174 research outputs found
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of gold(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible CâO bond formation followed by turnover-limiting protodeauration from a mono(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation and formation of an off-cycle bis(gold) vinyl complex
Mechanistic Studies of Ethylene Hydrophenylation Catalyzed by Bipyridyl Pt(II) Complexes
This article discusses mechanistic studies of ethylene hydrophenylation catalyzed by bipyridyl Pt(II) complexes
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of goldÂ(I)-catalyzed intramolecular
allene
hydroalkoxylation established a mechanism involving rapid and reversible
CâO bond formation followed by turnover-limiting protodeauration
from a monoÂ(gold) vinyl complex. This on-cycle pathway competes with
catalyst aggregation and formation of an off-cycle bisÂ(gold) vinyl
complex
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible CâO Bond Formation
Mechanistic investigation of goldÂ(I)-catalyzed intramolecular
allene
hydroalkoxylation established a mechanism involving rapid and reversible
CâO bond formation followed by turnover-limiting protodeauration
from a monoÂ(gold) vinyl complex. This on-cycle pathway competes with
catalyst aggregation and formation of an off-cycle bisÂ(gold) vinyl
complex
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