Cyano-Bridged Dy(III) and Ho(III) Complexes with Square-Wave Structure of the Chains

Four new cyano-bridged DyIII-CrIII, DyIII-FeIII, HoIII-CrIII and HoIII-FeIII bimetallic coordination polymers were synthesized by the reaction of [Ln(H2dapsc)(H2O)4](NO3)3 (Ln = Dy, Ho); H2dapsc = 2,6-diacetylpyridinebis(semicarbazone)) with K3[M(CN)6] (M = Cr, Fe) in H2O, resulting in the substitution of two water molecules in the coordination sphere of rare earth by paramagnetic tricharged hexacyanides of Fe and Cr. The complexes are isostructural and consist of alternating [Ln(H2dapsc)(H2O)2]3+ and [M(CN)6]3− units linked by bridges of two cis-cyano ligands of the anion to form square-wave chains. The ac magnetic measurements revealed that the DyCr and DyFe complexes are field-induced single molecule magnets, while their Ho analogs do not exhibit slow magnetic relaxation

A Series of Field-Induced Single-Ion Magnets Based on the Seven-Coordinate Co(II) Complexes with the Pentadentate (N3O2) H2dapsc Ligand

A series of five new mononuclear pentagonal bipyramidal Co(II) complexes with the equatorial 2,6-diacetylpyridine bis(semicarbazone) ligand (H2dapsc) and various axial pseudohalide ligands (SCN, SeCN, N(CN)2, C(CN)3, and N3) was prepared and structurally characterizated: [Co(H2dapsc)(SCN)2]∙0.5C2H5OH (1), [Co(H2dapsc)(SeCN)2]∙0.5C2H5OH (2), [Co(H2dapsc)(N(CN)2)2]∙2H2O (3), [Co(H2dapsc)(C(CN)3)(H2O)](NO3)∙1.16H2O (4), and {[Co(H2dapsc)(H2O)(N3)][Co(H2dapsc)(N3)2]}N3∙4H2O (5). The combined analyses of the experimental DC and AC magnetic data of the complexes (1–5) and two other earlier described those of this family [Co(H2dapsc)(H2O)2)](NO3)2∙2H2O (6) and [Co(H2dapsc)(Cl)(H2O)]Cl∙2H2O (7), their theoretical description and the ab initio CASSCF/NEVPT2 calculations reveal large easy-plane magnetic anisotropies for all complexes (D = + 35 − 40 cm−1). All complexes under consideration demonstrate slow magnetic relaxation with dominant Raman and direct spin–phonon processes at static magnetic field and so they belong to the class of field-induced single-ion magnets (SIMs)

New insights on frequency combinations and 'forbidden frequencies' in de Haas-van Alphen spectrum of κ-(ET) 2 Cu(SCN) 2

Accepted in Journal of Physics: Condensed Matter (2016)De Haas-van Alphen oscillations of the organic metal κ-(ET) 2 Cu(SCN) 2 have been measured up to 55 T at liquid helium temperatures. The Fermi surface of this charge transfer salt is a textbook example of linear chain of orbits coupled by magnetic breakdown. Accordingly, the oscillation spectrum is composed of linear combinations of the frequencies linked to the α and magnetic breakdown-induced β orbits. The field and temperature dependence of all the observed Fourier components, in particular the 'forbidden frequency' β − α which cannot correspond to a classical orbit, are quantitatively accounted for by analytical calculations based on a second order development of the free energy, i.e. beyond the first order Lifshitz-Kosevich formula

New insights on frequency combinations and forbidden frequencies in the de Haas-van Alphen spectrumof k-(ET)2 Cu(SCN)2

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New insights on frequency combinations and 'forbidden frequencies' in de Haas-van Alphen spectrum of κ-(ET) 2 Cu(SCN) 2

Accepted in Journal of Physics: Condensed Matter (2016)De Haas-van Alphen oscillations of the organic metal κ-(ET) 2 Cu(SCN) 2 have been measured up to 55 T at liquid helium temperatures. The Fermi surface of this charge transfer salt is a textbook example of linear chain of orbits coupled by magnetic breakdown. Accordingly, the oscillation spectrum is composed of linear combinations of the frequencies linked to the α and magnetic breakdown-induced β orbits. The field and temperature dependence of all the observed Fourier components, in particular the 'forbidden frequency' β − α which cannot correspond to a classical orbit, are quantitatively accounted for by analytical calculations based on a second order development of the free energy, i.e. beyond the first order Lifshitz-Kosevich formula

New insights on frequency combinations and 'forbidden frequencies' in de Haas-van Alphen spectrum of κ-(ET) 2 Cu(SCN) 2

Accepted in Journal of Physics: Condensed Matter (2016)De Haas-van Alphen oscillations of the organic metal κ-(ET) 2 Cu(SCN) 2 have been measured up to 55 T at liquid helium temperatures. The Fermi surface of this charge transfer salt is a textbook example of linear chain of orbits coupled by magnetic breakdown. Accordingly, the oscillation spectrum is composed of linear combinations of the frequencies linked to the α and magnetic breakdown-induced β orbits. The field and temperature dependence of all the observed Fourier components, in particular the 'forbidden frequency' β − α which cannot correspond to a classical orbit, are quantitatively accounted for by analytical calculations based on a second order development of the free energy, i.e. beyond the first order Lifshitz-Kosevich formula

Quantum oscillations in coupled orbits networks of (BEDT-TTF) salts with tris(oxalato) metallate anions

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