Preparation of a Ni-P-nanoPTFE Composite Coating on the Surface of GCr15 Steel for Spinning Rings via a Defoamer and Transition Layer and Its Wear and Corrosion Resistance

In this study, a method of preparing a Ni-P-nanoPTFE composite coating on the surface of GCr15 steel for spinning rings is proposed. The method incorporates a defoamer into the plating solution to inhibit the agglomeration of nano-PTFE particles and pre-deposits a Ni-P transition layer to reduce the possibility of leakage coating. Meanwhile, the effect of varying the PTFE emulsion content in the bath on the micromorphology, hardness, deposition rate, crystal structure, and PTFE content of the composite coatings was investigated. The wear and corrosion resistances of the GCr15 substrate, Ni-P coating, and Ni-P-nanoPTFE composite coating are compared. The results show that the composite coating prepared at a PTFE emulsion concentration of 8 mL/L has the highest concentration of PTFE particles (up to 2.16 wt%). Additionally, its wear resistance and corrosion resistance are improved compared with Ni-P coating. The friction and wear study shows that the nano-PTFE particles with low dynamic friction coefficient are mixed in the grinding chip, which gives the composite coating self-lubricating characteristics, and the friction coefficient decreases to 0.3 compared with 0.4 of Ni-P coating. The corrosion study shows that the corrosion potential of the composite coating has increased by 7.6% compared with that of the Ni-P coating, which shifts from −456 mV to a more positive value of −421 mV. The corrosion current reduces from 6.71 μA to 1.54 μA, which is a 77% reduction. Meanwhile, the impedance increased from 5504 Ω·cm2 to 36,440 Ω·cm2, which is an increase of 562%

Fabrication and application of molecularly imprinted polymer doped carbon dots coated silica stationary phase

Facing the difficulties in chromatographic separation of polar compounds, this investigation devotes to developing novel stationary phase. Molecularly imprinted polymers (MIPs) have aroused wide attention, owing to their outstanding selectivity, high stability, and low cost. In this work, a novel stationary phase based on carbon dots (CDs), MIP layer, and silica beads was synthesized to exploit high selectivity of MIPs, excellent physicochemical property of CDs, and outstanding chromatographic performances of silica microspheres simultaneously. The MIP doped CDs coated silica (MIP-CDs/SiO2) stationary phase was systematically characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area measurement, and carbon elemental analysis. Furthermore, the chromatographic performance of the MIP-CDs/SiO2 column was thoroughly assessed by using a wide variety of compounds (including nucleosides, sulfonamides, benzoic acids, and some other antibiotics). Meanwhile, the separation efficiency of the MIP-CDs/SiO2 stationary phase was superior to other kinds of stationary phases (e.g. nonimprinted NIP-CDs/SiO2, MIP/SiO2, and C18-SiO2). The results demonstrated that MIP-CDs/SiO2 column exhibited best performance in terms of chromatographic separation. For all tested compounds, the resolution value was not less than 1.60, and the column efficiency of MIP-CDs/SiO2 for thymidine was 22,740 plates/m. The results further indicate that the MIP-CDs/SiO2 column can combine the good properties of MIP, CDs, with those of silica microbeads. Therefore, the developed MIP-CDs/SiO2 stationary phase can be applied in the separation science and chromatography-based techniques

The 2022 report of synergetic roadmap on carbon neutrality and clean air for China: Accelerating transition in key sectors

China is now confronting the intertwined challenges of air pollution and climate change. Given the high synergies between air pollution abatement and climate change mitigation, the Chinese government is actively promoting synergetic control of these two issues. The Synergetic Roadmap project was launched in 2021 to track and analyze the progress of synergetic control in China by developing and monitoring key indicators. The Synergetic Roadmap 2022 report is the first annual update, featuring 20 indicators across five aspects: synergetic governance system and practices, progress in structural transition, air pollution and associated weather-climate interactions, sources, sinks, and mitigation pathway of atmospheric composition, and health impacts and benefits of coordinated control. Compared to the comprehensive review presented in the 2021 report, the Synergetic Roadmap 2022 report places particular emphasis on progress in 2021 with highlights on actions in key sectors and the relevant milestones. These milestones include the proportion of non-fossil power generation capacity surpassing coal-fired capacity for the first time, a decline in the production of crude steel and cement after years of growth, and the surging penetration of electric vehicles. Additionally, in 2022, China issued the first national policy that synergizes abatements of pollution and carbon emissions, marking a new era for China's pollution-carbon co-control. These changes highlight China's efforts to reshape its energy, economic, and transportation structures to meet the demand for synergetic control and sustainable development. Consequently, the country has witnessed a slowdown in carbon emission growth, improved air quality, and increased health benefits in recent years