Identified Hadrons and Jet Chemistry for p+p and Au+Au Collisions at RHIC

The study of hadron spectra at high $p_{T}$ in p+p collisions provides a good test of perturbative quantum chromo-dynamic calculations (pQCD) and baseline for measurements of nuclear modification factors in Au+Au collisions. Using events triggered by the Barrel Electro-Magnetic Calorimeter, identified charged hadron transverse momentum ($p_T$) spectra are measured up to 15 GeV/$c$ at mid-rapidity ($\mid y\mid$ $<$ 0.5) and neutral kaon $p_T$ spectra up to 12 GeV/$c$ in p + p collisions at $\sqrt{s_{NN}}$ = 200 GeV. The particle ratios of $p/\pi^{+}$, $\bar{p}/\pi^{-}$ and $K^{\pm,0}$ / $\pi^{\pm}$ in p + p collisions are shown and compared with next-to-leading order pQCD calculations. In central Au+Au collisions, we report nuclear modification factors ($R_{AA}$) for pion, kaon, proton and $\rho$ and discuss several model calculations: color-charge dependence of jet quenching and jet conversion. Finally, centrality dependence of $R_{AA}$ at high $p_T$ ($>$ 5.5 GeV/c) for kaon are compared with that of pion in Au + Au collisions at 200 GeV.Comment: 6 pages, 4 figures, SQM 2009 contributio

Testing the Color Charge and Mass Dependence of Parton Energy Loss with Heavy-to-light Ratios at RHIC and LHC

The ratio of nuclear modification factors of high-pT heavy-flavored mesons to light-flavored hadrons (``heavy-to-light ratio'') in nucleus-nucleus collisions tests the partonic mechanism expected to underlie jet quenching. Heavy-to-light ratios are mainly sensitive to the mass and color-charge dependences of medium-induced parton energy loss. Here, we assess the potential for identifying these two effects in D and B meson production at RHIC and at the LHC. To this end, we supplement the perturbative QCD factorized formalism for leading hadron production with radiative parton energy loss. For D meson spectra at high but experimentally accessible transverse momentum (10 < pT < 20 GeV) in Pb-Pb collisions at the LHC, we find that charm quarks behave essentially like light quarks. However, since light-flavored hadron yields are dominated by gluon parents, the heavy-to-light ratio of D mesons is a sensitive probe of the color charge dependence of parton energy loss. In contrast, due to the larger b quark mass, the medium modification of B mesons in the same kinematical regime provides a sensitive test of the mass dependence of parton energy loss. At RHIC energies, the strategies for identifying and disentangling the color charge and mass dependence of parton energy loss are more involved because of the smaller kinematical range accessible. We argue that at RHIC, the kinematical regime best suited for such an analysis of D mesons is 7 < pT < 12 GeV, whereas the study of lower transverse momenta is further complicated due to the known dominant contribution of additional, particle species dependent, non-perturbative effects.Comment: 21 pages RevTex, 9 Figure

Violation of Wiedemann-Franz law at the Kondo breakdown quantum critical point

We study both the electrical and thermal transport near the heavy-fermion quantum critical point (QCP), identified with the breakdown of the Kondo effect as an orbital selective Mott transition. We show that the contribution to the electrical conductivity comes mainly from conduction electrons while the thermal conductivity is given by both conduction electrons and localized fermions (spinons), scattered with dynamical exponent $z = 3$. This scattering mechanism gives rise to a quasi-linear temperature dependence of the electrical and thermal resistivity. The characteristic feature of the Kondo breakdown scenario turns out to be emergence of additional entropy carriers, that is, spinon excitations. As a result, we find that the Wiedemann-Franz ratio should be larger than the standard value, a fact which enables to differentiate the Kondo breakdown scenario from the Hertz-Moriya-Millis framework

Substituted bisphosphanylamines as ligands in gold(I) chemistry – synthesis and structures

Dimethyl 5-aminoisophthalate, which is a building block of amino-substituted tetralactam macrocycles, was used as ligand in gold(I) chemistry to form model complexes for macrocyclic gold compounds. Reaction of dimethyl 5-aminoisophthalate with chlorodiphenylphosphine gave the diphosphine compound dimethyl 5-[N,N-bis(diphenylphosphanyl)amino]isophthalate (dmbpaip). This compound can further be reacted with [AuCl(tht)] (tht = tetrahydrothiophene) to give the dinuclear complex [Au(2),Cl(2)(dmbpaip)]. In contrast, treatment of dinbpaip with [Au(tht)(2)]ClO(4) resulted in the ionic compound [Au(2)(dmbpaip)(2)](ClO(4))(2) in which the cation forms an eight-membered Au(2)P(4)N(2) heterocycle. In both gold(I) compounds Au center dot center dot center dot Au interactions are observed. All new compounds were characterized by single-crystal X-ray diffraction

