Hierarchical quantum master equation with semiclassical Drude dissipation

We propose a nonperturbative quantum dissipation theory, in term of hierarchical quantum master equation. It may be used with a great degree of confidence to various dynamics systems in condensed phases. The theoretical development is rooted in an improved semiclassical treatment of Drude bath, beyond the conventional high temperature approximations. It leads to the new theory a simple modification but important improvement over the conventional stochastic Liouville equation theory, without extra numerical cost. Its broad range of validity and applicability is extensively demonstrated with two--level electron transfer model systems, where the new theory can be considered as the modified Zusman equation. We also present a criterion, which depends only on the system--bath coupling strength, characteristic bath memory time, and temperature, to estimate the performance of the hierarchical quantum master equation.Comment: 10 pages, 8 figures, submitted to J. Chem. Phys. on 2009-08-0

Efficient infrared upconversion via a ladder-type atomic configuration

We have demonstrated experimentally that infrared light at 1529.4nm can be converted into the visible at 780nm with 54% efficiency through a ladder-type atomic configuration in 85Rb. Specifically we theoretically analyze that high efficiency is due to the large nonlinear dispersion of the index of refraction from the off-resonant enhancement in a four-wave mixing (FWM) process. By using two perpendicular polarized pump fields, the coherence of two FWM processes in this configuration is verified.Comment: The new version is published in Journal of Modern Optic