Large-scale multi-stage constructed wetlands for secondary effluents treatment in northern China: Carbon dynamics

© 2017 Elsevier Ltd Multi-stage constructed wetlands (CWs) have been proved to be a cost-effective alternative in the treatment of various wastewaters for improving the treatment performance as compared with the conventional single-stage CWs. However, few long-term full-scale multi-stage CWs have been performed and evaluated for polishing effluents from domestic wastewater treatment plants (WWTP). This study investigated the seasonal and spatial dynamics of carbon and the effects of the key factors (input loading and temperature) in the large-scale seven-stage Wu River CW polishing domestic WWTP effluents in northern China. The results indicated a significant improvement in water quality. Significant seasonal and spatial variations of organics removal were observed in the Wu River CW with a higher COD removal efficiency of 64–66% in summer and fall. Obvious seasonal and spatial variations of CH4 and CO2 emissions were also found with the average CH4 and CO2 emission rates of 3.78–35.54 mg m−2 d−1 and 610.78–8992.71 mg m−2 d−1, respectively, while the higher CH4 and CO2 emission flux was obtained in spring and summer. Seasonal air temperatures and inflow COD loading rates significantly affected organics removal and CH4 emission, but they appeared to have a weak influence on CO2 emission. Overall, this study suggested that large-scale Wu River CW might be a potential source of GHG, but considering the sustainability of the multi-stage CW, the inflow COD loading rate of 1.8–2.0 g m−2 d−1 and temperature of 15–20 °C may be the suitable condition for achieving the higher organics removal efficiency and lower greenhouse gases (GHG) emission in polishing the domestic WWTP effluent. The obtained knowledge of the carbon dynamics in large-scale Wu River CW will be helpful for understanding the carbon cycles, but also can provide useful field experience for the design, operation and management of multi-stage CW treatments

The impact of gas slug flow on microfiltration performance in an airlift external loop tubular membrane reactor

© 2016 The Royal Society of Chemistry. This work investigated the impact of gas slug flow on microfiltration in an airlift external loop tubular membrane reactor. A complete description for the characteristics of the slug flow was obtained as the aeration rate increased from 30 to 120 L h-1 with an interval of 30 L h-1. The shear stress of the falling film region could reach 6.37 × 10-3 Pa with the aeration rate of 90 L h-1. Experimental results showed that the growth of transmembrane pressure (TMP) could be controlled effectively by increasing the aeration rate and the optimal aeration rate in a slug flow was around 90 L h-1. However, a subsequent increase in the aeration rate had no significant effect on slowing down the TMP growth rate. Turning the constant air-flow into periodic pulsatile air-flow, low gas-velocity and high gas-velocity led to alternate operation in filtration. When the alternate interval of pulsatile air-flow was 60 s at the alternate aeration rates of 30/90 L h-1 and 60/90 L h-1, it could delay membrane fouling and save a lot of gas compared with implementing a constant air-flow of 90 L h-1. Finally, for different water outlet positions along the membrane tube, membrane fouling gradually slowed down from the bottom to the top

Optimization of organics and nitrogen removal in intermittently aerated vertical flow constructed wetlands: Effects of aeration time and aeration rate

© 2016 Elsevier Ltd In this study, to optimize aeration for the enhancement of organics and nitrogen removal in intermittently aerated vertical flow constructed wetlands (VF CWs) for treating domestic wastewater, the experimental VF CWs were operated at different aeration time (1 h d−1, 2 h d−1, 4 h d−1, 6 h d−1, 8 h d−1 and 10 h d−1) and aeration rate (0.1 L min−1, 0.2 L min−1, 0.5 L min−1, 1.0 L min−1 and 2.0 L min−1) to investigate the effect of artificial aeration on the removal efficiency of organics and nitrogen. The results showed that the optimal aeration time and aeration rate were 4 h d−1 and 1.0 L min−1, which could create the appropriate aerobic and anoxic regions in CWs with the greater removal of COD (97.2%), NH4+-N (98.4%) and TN (90.6%) achieved simultaneously during the experiment. The results demonstrate that the optimized intermittent aeration is reliable option to enhance the treatment performance of organics and nitrogen at a lower operating cost

Nitrogen removal and nitrous oxide emission in surface flow constructed wetlands for treating sewage treatment plant effluent: Effect of C/N ratios

© 2017 Elsevier Ltd In order to design treatment wetlands with maximal nitrogen removal and minimal nitrous oxide (N2O) emission, the effect of influent C/N ratios on nitrogen removal and N2O emission in surface flow constructed wetlands (SF CWs) for sewage treatment plant effluent treatment was investigated in this study. The results showed that nitrogen removal and N2O emission in CWs were significantly affected by C/N ratio of influent. Much higher removal efficiency of NH4+-N (98%) and TN (90%) was obtained simultaneously in SF CWs at C/N ratios of 12:1, and low N2O emission (8.2 mg/m2/d) and the percentage of N2O-N emission in TN removal (1.44%) were also observed. These results obtained in this study would be utilized to determine how N2O fluxes respond to variations in C/N ratios and to improve the sustainability of CWs for wastewater treatment

Carbohydrate-based activated carbon with high surface acidity and basicity for nickel removal from synthetic wastewater

