First-principles calculations of a high-pressure synthesized compound PtC

First-principles density-functional method is used to study the recently high-pressure synthesized compound PtC. It is confirmed by our calculations that the platinum carbide has a zinc-blende ground-state phase at zero pressure and the rock-salt structure is a high-pressure phase. The theoretical transition pressure from zinc-blende to rock-salt is determined to be 52GPa. Furthermore, our calculation shows the possibility that the experimentally synthesized PtC by Ono et al. under high pressure condition might undergo a transition from rock-salt structure to zinc-blende after the pressure quench to ambient condition.Comment: A revised versio

Out of plane effect on the superconductivity of Sr2-xBaxCuO3+y with Tc up to 98K

A series of new Sr2-xBaxCuO3+y (0 x 0.6) superconductors were prepared using high-pressure and high-temperature synthesis. A Rietveld refinement based on powder x-ray diffraction confirms that the superconductors crystallize in the K2NiF4-type structure of a space group I4/mmm similar to that of La2CuO4 but with partially occupied apical oxygen sites. It is found that the superconducting transition temperature Tc of this Ba substituted Sr2CuO3+y superconductor with constant carrier doping level, i.e., constant d, is controlled not only by order/disorder of apical-O atoms but also by Ba content. Tcmax =98 K is achieved in the material with x=0.6 that reaches the record value of Tc among the single-layer copper oxide superconductors, and is higher than Tc=95K of Sr2CuO3+y with optimally ordered apical-O atoms. There is Sr-site disorder in Sr2-xBaxCuO3+y which might lead to a reduction of Tc. The result indicates that another effect surpasses the disorder effect that is related either to the increased in-plane Cu-O bond length or to elongated apical-O distance due to Ba substitution with larger cation size. The present experiment demonstrates that the optimization of local geometry out of the Cu-O plane can dramatically enhance Tc in the cuprate superconductors.Comment: 23 Pages, 1 Table, 5 Figure

Observation of Andreev Surface Bound States in the 3-K phase Region of Sr_2RuO_4

The tunneling spectrum of the superconducting phase with T_c ~ 3.0 K has been measured in the Ru-embedded region of Sr_2RuO_4 using cleaved junctions. A sharp zero-bias conductance peak (ZBCP) has been observed below 3 K. All characteristics of this ZBCP suggest that it originates from Andreev surface bound states, indicating that the pairing in the 3-K phase is also non-s-wave. Below the bulk T_c of Sr_2RuO_4 (~1.5 K), a bell-shaped ZBCP was found. This supports that there is a phase transition in the 3-K phase region near the bulk T_c.Comment: 4 pages, to appear in Phys. Rev. Lett. 87 (2001

Optical properties of MgCNi3MgCNi_3 in the normal state

We present the optical reflectance and conductivity spectra for non-oxide antiperovskite superconductor $MgCNi_{3}$ at different temperatures. The reflectance drops gradually over a large energy scale up to 33,000 cm$^{-1}$, with the presence of several wiggles. The reflectance has slight temperature dependence at low frequency but becomes temperature independent at high frequency. The optical conductivity shows a Drude response at low frequencies and four broad absorption features in the frequency range from 600 $cm^{-1}$ to 33,000 $cm^{-1}$. We illustrate that those features can be well understood from the intra- and interband transitions between different components of Ni 3d bands which are hybridized with C 2p bands. There is a good agreement between our experimental data and the first-principle band structure calculations.Comment: 4 pages, to be published in Phys. Rev.

Feasibility Study of Tractor-Test Vehicle Technique for Practical Structural Condition Assessment of Beam-Like Bridge Deck

The tractor-test vehicle technique of non-destructive testing for indirect measurement of the modal properties of a bridge deck is revisited in this paper with several improvements for possible practical application to the structural condition assessment of a beam-like bridge deck. The effect of damping of the vehicle-bridge system is considered and the modal properties from only the first vibration mode of the structure will be used for a quick and simple assessment. The two test vehicles are designed to have the same modal frequency and damping ratio but with parameters in the follower No.2 test vehicle proportional to those in the follower No.1 test vehicle. This effectively removes the effect of road surface roughness in the response of an equivalent vehicle such that the error in the subsequent condition assessment is reduced. Through data collected on-site transmitted to the remote computer platform, a simple technique based on the moment-curvature relationship acceptable to practical engineers is adopted for the condition assessment with improvements in the estimation of the element bending stiffness of the deck. Scenarios with different damping, vehicle speed, road surface roughness, and local damages in the bridge structure are studied with or without temperature effect in the measurement. Through numerical simulations and field tests, the tractor-test vehicle technique of non-destructive testing with the proposed modifications and improvements has been demonstrated to give consistently accurate estimates of the element bending stiffness of the bridge deck but with a small error close to the end of the deck