Photoionization of the Ne-like Si4+ ion in ground and metastable states in the 110–184-eV photon energy range

We present measurements of the absolute photoionization cross section of the neonlike Si4+ ion over the 110–184 eV photon energy range. The measurements were performed using two independent merged-beam setups at the super-ACO and ASTRID synchrotron-radiation facilities, respectively. Signals produced in the photoionization of the 2p subshell of the Si4+ ion both from the 2p6 1S0 ground state and the 2p53s 3P0,2 metastable levels were observed. Calculations of the 2p photoionization cross sections were carried out using a multi-configuration Dirac-Fock code. They give results in good agreement with the measured spectra. Comparison with other available theoretical results is also presented

Experimental observation and theoretical calculations of rydberg series in hollow lithium atomic states

Several extended Rydberg series have been experimentally identified in triply excited states of hollow lithium, by use of electron spectrometry and synchrotron radiation at the Advanced Light Source. Energies, partial cross sections, and quantum defects have also been calculated using the R-matrix approximation. Our results show that the two inner electrons stay in a core-excited state of given symmetry while the behavior of the third electron is mostly governed by the nuclear potential screened by the two inner electrons

Absolute photoionization cross sections and resonance structure of doubly ionized silicon in the region of the 2p-1 threshold: experiment and theory

We present the absolute photoionization cross section of doubly ionized silicon as a function of photon energy. These were obtained by merging a Si2+ ion beam generated in an electron cyclotron resonance source with monochromatized synchrotron radiation from an undulator. The photoion yield measurements were carried out in the photon energy range between 95 eV and 170 eV, i.e., the region corresponding to the excitation followed by the ionization (threshold ∼133.8eV) of an inner-subshell 2p electron. Resonance structure due to 2p excitation in the 2p63s3p3P metastable state was also observed with its contribution to the total cross section not exceeding 3%. Calculation of the 2p photoionization continuum cross section as a function of photon energy was carried out using the relativistic random-phase approximation (RRPA) and agreed very well with the corresponding measurements. The resonance structure in the 3s cross section below the 2p threshold was found to be in good agreement with the multiconfiguration atomic structure calculations of Sayyad et al. [J. Phys. B 28, 1715 (1995)], while the corresponding RRPA-RMQDT (relativistic multi-channel quantum-defect theory) calculations proved less successful

Photoelectron spectroscopy measurements and theoretical calculations of the lowest doubly hollow lithium state

We have measured, using electron spectroscopy, the lowest-energy doubly hollow lithium triply excited (3l3l′3l″) 2P state. Energies, widths, and partial cross sections have been measured and calculated using the saddle-point technique and the R-matrix approximation. Our results show good agreement between experimental and theoretical data for the energy and the width of the doubly hollow state

Strong-field control of x-ray absorption

Strong optical laser fields modify the way x rays interact with matter. This allows us to use x rays to gain deeper insight into strong-field processes. Alternatively, optical lasers may be utilized to control the propagation of x rays through a medium. Gas-phase systems are particularly suitable for illustrating the basic principles underlying combined x-ray and laser interactions. Topics addressed include the impact of spin-orbit interaction on the alignment of atomic ions produced in a strong laser field, electromagnetically induced transparency in the x-ray regime, and laser-induced alignment of molecules.Comment: 8 pages, 5 figures, 1 table, LaTe

The transition from the adiabatic to the sudden limit in core level photoemission: A model study of a localized system

We consider core electron photoemission in a localized system, where there is a charge transfer excitation. The system is modelled by three electron levels, one core level and two outer levels. The model has a Coulomb interaction between these levels and the continuum states into which the core electron is emitted. The model is simple enough to allow an exact numerical solution, and with a separable potential an analytic solution. We calculate the ratio r(omega) between the weights of the satellite and the main peak as a function of the photon energy omega. The transition from the adiabatic to the sudden limit takes place for quite small photoelectron kinetic energies. For such small energies, the variation of the dipole matrix element is substantial and described by the energy scale Ed. Without the coupling to the photoelectron, the corresponding ratio r0(omega) is determined by Ed and the satellite excitation energy dE. When the interaction potential with the continuum states is introduced, a new energy scale Es=1/(2Rs^2) enters, where Rs is a length scale of the interaction potential. At threshold there is typically a (weak) constructive interference between intrinsic and extrinsic contributions, and the ratio r(omega)/r0(omega) is larger than its limiting value for large omega. The interference becomes small or weakly destructive for photoelectron energies of the order Es. For larger energies r(omega)/r0(omega) therefore typically has a weak undershoot. If this undershoot is neglected, r(omega)/r0(omega) reaches its limiting value on the energy scale Es.Comment: 18 pages, latex2e, 13 eps figure

Anomalous behavior of the near-threshold photoionization cross section of the neon isoelectronic sequence: a combined experimental and theoretical study

We present a combined theoretical and experimental investigation of photoionization along the Ne isoelectronic sequence and show that the near-threshold behavior of the cross section for Si4+ differs radically from the nearby ions in the sequence. We demonstrate that the general nature of the underlying physics implies that dramatic changes in near-threshold behavior may be expected for many other ions

Even-parity autoionizing states in the extreme-ultraviolet photoabsorption spectra of Mg, Al⁺, and Si²⁺

The dual-laser-produced plasma (DLP) photoabsorption technique has been used to study 2p→3s excitations in the isoelectronic species Mg, Al+, and Si2+ prepared in the excited configuration 2p63s3p. The autoionizing upper states belong to the 2p53s23p even-parity configuration. The versatility of the technique is demonstrated through a careful combination of space- and time-resolved photoabsorption scans. Plasma conditions optimized for the observation of the inaccessible parity regime were successfully reproduced along the isoelectronic sequence of interest. All the observed transitions were interpreted with the help of multiconfigurational atomic structure calculations. In the case of magnesium, the photoabsorption data are compared with the ejected-electron spectra excited by low-energy electron impact of Pejcev et al. [J. Phys. B 10, 2389 (1977)]

Angle-resolved photoelectron spectrometry studies of the autoionization of the 2s22p 2P triply excited state of atomic lithium: experimental results and R-matrix calculations

We have measured the angle-resolved energy dependence of the electrons emitted over the energy range of the triply excited 2s22p2P lithium resonance using synchrotron radiation. We have also calculated the behavior of the angular distribution parameter β using the R-matrix approximation. Experimental and theoretical results are in good agreement and show deep minima in the 1s2p1,3P ionic channels. The energy at which the minima occur does not coincide with the resonance energy, but is shifted towards higher energy