180 research outputs found
Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C–O Bond Formation
Get PDFMechanistic investigation of gold(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible C–O bond formation followed by turnover-limiting protodeauration from a mono(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation and formation of an off-cycle bis(gold) vinyl complex
Mechanistic Studies of Ethylene Hydrophenylation Catalyzed by Bipyridyl Pt(II) Complexes
Get PDFThis article discusses mechanistic studies of ethylene hydrophenylation catalyzed by bipyridyl Pt(II) complexes
Arylpalladium Phosphonate Complexes as Reactive Intermediates in Phosphorus−Carbon Bond Forming Reactions
Full text linkRoom Temperature Hydroamination of Alkynes Catalyzed by Gold Clusters in Interfacially Cross-Linked Reverse Micelles
Full text linkGold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition
Full text linkThis review highlights recent advances made in the synthesis of cationic gold carbene complexes and in the direct detection of cationic intermediates generated via gold-catalysed enyne cycloaddition.</p
ChemInform Abstract: Gold Carbenes, Gold-Stabilized Carbocations, and Cationic Intermediates Relevant to Gold-Catalyzed Enyne Cycloaddition
Full text linkChemInform Abstract: Tandem Cyclization/Hydrosilylation of Functionalized 1,6-Dienes Catalyzed by a Cationic Palladium Complex.
Full text linkUse of Pentamethyldisiloxane in the Palladium-Catalyzed Cyclization/Hydrosilylation of Functionalized Dienes
No full textInvestigations on Gold‐Catalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals
No full textPhoto‐Organocatalytic Enantioselective Radical Cascade Enabled by Single‐Electron Transfer Activation of Allenes
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