the brushes were uniformly stretched, undergoing a gradual transition from the brush to the bulk electrolyte in the absence of divalent cations. When 1 mM calcium ions were added, the brushes were uniformly compacted, exhibiting a sharper brush-to-bulk transition. Remarkably, the addition of 1 mM cadmium ions made the brush surface significantly rough and the mechanical landscape highly heterogeneous. Currently, cadmium-specific nanoscale compaction of the brushes is attributed to the coordination of thiol and carboxyl side chains with cadmium ions, as suggested for naturally occurring, heavy metal binding proteins
Production of an Amorphous Fe_<75>Si_<10>B_<15> Sheet by a Metallic Mold Casting Method and its Properties
The application of a metallic mold casting method to an Fe_Si_B_ alloy with the largest glass-forming ability in (Fe, Co, Ni)-Si-B system was found to cause the formation of a mostly single amorphous phase in a sheet form with a thickness of 0.1 mm. No distinct difference in thermal stability (crystallization temperature and heat of crystallization), hardness, Curie temperature and magnetization is detected between the as-cast sheet and the melt-spun amorphous ribbon with a thickness of 0.02 mm. On the other hand, bending ductility, heat of relaxation (ΔH_r) and coercivity (H_c) which can be regarded as structure sensitive properties are significantly different from those for the amorphous ribbon. That is, the sheet sample fractures during bending deformation and has a smaller ΔH_r and a larger H_c. The difference is induced presumably because the sheet sample has a more relaxed atomic configuration on a short-range scale as compared with that for the amorphous ribbon sample
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