Neon diffusion kinetics and implications for cosmogenic neon paleothermometry in feldspars

Observations of cosmogenic neon concentrations in feldspars can potentially be used to constrain the surface exposure duration or surface temperature history of geologic samples. The applicability of cosmogenic neon to either application depends on the temperature-dependent diffusivity of neon isotopes. In this work, we investigate the kinetics of neon diffusion in feldspars of different compositions and geologic origins through stepwise degassing experiments on single, proton-irradiated crystals. To understand the potential causes of complex diffusion behavior that is sometimes manifest as nonlinearity in Arrhenius plots, we compare our results to argon stepwise degassing experiments previously conducted on the same feldspars. Many of the feldspars we studied exhibit linear Arrhenius behavior for neon whereas argon degassing from the same feldspars did not. This suggests that nonlinear behavior in argon experiments is an artifact of structural changes during laboratory heating. However, other feldspars that we examined exhibit nonlinear Arrhenius behavior for neon diffusion at temperatures far below any known structural changes, which suggests that some preexisting material property is responsible for the complex behavior. In general, neon diffusion kinetics vary widely across the different feldspars studied, with estimated activation energies (Ea) ranging from 83.3 to 110.7 kJ/mol and apparent pre-exponential factors (D0) spanning three orders of magnitude from 2.4 × 10−3 to 8.9 × 10−1 cm2 s−1. As a consequence of this variability, the ability to reconstruct temperatures or exposure durations from cosmogenic neon abundances will depend on both the specific feldspar and the surface temperature conditions at the geologic site of interest

Front-loading Urban Stormwater Management for Success – A Perspective Incorporating Current Studies on the Implementation of Retrofit Low-impact Development

Recent work into the implementation of low-impact development (LID) suggests that a decentralized, source-control approach has the potential to significantly reduce urban stormwater runoff quantity. The practice of retrofit stormwater management is currently dominated by demonstration projects, and some additional momentum is required to spur adoption and upscaling of LID practices so that the scale of this management approach can better match the scale of disturbance. This momentum may be provided in part by targeted research into effectiveness of stormwater best management practices insofar as research accounts for cost and effectiveness (e.g., water quality benefits, and actual stormwater capture) under a variety of climate conditions. We posit that the factors of increasing public participation in stormwater management; engaging local agencies and non-governmental organizations (NGOs); application of proven source control methods to mitigate runoff formation; and science-based, comprehensive monitoring strategies are all important to the sustainable implementation of retrofit low-impact development. From the perspective of Federal researchers and local NGOs, this paper presents features, objectives, and costs of recent efforts to properly scale demonstration projects and broader LID initiatives. In order to realize the full benefits of decentralized LID stormwater management practices in urban and suburban areas, we conclude that a nexus must exist of a motivated and engaged citizenry, solid support from municipal and regional agencies, sound source control management practices, and follow-up monitoring to judge effectiveness

A structured decision approach for integrating and analyzing community perspectives in re-use planning of vacant properties in Cleveland, Ohio

An integrated GIS-based, multi-attribute decision model deployed in a web-based platform is presented enabling an iterative, spatially explicit and collaborative analysis of relevant and available information for repurposing vacant land. The process incorporated traditional and novel aspects of decision science, beginning with an analysis of alternatives, building on this analysis with a workshop to elucidate opinions and concerns from key decision-makers relevant to the problem at hand, then expanded by extracting and compiling fundamental objectives from existing planning efforts and previously published long-term goals. The model was then constructed as an open-source, web-based software platform for use as a process for exploring, evaluating, comparing, and optimizing fundamental, strategic, and means objectives. The resulting beta model, MURL-CLE, is intended to allow all interested parties, from stakeholders to decision makers, to consider alternative options for reuse of vacant land in a neighborhood in Cleveland, OH and to do so in a deliberative, transparent, and defensible process. The beta model is intended to be a platform for growth as a decision science tool and to provide a reproducible mechanism for considering any complex decision that attempts to incorporate multiple competing objectives and to allow an iterative process, as opposed to a prescribed solution or ranking of alternatives, for community decision making

