155 research outputs found
Photoemission evidence for a Mott-Hubbard metal-insulator transition in VO
The temperature () dependent metal-insulator transition (MIT) in VO is
investigated using bulk sensitive hard x-ray ( 8 keV) valence band, core
level, and V 2 resonant photoemission spectroscopy (PES). The valence
band and core level spectra are compared with full-multiplet cluster model
calculations including a coherent screening channel. Across the MIT, V 3
spectral weight transfer from the coherent ( final)
states at Fermi level to the incoherent ( final)
states, corresponding to the lower Hubbard band, lead to gap-formation. The
spectral shape changes in V 1 and V 2 core levels as well as the valence
band are nicely reproduced from a cluster model calculations, providing
electronic structure parameters. Resonant-PES finds that the
states resonate across the V 2 threshold in
addition to the and states. The results support
a Mott-Hubbard transition picture for the first order MIT in VO.Comment: 6 pages, 3 figures. to be published in Phys. Rev.
Evidence for mass renormalization in LaNiO$"" sub 3_: an in situ soft x-ray photoemission study of epitaxial films
We investigate the electronic structure of high-quality single-crystal
LaNiO (LNO) thin films using in situ photoemission spectroscopy (PES). The
in situ high-resolution soft x-ray PES measurements on epitaxial thin films
reveal the intrinsic electronic structure of LNO. We find a new sharp feature
in the PES spectra crossing the Fermi level, which is derived from the
correlated Ni 3 electrons. This feature shows significant enhancement
of spectral weight with decreasing temperature. From a detailed analysis of
resistivity data, the enhancement of spectral weight is attributed to
increasing electron correlations due to antiferromagnetic fluctuations.Comment: 4 pages, 4 figures. submitted to Phys. Rev.
Giant Rashba splitting of quasi-1D surface states on Bi/InAs(110)-(21)
Electronic states on the Bi/InAs(110)-(21) surface and its
spin-polarized structure are revealed by angle-resolved photoelectron
spectroscopy (ARPES), spin-resolved ARPES, and density-functional-theory
calculation. The surface state showed quasi-one-dimensional (Q1D) dispersion
and a nearly metallic character; the top of the hole-like surface band is just
below the Fermi level. The size of the Rashba parameter ()
reached quite a large value (5.5 eV\AA). The present result would provide
a fertile playground for further studies of the exotic electronic phenomena in
1D or Q1D systems with the spin-split electronic states as well as for advanced
spintronic devices.Comment: 8 pages (double column), 7 figures and 1 tabl
Recoil effects of photoelectrons in a solid
High energy resolution C 1 photoelectron spectra of graphite were measured
at the excitation energy of 340, 870, 5950 and 7940eV using synchrotron
radiation. On increasing the excitation energy, i.e., increasing kinetic energy
of the photoelectron, the bulk origin C 1 peak position shifts to higher
binding energies. This systematic shift is due to the kinetic energy loss of
the high-energy photoelectron by kicking the atom, and is clear evidence of the
recoil effect in photoelectron emission. It is also observed that the
asymmetric broadening increases for the higher energy photoelectrons. All these
recoil effects can be quantified in the same manner as the M\"ossbauer effect
for -ray emission from nuclei embedded in crystals.Comment: 4 pages, 2 figure
Temperature dependent Eu 3d-4f X-ray Absorption and Resonant Photoemission Study of the Valence Transition in
We study the mixed valence transition ( 80 K) in
EuNi(SiGe) using Eu 3 X-ray absorption
spectroscopy (XAS) and resonant photoemission spectroscopy (RESPES). The
Eu and Eu main peaks show a giant resonance and the spectral
features match very well with atomic multiplet calculations. The spectra show
dramatic temperature ()-dependent changes over large energies (10 eV)
in RESPES and XAS. The observed non-integral mean valencies of 2.35
0.03 ( = 120 K) and 2.70 0.03 ( = 40 K) indicate homogeneous
mixed valence above and below . The redistribution between
Eu+ and Eu+ states is attributed to
a hybridization change coupled to a Kondo-like volume collapse.Comment: 4 pages, 3 figure
- …