Reconstructing the Freeze-out State in Pb + Pb Collisions at 158 AGeV/c

For a class of analytical parametrizations of the freeze-out state of relativistic heavy ion collisions, we perform a simultaneous analysis of the single-particle m_t-spectra and two-particle Bose-Einstein correlations measured in central Pb+Pb collisions at the CERN SPS. The analysis includes a full model parameter scan with chi^2 confidence levels. A comparison of different transverse density profiles for the particle emission region allows for a quantitative discussion of possible model dependencies of the results. Our fit results suggest a low thermal freeze-out temperature T approximately 95 +- 15 MeV and a large average transverse flow velocity of about 0.55c +- 0.07c. Moreover, the fit favours a box-shaped transverse density profile over a Gaussian one. We discuss the origins and the consequences of these results in detail. In order to reproduce the measured pion multiplicity our model requires a positive pion chemical potential. A study of the pion phase-space density indicates \mu_\pi approximately 60 MeV for T = 100 MeV

Bond activation in iron(II) and nickel(II) complexes of polypodal phosphanes

A pyridine-derived tetraphosphane ligand (donor set: NP4) has been found to undergo remarkably specific C-P bond cleavage reactions, thereby producing a ligand with an NP3 donor set. The reaction may be reversed under suitable conditions, with regeneration of the original NP4 ligand. In order to investigate the mechanism of this reaction, the NP3 donor ligand C5H3N[CMe(CH2PMe2)2][CMe2(CH2PMe2)] (11) was prepd., and its iron(II) complex 4 generated from Fe(BF4)2·6 H2O, with Me diethylphosphinite (7) as an addnl. monodentate ligand. Ligand 11 has, in addn. to the NP3 donor set, one Me group in close contact with the iron center, reminiscent of an agostic M···H-C interaction. Depending on the stoichiometric amt. of iron(II) salt, a side product 15 is formed, which has a diethylphosphane ligand instead of the phosphinite 7 coordinated to iron(II). While attempts to deprotonate the metal-coordinated Me group in 4 were unsuccessful, the reaction was shown to occur in an alternative complex (18), which is similar to 4 but has a trimethylphosphane ligand instead of the phosphinite 7. The reaction of complex 15 with CO gave two different products, which were both characterized by single-crystal X-ray diffraction. One (19) is the dicarbonyl iron(II) complex of the triphosphane ligand 11, the other (3) is the carbonyl iron(II) complex of the tetraphosphane C5H3N[CMe(CH2PMe2)2]2 (1). This suggests an intermol. mechanism for the C-P bond formation in question. [on SciFinder(R)

Infrared Observations During the Secondary Eclipse of HD 209458b: I. 3.6-Micron Occultation Spectroscopy Using the VLT

We search for an infrared signature of the transiting extrasolar planet HD 209458b during secondary eclipse. Our method, which we call `occultation spectroscopy,' searches for the disappearance and reappearance of weak spectral features due to the exoplanet as it passes behind the star and later reappears. We argue that at the longest infrared wavelengths, this technique becomes preferable to conventional `transit spectroscopy'. We observed the system in the wing of the strong nu-3 band of methane near 3.6 microns during two secondary eclipses, using the VLT/ISAAC spectrometer at a spectral resolution of 3300. Our analysis, which utilizes a model template spectrum, achieves sufficient precision to expect detection of the spectral structure predicted by an irradiated, low-opacity (cloudless), low-albedo, thermochemical equilibrium model for the exoplanet atmosphere. However, our observations show no evidence for the presence of this spectrum from the exoplanet, with the statistical significance of the non-detection depending on the timing of the secondary eclipse, which depends on the assumed value for the orbital eccentricity. Our results reject certain specific models of the atmosphere of HD 209458b as inconsistent with our observations at the 3-sigma level, given assumptions about the stellar and planetary parameters.Comment: 26 pages, 8 figures Accepted to Astrophysical Journa