Nonequilibrium material effects on the behavior of polymeric composite matrices and their related composites

The effects of physical aging on the material properties of some linear and network macromolecular glasses are discussed. The free volume concept is used to describe this behavior. The effect of physical aging on properties of some uniaxial graphite/fiber epoxy resin composites is investigated using stress relaxation in both tensile and flexural modes. The matrix polymers used were resins both of which are based on a 4,4-methylenedianiline derivative of epichlorohydrin with diamino diphenyl sulfone (DDS) as the curing agent. The matrix resin, as used in the practical application in composites, not fully cured and the glass transition of the network was dependent on the curing schedule. The physical aging of the bulk crosslinked epoxy was found to depend on the annealing temperature, and the T sub g of the resin. The physical aging of the composite, monitored by the stress relaxation method, was found to be dependent on the testing direction

Thermal control surfaces experiment: Initial flight data analysis

The behavior of materials in the space environment continues to be a limiting technology for spacecraft and experiments. The thermal control surfaces experiment (TCSE) aboard the Long Duration Exposure Facility (LDEF) is the most comprehensive experiment flown to study the effects of the space environment on thermal control surfaces. Selected thermal control surfaces were exposed to the LDEF orbital environment and the effects of this exposure were measured. The TCSE combined in-space orbital measurements with pre and post-flight analyses of flight materials to determine the effects of long term space exposure. The TCSE experiment objective, method, and measurements are described along with the results of the initial materials analysis. The TCSE flight system and its excellent performance on the LDEF mission is described. A few operational anomalies were encountered and are discussed

Drift-diffusion model of the fragmentation of the external ring structure in the photoluminescence pattern of indirect excitons in coupled quantum wells

Under optical excitation, coupled quantum wells are known to reveal fascinating features in the photoluminescence pattern originating from dipole orientated indirect excitons. The appearance of an external ring has been attributed to macroscopic charge separation in the quantum well plane. We present a classical model of non-linear diffusion to account for the observed fragmentation of the external ring into a periodic array of islands. The model incorporates the Coulomb interactions between electrons, holes and indirect excitons. At low temperatures, these interactions lead to pattern formation similar to the experimentally observed ring fragmentation. The fragmentation is found to persist to temperatures above the quantum degeneracy temperature of indirect excitons.Comment: 5 pages, 3 figure

Standing in the Shadow of Empire: Ideology in the Path to West Virginia Statehood

An empire of industry moved through West Virginia prior to the US Civil War, and saw a breed of capitalists and politicians who acquired control of land through purchase and through patent, developed control of the vote through industrial political influence, and encouraged the West Virginian to separate from an eastern Virginian society based in planter-elite agrarian society. The West Virginian who believed that self-sufficiency and subsistence farming could sustain his family saw his vote for statehood and separation from the Old Dominion transformed into an industrial coup. Land slowly but steadily slipped away from the hands of the mountaineer and into the hands of industrialists who extracted wealth, transforming the new state into an environment that privileged the capitalist and industry above the yeoman farmer. For the industrialists who made West Virginia their home, it appears that extraction of minerals and timber was not the only value taken from West Virginia. Political power and entre into the world of the global industrialist may have been a strong motivating factor, as opposed to simply reaping financial rewards. This work seeks to highlight the influence of these industrialists at the local level in such a way as to demonstrate the weight of this collective group of individuals upon the crafting of West Virginia statehood

Thermal control surfaces experiment flight system performance

The Thermal Control Surfaces Experiment (TCSE) is the most complex system, other than the LDEF, retrieved after long term space exposure. The TCSE is a microcosm of complex electro-optical payloads being developed and flow by NASA and the DoD including SDI. The objective of TCSE was to determine the effects of the near-Earth orbital environment and the LDEF induced environment on spacecraft thermal control surfaces. The TCSE was a comprehensive experiment that combined in-space measurements with extensive post flight analyses of thermal control surfaces to determine the effects of exposure to the low earth orbit space environment. The TCSE was the first space experiment to measure the optical properties of thermal control surfaces the way they are routinely measured in a lab. The performance of the TCSE confirms that low cost, complex experiment packages can be developed that perform well in space