787 research outputs found
A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
In the title compound, C13H14N2O, the Npyrrole—C(H2)—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules into chains extending along the c axis. We have previously reported another polymorphic form of this title compound, which has the same space group with different cell parameters: a = 9.8285 (18) Å, b = 23.588 (4) Å, c = 9.9230 (17) Å, β = 90.107 (3)°, Z = 8 and V = 2300.5 (7) Å3 [Zeng et al. (2010 ▶). Acta Cryst. E66, o2051]
rac-Dimethyl 2-(1H-pyrrole-2-carboxamido)butanedioate
The title compound, C11H14N2O5, was synthesized by condensation of (RS)-2-aminosuccinic acid dimethyl ester with 2-trichloroacetylpyrrole at room temperature. The amide group is twisted by 7.4 (1)° from the plane of the pyrrole ring. In the crystal, molecules are linked by intermolecular N—H⋯O hydrogen bonds into chains extending along the c axis
Adversarial Multimodal Representation Learning for Click-Through Rate Prediction
For better user experience and business effectiveness, Click-Through Rate
(CTR) prediction has been one of the most important tasks in E-commerce.
Although extensive CTR prediction models have been proposed, learning good
representation of items from multimodal features is still less investigated,
considering an item in E-commerce usually contains multiple heterogeneous
modalities. Previous works either concatenate the multiple modality features,
that is equivalent to giving a fixed importance weight to each modality; or
learn dynamic weights of different modalities for different items through
technique like attention mechanism. However, a problem is that there usually
exists common redundant information across multiple modalities. The dynamic
weights of different modalities computed by using the redundant information may
not correctly reflect the different importance of each modality. To address
this, we explore the complementarity and redundancy of modalities by
considering modality-specific and modality-invariant features differently. We
propose a novel Multimodal Adversarial Representation Network (MARN) for the
CTR prediction task. A multimodal attention network first calculates the
weights of multiple modalities for each item according to its modality-specific
features. Then a multimodal adversarial network learns modality-invariant
representations where a double-discriminators strategy is introduced. Finally,
we achieve the multimodal item representations by combining both
modality-specific and modality-invariant representations. We conduct extensive
experiments on both public and industrial datasets, and the proposed method
consistently achieves remarkable improvements to the state-of-the-art methods.
Moreover, the approach has been deployed in an operational E-commerce system
and online A/B testing further demonstrates the effectiveness.Comment: Accepted to WWW 2020, 10 page
2-Iodo-5-nitrothiophene
The title compound, C4H2INO2S, was synthesized by nitration of iodothiophene with acetyl nitrate. The molecule is essentially planar, withthe nitro group tilted by 1.78 (19)° and the iodine atom displaced by 0.0233 (2) Å with respect to the thiophene ring. In the crystal structure, adjacent molecules are linked through weak I⋯O interactions [3.039 (2)Å], forming chains extending along the b axis
1H-Pyrrole-2-carboxylic acid
In the title compound, C5H5NO2, the pyrrole ring and its carboxyl substituent are close to coplanar, with a dihedral angle of 11.7 (3)° between the planes. In the crystal structure, adjacent molecules are linked by pairs of O—H⋯O hydrogen bonds to form inversion dimers. Additional N—H⋯O hydrogen bonds link these dimers into chains extending along the a axis
Methyl 3-[(1-butyl-1H-indol-3-yl)carbonylamino]propionate
In the title molecule, C17H22N2O3, the mean plane of the terminal (C=O)OMe fragment and the indole plane form a dihedral angle of 78.94 (3)°. Intermolecular N—H⋯O hydrogen bonds link the molecules into chains extended along the c axis. The crystal packing exhibits π–π interactions, indicated by the short distance of 3.472 (2) Å between the centroids of the five-membered heterocycles of neighbouring molecules
1-Ethyl-1H,6H-pyrrolo[2,3-c]azepine-4,8(5H,7H)-dione
The title compound, C10H12N2O2, was synthesized by cyclization of 3-(1-ethylpyrrole-2-carboxamido)propanoic acid in the presence of polyphosphoric acid and diphosphorus pentoxide. In the crystal structure, adjacent molecules are linked by N—H⋯O hydrogen bonds, forming chains extending along the b axis
Methyl (1H-pyrrol-2-ylcarbonylamino)acetate
In the crystal structure of the title compound, C8H10N2O3, molecules are linked by N—H⋯O hydrogen bonds, forming ribbons of centrosymmetric dimers extending along the c axis
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