The hydrologic role of urban green space in mitigating flooding (Luohe, China)

Even if urban catchments are adequately drained by sewer infrastructures, flooding hotspots develop where ongoing development and poor coordination among utilities conspire with land use and land cover, drainage, and rainfall. We combined spatially explicit land use/land cover data from Luohe City (central China) with soil hydrology (as measured, green space hydraulic conductivity), topography, and observed chronic flooding to analyze the relationships between spatial patterns in pervious surface and flooding. When compared to spatial–structural metrics of land use/cover where flooding was commonly observed, we found that some areas expected to remain dry (given soil and elevation characteristics) still experienced localized flooding, indicating hotspots with overwhelmed sewer infrastructure and a lack of pervious surfaces to effectively infiltrate and drain rainfall. Next, we used curve numbers to represent the composite hydrology of different land use/covers within both chronic flooding and dry (non-flooding) circles of 750 m diameter, and local design storms to determine the anticipated average proportion of runoff. We found that dry circles were more permeable (curve number (mean ± std. error) = 74 ± 2, n = 25) than wetter, flooded circles (curve number = 87 ± 1). Given design storm forcing (20, 50, 100 years’ recurrence interval, and maximum anticipated storm depths), dry points would produce runoff of 26 to 35 percent rainfall, and wet points of 52 to 61 percent of applied rainfall. However, we estimate by simulation that runoff reduction benefits would decline once infiltration-excess (Hortonian) runoff mechanisms activate for storms with precipitation rates in excess of an average of 21 mm/h, contingent on antecedent moisture conditions. Our spatial metrics indicate that larger amounts and patches of dispersed green space mitigate flooding risk, while aggregating buildings (roofs) and green space into larger, separate areas exacerbates risk

Trapped Ar isotopes in meteorite ALH 84001 indicate Mars did not have a thick ancient atmosphere

Water is not currently stable in liquid form on the martian surface due to the present mean atmospheric pressure of ∼7 mbar and mean global temperature of ∼220 K. However, geomorphic features and hydrated mineral assemblages suggest that Mars’ climate was once warmer and liquid water flowed on the surface. These observations may indicate a substantially more massive atmosphere in the past, but there have been few observational constraints on paleoatmospheric pressures. Here we show how the [superscript 40]Ar/[superscript 36]Ar ratios of trapped gases within martian meteorite ALH 84001 constrain paleoatmospheric pressure on Mars during the Noachian era [∼4.56–3.8 billion years (Ga)]. Our model indicates that atmospheric pressures did not exceed ∼1.5 bar during the first 400 million years (Ma) of the Noachian era, and were <400 mbar by 4.16 Ga. Such pressures of CO[subscript 2] are only sufficient to stabilize liquid water on Mars’ surface at low latitudes during seasonally warm periods. Other greenhouse gases like SO[superscript 2] and water vapor may have played an important role in intermittently stabilizing liquid water at higher latitudes following major volcanic eruptions or impact events.United States. National Aeronautics and Space Administration. Mars Fundamental Research Program (Grant MFRP05-0108)Ann and Gordon Getty Foundatio

Continuous monitoring reveals multiple controls on ecosystem metabolism in a suburban stream

