Tunable Unidirectional Sound Propagation through a Sonic-Crystal-Based Acoustic Diode

Nonreciprocal wave propagation typically requires strong nonlinear materials to break time reversal symmetry. Here, we utilized a sonic-crystal-based acoustic diode that had broken spatial inversion symmetry and experimentally realized sound unidirectional transmission in this acoustic diode. These novel phenomena are attributed to different mode transitions as well as their associated different energy conversion efficiencies among different diffraction orders at two sides of the diode. This nonreciprocal sound transmission could be systematically controlled by simply mechanically rotating the square rods of the sonic crystal. Different from nonreciprocity due to the nonlinear acoustic effect and broken time reversal symmetry, this new model leads to a one-way effect with higher efficiency, broader bandwidth, and much less power consumption, showing promising applications in various sound devices

N′-[6-(3,5-Dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetra­zin-3-yl]butano­hydrazide

In the title compound, C11H16N8O, the tetra­zine and pyrazole rings form a dihedral angle of 48.75 (2)°. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the mol­ecules into layers parallel to (101)

Nonadiabatic molecular dynamics simulation: An approach based on quantum measurement picture

Mixed-quantum-classical molecular dynamics simulation implies an effective measurement on the electronic states owing to continuously tracking the atomic forces.Based on this insight, we propose a quantum trajectory mean-field approach for nonadiabatic molecular dynamics simulations. The new protocol provides a natural interface between the separate quantum and classical treatments, without invoking artificial surface hopping algorithm. Moreover, it also bridges two widely adopted nonadiabatic dynamics methods, the Ehrenfest mean-field theory and the trajectory surface-hopping method. Excellent agreement with the exact results is illustrated with representative model systems, including the challenging ones for traditional methods