2,072 research outputs found
Study of Ni Metallization in Macroporous Si Using Wet Chemistry for Radio Frequency Cross-Talk Isolation in Mixed Signal Integrated Circuits.
A highly conductive moat or Faraday cage of through-the-wafer thickness in Si substrate was proposed to be effective in shielding electromagnetic interference thereby reducing radio frequency (RF) cross-talk in high performance mixed signal integrated circuits. Such a structure was realized by metallization of selected ultra-high-aspect-ratio macroporous regions that were electrochemically etched in p- Si substrates. The metallization process was conducted by means of wet chemistry in an alkaline aqueous solution containing Ni2+ without reducing agent. It is found that at elevated temperature during immersion, Ni2+ was rapidly reduced and deposited into macroporous Si and a conformal metallization of the macropore sidewalls was obtained in a way that the entire porous Si framework was converted to Ni. A conductive moat was as a result incorporated into p- Si substrate. The experimentally measured reduction of crosstalk in this structure is 5~18 dB at frequencies up to 35 GHz
Evaluating remotely sensed phenological metrics in a dynamic ecosystem model
© The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Remote Sensing 6 (2014): 4660-4686, doi:10.3390/rs6064660.Vegetation phenology plays an important role in regulating processes of terrestrial ecosystems. Dynamic ecosystem models (DEMs) require representation of phenology to simulate the exchange of matter and energy between the land and atmosphere. Location-specific parameterization with phenological observations can potentially improve the performance of phenological models embedded in DEMs. As ground-based phenological observations are limited, phenology derived from remote sensing can be used as an alternative to parameterize phenological models. It is important to evaluate to what extent remotely sensed phenological metrics are capturing the phenology observed on the ground. We evaluated six methods based on two vegetation indices (VIs) (i.e., Normalized Difference Vegetation Index and Enhanced Vegetation Index) for retrieving the phenology of temperate forest in the Agro-IBIS model. First, we compared the remotely sensed phenological metrics with observations at Harvard Forest and found that most of the methods have large biases regardless of the VI used. Only two methods for the leaf onset and one method for the leaf offset showed a moderate performance. When remotely sensed phenological metrics were used to parameterize phenological models, the bias is maintained, and errors propagate to predictions of gross primary productivity and net ecosystem production. Our results show that Agro-IBIS has different sensitivities to leaf onset and offset in terms of carbon assimilation, suggesting it might be better to examine the respective impact of leaf onset and offset rather than the overall impact of the growing season length
Molecular Lines of 13 Galactic Infrared Bubble Regions
We investigated the physical properties of molecular clouds and star
formation processes around infrared bubbles which are essentially expanding HII
regions. We performed observations of 13 galactic infrared bubble fields
containing 18 bubbles. Five molecular lines, 12CO (J=1-0), 13CO (J=1-0),
C18O(J=1-0), HCN (J=1-0), and HCO+ (J=1-0), were observed, and several publicly
available surveys, GLIMPSE, MIPSGAL, ATLASGAL, BGPS, VGPS, MAGPIS, and NVSS,
were used for comparison. We find that these bubbles are generally connected
with molecular clouds, most of which are giant. Several bubble regions display
velocity gradients and broad shifted profiles, which could be due to the
expansion of bubbles. The masses of molecular clouds within bubbles range from
100 to 19,000 solar mass, and their dynamic ages are about 0.3-3.7 Myr, which
takes into account the internal turbulence pressure of surrounding molecular
clouds. Clumps are found in the vicinity of all 18 bubbles, and molecular
clouds near four of these bubbles with larger angular sizes show shell-like
morphologies, indicating that either collect-and-collapse or radiation-driven
implosion processes may have occurred. Due to the contamination of adjacent
molecular clouds, only six bubble regions are appropriate to search for
outflows, and we find that four of them have outflow activities. Three bubbles
display ultra-compact HII regions at their borders, and one of them is probably
responsible for its outflow. In total, only six bubbles show star formation
activities in the vicinity, and we suggest that star formation processes might
have been triggered.Comment: 55 Pages, 32 figures. Accepted for publication in A
3′,6′-Bis(ethylÂamino)-2′,7′-dimethyl-2-{2-(E)-[(thioÂphen-2-yl)methylÂideneÂamino]ÂethÂyl}spiroÂ[isoindoline-1,9′-xanthen]-3-one methanol monosolvate
The title compound, C33H34N4O2S·CH3OH, was prepared as a spiroÂlactam ring formation of rhodamine 6 G dye for comparison with a ring-opened form. The xanthene and spiroÂlactam rings are approximately planar [r.m.s. deviations from planarity = 0.122 (3) and 0.072 (6) Å, respectively]. The dihedral angles formed by the spiroÂlactam and thioÂphene rings with the xanthene ring system are 89.7 (6) and 86.5 (2)°, respectively. The crystal structure features N—H⋯O and C—H⋯O hydrogen bonds
- …