Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN 1}cobalt(II)

In the structure of the title compound, [CoCl2(C9H16N2Si)2], the CoII atom is located on an inversion center in a slightly distorted tetra­hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl­silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H⋯Cl hydrogen bonds

Unveiling the green path:How urban openness reduces pollution and paves the way to sustainability

This study investigates the relationship between openness and pollutant emission intensity across 286 Chinese cities from 1990 to 2019, aiming to evaluate the potential environmental benefits of open economy strategies. The findings indicate that enhanced urban openness significantly lowers pollutant emission intensity. To ensure the robustness of our findings, we make an innovative attempt to employ high-speed rail connection and motorway density as instrumental variables to address potential endogeneity issues, corroborating the reliability of the results through various robustness tests. Moreover, we also find the heterogeneous effects of urban openness on pollution emissions, highlighting the moderating influences of trade complexity, urbanization level, and environmental regulatory intensity. Lastly, the study elucidates the mechanisms through which urban openness diminishes pollution emissions, namely fostering green innovation capacity and enhancing public environmental awareness. This research makes theoretical contributions on understanding the nexus between open economies and environmental protection while offering practical insights to inform governmental environmental policy formulation.</p

Optimizing Bacillus circulans Xue-113168 for biofertilizer production and its effects on crops

In this study, Bacillus circulans Xue-113168 biofertilizer was produced through solid state fermentation processes using food waste and feldspar. Results confirmed that solid state fermentation has considerable advantages compared to complex process (solid-state and bio-bleach). The control of pH, temperature, and humidity effectively led to the formation of 2×109 cfu/g spore and dissolution of potassium at a rate of 41.53%. Compound microbial fertilizer (CMF), formulated by humic acid and K2HPO4 with biofertilizer, has a quick and durable effect. CMF increases the yield of rapeseeds by 75 to 89%, provides higher vitamin C and reduces nitrate in leaf. Yields of selenium-enriched jujube and jujube increased, respectively, in the CMF compared to the matrix control; rates of anthracnose and rust diseases also decreased. Furthermore, our results showed that CMF improved soil properties, such as organic matter, NPK content from 8.83 to 16.16 kg hm2, and reduced chemical fertilizer from 25 to 11%, respectively. For convenient medium, robust process and good effect, CMF is suitable for potassium deficiency and undeveloped arable land resources.Keywords: compound microbial fertilizer, Bacillus circulans Xue-113168, solid-state fermentation (SSF), process, optimiz

One-shot ultraspectral imaging with reconfigurable metasurfaces

One-shot spectral imaging that can obtain spectral information from thousands of different points in space at one time has always been difficult to achieve. Its realization makes it possible to get spatial real-time dynamic spectral information, which is extremely important for both fundamental scientific research and various practical applications. In this study, a one-shot ultraspectral imaging device fitting thousands of micro-spectrometers (6336 pixels) on a chip no larger than 0.5 cm$^2$, is proposed and demonstrated. Exotic light modulation is achieved by using a unique reconfigurable metasurface supercell with 158400 metasurface units, which enables 6336 micro-spectrometers with dynamic image-adaptive performances to simultaneously guarantee the density of spectral pixels and the quality of spectral reconstruction. Additionally, by constructing a new algorithm based on compressive sensing, the snapshot device can reconstruct ultraspectral imaging information ($\Delta\lambda$/$\lambda$~0.001) covering a broad (300-nm-wide) visible spectrum with an ultra-high center-wavelength accuracy of 0.04-nm standard deviation and spectral resolution of 0.8 nm. This scheme of reconfigurable metasurfaces makes the device can be directly extended to almost any commercial camera with different spectral bands to seamlessly switch the information between image and spectral image, and will open up a new space for the application of spectral analysis combining with image recognition and intellisense

Improving Distantly-Supervised Named Entity Recognition with Self-Collaborative Denoising Learning

Distantly supervised named entity recognition (DS-NER) efficiently reduces labor costs but meanwhile intrinsically suffers from the label noise due to the strong assumption of distant supervision. Typically, the wrongly labeled instances comprise numbers of incomplete and inaccurate annotation noise, while most prior denoising works are only concerned with one kind of noise and fail to fully explore useful information in the whole training set. To address this issue, we propose a robust learning paradigm named Self-Collaborative Denoising Learning (SCDL), which jointly trains two teacher-student networks in a mutually-beneficial manner to iteratively perform noisy label refinery. Each network is designed to exploit reliable labels via self denoising, and two networks communicate with each other to explore unreliable annotations by collaborative denoising. Extensive experimental results on five real-world datasets demonstrate that SCDL is superior to state-of-the-art DS-NER denoising methods.Comment: EMNLP (12 pages, 4 figures, 6 tables

Replication of the Association of a MET Variant with Autism in a Chinese Han Population

Background: Autism is a common, severe and highly heritable neurodevelopmental disorder in children, affecting up to 100 children per 10,000. The MET gene has been regarded as a promising candidate gene for this disorder because it is located within a replicated linkage interval, is involved in pathways affecting the development of the cerebral cortex and cerebellum in ways relevant to autism patients, and has shown significant association signals in previous studies. Principal Findings: Here, we present new ASD patient and control samples from Heilongjiang, China and use them in a case-control and family-based replication study of two MET variants. One SNP, rs38845, was successfully replicated in a case-control association study, but failed to replicate in a family-based study, possibly due to small sample size. The other SNP, rs1858830, failed to replicate in both case-control and family-based studies. Conclusions: This is the first attempt to replicate associations in Chinese autism samples, and our result provides evidence that MET variants may be relevant to autism susceptibility in the Chinese Han population