Morphology and microstructure evolution of gold nanostructures in the limited volume porous matrices

The modern development of nanotechnology requires the discovery of simple approaches that ensure the controlled formation of functional nanostructures with a predetermined morphology. One of the simplest approaches is the self-assembly of nanostructures. The widespread implementation of self-assembly is limited by the complexity of controlled processes in a large volume where, due to the temperature, ion concentration, and other thermodynamics factors, local changes in diffusion-limited processes may occur, leading to unexpected nanostructure growth. The easiest ways to control the diffusion-limited processes are spatial limitation and localized growth of nanostructures in a porous matrix. In this paper, we propose to apply the method of controlled self-assembly of gold nanostructures in a limited pore volume of a silicon oxide matrix with submicron pore sizes. A detailed study of achieved gold nanostructures’ morphology, microstructure, and surface composition at different formation stages is carried out to understand the peculiarities of realized nanostructures. Based on the obtained results, a mechanism for the growth of gold nanostructures in a limited volume, which can be used for the controlled formation of nanostructures with a predetermined geometry and composition, has been proposed. The results observed in the present study can be useful for the design of plasmonic-active surfaces for surface-enhanced Raman spectroscopy-based detection of ultra-low concentration of different chemical or biological analytes, where the size of the localized gold nanostructures is comparable with the spot area of the focused laser beam. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.3.1.5.1Ministry of Education and Science of the Russian Federation, Minobrnauka: К-2018-036, N 211Russian Foundation for Fundamental Investigations, RFFI: 19-32-50058European Commission, ECMinistry of Science and Technology, MOSTFunding: This research was funded by H2020-MSCA-RISE2017-778308-SPINMULTIFILM Project, the scientific– technical program, ‘Technology-SG’ [project number 3.1.5.1], Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST «MISiS» [№ К-2018-036], implemented by a governmental decree dated 16th of March 2013, N 211 and Russian Foundation for Fundamental Investigations [project number 19-32-50058].Acknowledgments: D.V.Y. greatly acknowledges the World Federation of Scientists National Scholarship Program. E.Yu.K., D.V.Y., V.D.B., and V.S. greatly acknowledge the European Union program Mobility Scheme for Targeted People-to-People-Contacts (MOST) for supporting research visits

SRIM Simulation of Carbon Ions Interaction with Ni Nanotubes

By template synthesis method nickel nanotubes with diameter of 400 nm and length of 12 μm were produced in the pores of PET template. The nanotubes were modified by irradiation with carbon ions with energy of 28 MeV and a dose of 5 × 1011 cm-2. To ensure the maximum efficiency of nanostructures modification process, energy of irradiation was decided by using of SRIM software. Based on SRIM simulation of carbon ions interaction with Ni nanotubes, the areas on which effect of high energy ions will maximum were predicted. A comparative analysis of nanostructures before and after irradiation was carried out by scanning electron microscopy. The maximum change in nanotubes morphology, in the form of destruction of walls, was appeared at a distance of about 10 μm from the start point of C3+ ions track inside the nanotubes. A substantiation of reason of wall degradation in this area was proposed. © 2019 Elsevier Ltd.Horizon 2020 Framework Programme, H2020: 778308

Comprehensive Study of Ni Nanotubes for Bioapplications: From Synthesis to Payloads Attaching

Due to the Ni nanotubes’ shape anisotropy, low specific density, large specific surface, and uniform magnetic field, they have been offered as carriers for targeted delivery of drug or protein and the process of their formation from synthesis stage to the stage of surface modification and protein attaching has been demonstrated. Some steps to hasten their biomedical application have been applied. First, to have full control over the carrier dimensions and structure parameters, electrodeposition method in pores of polyethylene terephthalate template has been applied. Second, to understand the scope of Ni nanostructures application, their degradation in media with different acidity has been studied. Third, to improve the biocompatibility and to make payloads attachment possible, nanotubes surface modification with organosilicon compound has been carried out. At last, the scheme of protein attaching to the nanostructure surface has been developed and the binding process was demonstrated as an example of the bovine serum albumin

Degradation mechanism and way of surface protection of nickel nanostructures

Stability of nanomaterials during their life cycle is a crucial problem of modern nanoscience. In order to understand the processes, which are going in the nanostructures, the comprehensive study of the influence of media with different acidity on the nickel nanotubes morphology and structure was carried out. On the base of the analysis of nanotubes characteristics, sequential evolution of degradation stages involving the surface passivation, formation of point defects, pitting and destruction of nanotubes walls was determined. The results are of importance for the wide range of potential nickel nanostructures applications, which are associated with their using in real-life conditions. To improve Ni nanostructures stability, the possible ways of surface protections from the aggressive environment effect and the routes of nanostructures covering with gold, organosilicon compounds and polymer coatings were considered. Demonstrated approaches for nanostructures covering provide an opportunity of surface functionalization for attaching of different molecules. It is useful for targeted delivery of drugs and genes, biodetection, bioseparation and catalysis application. © 2018 Elsevier B.V

Formation and corrosion properties of Ni-based composite material in the anodic alumina porous matrix

Ni nanopillars (Ni NPs) composite material formation technology embedded in porous anodic alumina by electrochemical deposition is presented in this paper. The morphological and structural properties of the composite material were investigated using scanning electron microscopy, atomic force microscopy, X-ray diffraction. The corrosion resistance of the nanocomposite materials has been studied by potentiodynamic polarization curves analysis and polarization resistance method. The composite represents the array of vertically ordered Ni NPs with the identical size in alumina matrix. XRD investigation indicates that Ni NPs are polynanocrystalline material with 18 nm crystallite size. It has been shown that Ni NPs and the composite material have sufficient corrosion resistance in a 0.9% aqueous NaCl solution. Porous alumina is the neutral and protective component of the composite. These nanocomposite materials can be excellent candidates for practical use in electronics, sensorics, biomedicine