A Novel Method to Significantly Improve the Mechanical Properties of n-Type Bi(1−x)Sbx Thermoelectrics Due to Plastic Deformation

A unique method was developed to significantly improve the strength of Bi(1−x)Sbx single crystals, the most effective thermoelectric (TE) materials in the temperature range from 100 to 200 K due to their plastic deformation by extrusion. After plastic deformation at room temperature under all-round hydrostatic compression in a liquid medium, n-type Bi–Sb polycrystalline solid solutions show a significant increase in mechanical strength compared to Bi–Sb single crystals in the temperature range from 300 to 80 K. The significantly higher strength of extruded alloys in comparison with Bi–Sb single crystals is associated with the development of numerous grains with a high boundary surface as well as structural defects, such as dislocations, that accumulate at grain boundaries. Significant stability of the structure of extruded samples is achieved due to the uniformity of crystal plastic deformation under all-round hydrostatic compression and the formation of the polycrystalline structure consisting of grains with the orientation of the main crystallographic directions close to the original single crystal. The strengthening of Bi–Sb single crystals after plastic deformation allows for the first time to create workable TE devices that cannot be created on the basis of single crystals that have excellent TE properties, but low strength

A Novel Method to Significantly Improve the Mechanical Properties of <i>n</i>-Type Bi_{(1−<i>x</i>)}Sb<i>_x</i> Thermoelectrics Due to Plastic Deformation

A unique method was developed to significantly improve the strength of Bi(1−x)Sbx single crystals, the most effective thermoelectric (TE) materials in the temperature range from 100 to 200 K due to their plastic deformation by extrusion. After plastic deformation at room temperature under all-round hydrostatic compression in a liquid medium, n-type Bi–Sb polycrystalline solid solutions show a significant increase in mechanical strength compared to Bi–Sb single crystals in the temperature range from 300 to 80 K. The significantly higher strength of extruded alloys in comparison with Bi–Sb single crystals is associated with the development of numerous grains with a high boundary surface as well as structural defects, such as dislocations, that accumulate at grain boundaries. Significant stability of the structure of extruded samples is achieved due to the uniformity of crystal plastic deformation under all-round hydrostatic compression and the formation of the polycrystalline structure consisting of grains with the orientation of the main crystallographic directions close to the original single crystal. The strengthening of Bi–Sb single crystals after plastic deformation allows for the first time to create workable TE devices that cannot be created on the basis of single crystals that have excellent TE properties, but low strength

Development of a High Perfomance Gas Thermoelectric Generator (TEG) with Possibible Use of Waste Heat

A huge concern regarding global warming, as well as the depletion of natural fuel resources, has led to a wide search for alternative energy sources. Due to their high reliability and long operation time, thermoelectric generators are of significant interest for waste heat recovery and power generation. The main disadvantage of TEGs is the low efficiency of thermoelectric commercial modules. In this work, a unique design for a multilayer TE unicouple is suggested for an operating temperature range of 50–600 °C. Two types of thermoelectric materials were selected: «low temperature» n-and p-type TE materials (for the operating temperature range of 50–300 °C) based on Bi2Te3 compounds and «middle temperature» (for the operating temperature range of 300–600 °C) n- and p-type TE materials based on the PbTe compound. The hot extrusion technology was applied to fabricate n- and p-type low-temperature TE materials. A unique design of multilayer TEG was experienced to achieve an efficiency of up to 15%. This allows for the possibility of extracting this amount of electrical power from the heat generated for domestic and water heating

Effect of Surface Dissolution on Dislocation Activation in Stressed FeSi6.5 Steel

The effects of surface dissolution on dislocation activation in FeSi6.5 steel are quantitatively studied by analyzing the stress relaxation data using the thermal activation theory of dislocation. The stressed FeSi6.5 steel sample in acid solutions (H2SO4 or HCl) exhibits a much higher rate of stress reduction with time compared with that in air or deionized water. As the stress relaxation time is prolonged to 20 min, the relaxation rates are 0.055 MPa&middot;min&minus;1 in water and 0.074, 0.1, 0.11 MPa&middot;min&minus;1 in H2SO4 solutions with pH 4, 3, and 2, respectively. In a NaCl solution, a slight increase in the relaxation rate compared with air was found. Higher acidity (lower pH) of the solution inducing higher stress relaxation rate implies the softening is associated with the anodic dissolution of the surface layer and the accelerated (additional) flow of dislocations. The analyses using the thermal activation theory of dislocation during relaxation reveal the mechanism for the accelerated plastic flow induced by the corrosive medium. The variations of these parameters are related to the relaxation of the stress field of dislocations and the weakening of interaction between slip dislocations and short-range obstacles. The chemomechanical effect, including a reduction in apparent activation energy and a decrease in waiting time for dislocation to obtain sufficient thermal activation energy to cross obstacles, causes an increase in the stress relaxation rate (plastic strain rate). The study confirms that surface dissolution accelerates the plastic flow of metals and supports the view that surface dissolution facilitates dislocation slip. It is helpful to improve the formability of brittle metals