1. Primary production and respiration in streams, collectively referred to as stream ecosystem metabolism, are fundamental processes that determine trophic structure, biomass and nutrient cycling. Few studies have used high‐frequency measurements of gross primary production (GPP) and ecosystem respiration (ER) over extended periods to characterise the factors that control stream ecosystem metabolism at hourly, daily, seasonal and annual scales. 2. We measured ecosystem metabolism at 5‐min intervals for 23 months in Shepherd Creek, a small suburban stream in Cincinnati, Ohio (U.S.A.). 3. Daily GPP was best predicted by a model containing light and its synergistic interaction with water temperature. Water temperature alone was not significantly related to daily GPP, rather high temperatures enhanced the capacity of autotrophs to use available light. 4. The relationship between GPP and light was further explored using photosynthesis–irradiance curves (P–I curves). Light saturation of GPP was evident throughout the winter and spring and the P–I curve frequently exhibited strong counterclockwise hysteresis. Hysteresis occurred when water temperatures were greater in the afternoon than in the morning, although light was similar, further suggesting that light availability interacts synergistically with water temperature. 5. Storm flows strongly depressed GPP in the spring while desiccation arrested aquatic GPP and ER in late summer and autumn. 6. Ecosystem respiration was best predicted by GPP, water temperature and the rate of water exchange between the surface channel and transient storage zones. We estimate that c. 70% of newly fixed carbon was immediately respired by autotrophs and closely associated heterotrophs. 7. Interannual, seasonal, daily and hourly variability in ecosystem metabolism was attributable to a combination of light availability, water temperature, storm flow dynamics and desiccation. Human activities affect all these factors in urban and suburban streams, suggesting stream ecosystem processes are likely to respond in complex ways to changing land use and climate

Sustainability for shrinking cities

Shrinking cities are widespread throughout the world despite the rapidly increasing global urban population. These cities are attempting to transition to sustainable trajectories to improve the health and well-being of urban residents, to build their capacity to adapt to changing conditions and to cope with major events. The dynamics of shrinking cities are different than the dynamics of growing cities, and therefore intentional research and planning around creating sustainable cities is needed for shrinking cities. We propose research that can be applied to shrinking cities by identifying parallel challenges in growing cities and translating urban research and planning that is specific to each city’s dynamics. In addition, we offer applications of panarchy concepts to this problem. The contributions to this Special Issue take on this forward-looking planning task through drawing lessons for urban sustainability from shrinking cities, or translating general lessons from urban research to the context of shrinking cities

Theology, News and Notes - Vol. 40, No. 01

Theology News & Notes was a theological journal published by Fuller Theological Seminary from 1954 through 2014.https://digitalcommons.fuller.edu/tnn/1201/thumbnail.jp

Enhancing the STEM Ecosystem through Teacher-Researcher Partnerships

STEM faculty at the University of Nebraska at Omaha (UNO) have partnered with teachers and administrators in the Omaha Public Schools (OPS) to implement a Teacher-Researcher Partnership Program. This program establishes resources and infrastructure that engage K-12 science teachers in scientific research experiences. In the first implementation of this program, eleven UNO faculty mentors, drawn from several STEM disciplines, were matched with eleven OPS teachers to conduct genuine research projects in support of their teaching

Genuine Faculty-Mentored Research Experiences for In-Service Science Teachers: Increases in Science Knowledge, Perception, and Confidence Levels

The overall purpose of this multifocused study was to explore how participation in genuine mentored scientific research experiences impacts in-service science teachers and the knowledge and skills needed for their own science teaching. The research experiences resulted from a partnership between the University of Nebraska at Omaha and the Omaha Public School District. This Teacher- Researcher Partnership Program facilitated opportunities in inquiry, science content, interaction with laboratory instrumentation and technologies, critical discussion of literature, and dissemination of findings for participating in-service science teacher professional development utilizing an inquiry-based theoretical framework wherein we examined science teacher preparation via inquiry-based methods in the research laboratory. A mixed-methods approach with a convergent typology (i.e., qualitative and quantitative analyses conducted separately and integrated) was used to investigate the impact of the program on teachers. Our research question was as follows: How do teachers define and approach scientific research before and after a genuine research experience? We observed 3 emergent nodes or themes by which teachers indicated significant gains: science content knowledge, confidence, and perception. Moreover, we determined that participation by science teachers in a mentored research experience using current scientific technologies and tools improved teacher confidence in science and inquiry as well as an ongoing commitment to provide similar types of experiences to their students. These data support the need for the participation of in-service science teachers in genuine research experiences to boost technological and pedagogical content knowledge, confidence in process and content, and the perception of translatability to the classroom