© The Royal Society of Chemistry. The feasibility of preparing activated carbon (AC-CHs) from carbohydrates (glucose, sucrose and starch) with phosphoric acid activation was evaluated by comparing its physicochemical properties and Ni(ii) adsorption performance with a reference activated carbon (AC-PA) derived from Phragmites australis. The textural and chemical properties of the prepared activated carbon were characterized by N2 adsorption/desorption isotherms, SEM, Boehm's titration and XPS. Although AC-CHs had much lower surface area (less than 700 m2 g-1) than AC-PA (1057 m2 g-1), they exhibited 45-70% larger Ni(ii) adsorption capacity which could be mainly attributed to their 50-75% higher contents of total acidic and basic groups. The comparison of XPS analyses for starch-based activated carbon before and after Ni(ii) adsorption indicated that Ni(ii) cation combined with the oxygen-containing groups and basic groups (delocalized π-electrons) through the mechanisms of proton exchange, electrostatic attraction, and surface complexation. Kinetic results suggested that chemical reaction was the main rate-controlling step, and a very quick Ni(ii) adsorption performance of AC-CHs was presented with ∼95% of maximum adsorption within 30 min. Both adsorption capacity and rate of the activated carbon depended on the surface chemistry as revealed by batch adsorption experiments and XPS analyses. This study demonstrated that AC-CHs could be promising materials for Ni(ii) pollution minimization

Strategies and techniques to enhance constructed wetland performance for sustainable wastewater treatment

© 2015, Springer-Verlag Berlin Heidelberg. Constructed wetlands (CWs) have been used as an alternative to conventional technologies for wastewater treatment for more than five decades. Recently, the use of various modified CWs to improve treatment performance has also been reported in the literature. However, the available knowledge on various CW technologies considering the intensified and reliable removal of pollutants is still limited. Hence, this paper aims to provide an overview of the current development of CW strategies and techniques for enhanced wastewater treatment. Basic information on configurations and characteristics of different innovations was summarized. Then, overall treatment performance of those systems and their shortcomings were further discussed. Lastly, future perspectives were also identified for specialists to design more effective and sustainable CWs. This information is used to inspire some novel intensifying methodologies, and benefit the successful applications of potential CW technologies

A review on the sustainability of constructed wetlands for wastewater treatment: Design and operation

© 2014 Elsevier Ltd. Constructed wetlands (CWs) have been used as a green technology to treat various wastewaters for several decades. CWs offer a land-intensive, low-energy, and less-operational-requirements alternative to conventional treatment systems, especially for small communities and remote locations. However, the sustainable operation and successful application of these systems remains a challenge. Hence, this paper aims to provide and inspire sustainable solutions for the performance and application of CWs by giving a comprehensive review of CWs' application and the recent development on their sustainable design and operation for wastewater treatment. Firstly, a brief summary on the definition, classification and application of current CWs was presented. The design parameters and operational conditions of CWs including plant species, substrate types, water depth, hydraulic load, hydraulic retention time and feeding mode related to the sustainable operation for wastewater treatments were then discussed. Lastly, future research on improving the stability and sustainability of CWs were highlighted

Intensified organics and nitrogen removal in the intermittent-aerated constructed wetland using a novel sludge-ceramsite as substrate

© 2016 Elsevier Ltd. In this study, a novel sludge-ceramsite was applied as main substrate in intermittent-aerated subsurface flow constructed wetlands (SSF CWs) for treating decentralized domestic wastewater, and intensified organics and nitrogen removal in different SSF CWs (with and without intermittent aeration, with and without sludge-ceramsite substrate) were evaluated. High removal of 97.2% COD, 98.9% NH4+-N and 85.8% TN were obtained simultaneously in the intermittent-aerated CW system using sludge-ceramsite substrate compared with non-aerated CWs. Moreover, results from fluorescence in situ hybridization (FISH) analysis revealed that the growth of ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) in the intermittent-aerated CW system with sludge-ceramsite substrate was enhanced, thus indicating that the application of intermittent aeration and sludge-ceramsite plays an important role in nitrogen transformations. These results suggest that a combination of intermittent aeration and sludge-ceramsite substrate is reliable to enhance the treatment performance in SSF CWs

Effect of photosynthetically elevated pH on performance of surface flow-constructed wetland planted with Phragmites australis

© 2016, Springer-Verlag Berlin Heidelberg. Combination of emergent and submerged plants has been proved to be able to enhance pollutant removal efficiency of surface flow-constructed wetland (SFCW) during winter. However, intensive photosynthesis of submerged plants during summer would cause pH increase, which may have adverse effects on emergent plants. In this study, nitrogen transformation of lab-scale SFCW under pH gradient of 7.5, 8.5, 9.5 and 10.5 was systematically investigated. The results showed that total nitrogen (TN) removal efficiency decreased from 76.3 ± 0.04 to 51.8 ± 0.04 % when pH increased from 7.5 to 10.5, which was mainly attributed to plant assimilation decay and inhibition of microbe activities (i.e., nitrite-oxidizing bacteria and denitrifiers). Besides, the highest sediment adsorption in SFCW was observed at pH of 8.5. In general, the combination of submerged and emergent plants is feasible for most of the year, but precaution should be taken to mitigate the negative effect of high alkaline conditions when pH rises to above 8.5 in midsummer

Biofouling and control approaches in membrane bioreactors

© 2016 Elsevier Ltd Membrane fouling (especially biofouling) as a critical issue during membrane reactor (MBR) operation has attracted much attention in recent years. Although previous review papers have presented different aspects of MBR's fouling when treating various wastewaters, the information related to biofouling in MBRs has only simply or partially reviewed. This work attempts to give a more comprehensive and elaborate explanation of biofilm formation, biofouling factors and control approaches by addressing current achievements. This also suggests to a better way in controlling biofouling by developing new integrated MBR systems, novel flocculants and biomass carriers