1,120 research outputs found
C4 Dissymmetric resorcinarene derivatives: synthesis, crystal structure and micelle formation
The synthesis of a C4 dissymmetric resorcinarene tetracarboxylic acid derivative and determination of its critical micelle concentration is reported. The tetrahydroxy derivative was prepared by reduction of the tetra-acid. The low-temperature single crystal X-ray structure of the methyl ester derivative of the tetra-acid is also reported. This crystallised with two independent molecules of similar boat (flattened cone) conformation within the asymmetric unit
Spatial Curvature Falsifies Eternal Inflation
Inflation creates large-scale cosmological density perturbations that are
characterized by an isotropic, homogeneous, and Gaussian random distribution
about a locally flat background. Even in a flat universe, the spatial curvature
measured within one Hubble volume receives contributions from long wavelength
perturbations, and will not in general be zero. These same perturbations
determine the Cosmic Microwave Background (CMB) temperature fluctuations, which
are O(10^-5). Consequently, the low-l multipole moments in the CMB temperature
map predict the value of the measured spatial curvature \Omega_k. On this basis
we argue that a measurement of |\Omega_k| > 10^-4 would rule out slow-roll
eternal inflation in our past with high confidence, while a measurement of
\Omega_k < -10^-4 (which is positive curvature, a locally closed universe)
rules out false-vacuum eternal inflation as well, at the same confidence level.
In other words, negative curvature (a locally open universe) is consistent with
false-vacuum eternal inflation but not with slow-roll eternal inflation, and
positive curvature falsifies both. Near-future experiments will dramatically
extend the sensitivity of \Omega_k measurements and constitute a sharp test of
these predictions.Comment: 16+2 pages, 2 figure
Optical absorption of spin ladders
We present a theory of phonon-assisted optical two-magnon absorption in
two-leg spin-ladders. Based on the strong intra-rung-coupling limit we show
that collective excitations of total spin S=0, 1 and 2 exist outside of the
two-magnon continuum. It is demonstrated that the singlet collective state has
a clear signature in the optical spectrum.Comment: 4 pages, 3 figure
Suppression of static stripe formation by next-neighbor hopping
We show from real-space Hartree-Fock calculations within the extended Hubbard
model that next-nearest neighbor (t') hopping processes act to suppress the
formation of static charge stripes. This result is confirmed by investigating
the evolution of charge-inhomogeneous corral and stripe phases with increasing
t' of both signs. We propose that large t' values in YBCO prevent static stripe
formation, while anomalously small t' in LSCO provides an additional reason for
the appearance of static stripes only in these systems.Comment: 4 pages, 5 figure
Pairing and Density Correlations of Stripe Electrons in a Two-Dimensional Antiferromagnet
We study a one-dimensional electron liquid embedded in a 2D antiferromagnetic
insulator, and coupled to it via a weak antiferromagnetic spin exchange
interaction. We argue that this model may qualitatively capture the physics of
a single charge stripe in the cuprates on length- and time scales shorter than
those set by its fluctuation dynamics. Using a local mean-field approach we
identify the low-energy effective theory that describes the electronic spin
sector of the stripe as that of a sine-Gordon model. We determine its phases
via a perturbative renormalization group analysis. For realistic values of the
model parameters we obtain a phase characterized by enhanced spin density and
composite charge density wave correlations, coexisting with subleading triplet
and composite singlet pairing correlations. This result is shown to be
independent of the spatial orientation of the stripe on the square lattice.
Slow transverse fluctuations of the stripes tend to suppress the density
correlations, thus promoting the pairing instabilities. The largest amplitudes
for the composite instabilities appear when the stripe forms an antiphase
domain wall in the antiferromagnet. For twisted spin alignments the amplitudes
decrease and leave room for a new type of composite pairing correlation,
breaking parity but preserving time reversal symmetry.Comment: Revtex, 28 pages incl. 5 figure
Metal-insulator transition in the one-dimensional Holstein model at half filling
We study the one-dimensional Holstein model with spin-1/2 electrons at
half-filling. Ground state properties are calculated for long chains with great
accuracy using the density matrix renormalization group method and extrapolated
to the thermodynamic limit. We show that for small electron-phonon coupling or
large phonon frequency, the insulating Peierls ground state predicted by
mean-field theory is destroyed by quantum lattice fluctuations and that the
system remains in a metallic phase with a non-degenerate ground state and
power-law electronic and phononic correlations. When the electron-phonon
coupling becomes large or the phonon frequency small, the system undergoes a
transition to an insulating Peierls phase with a two-fold degenerate ground
state, long-range charge-density-wave order, a dimerized lattice structure, and
a gap in the electronic excitation spectrum.Comment: 6 pages (LaTex), 10 eps figure
Next-to-leading BFKL phenomenology of forward-jet cross sections at HERA
We show that the forward-jet measurements performed at HERA allow for a
detailed study of corrections due to next-to-leading logarithms (NLL) in the
Balitsky-Fadin-Kuraev-Lipatov (BFKL) approach. While the description of the
d\sigma/dx data shows small sensitivity to NLL-BFKL corrections, these can be
tested by the triple differential cross section d\sigma/dxdk_T^2dQ^2 recently
measured. These data can be successfully described using a
renormalization-group improved NLL kernel while the standard
next-to-leading-order QCD or leading-logarithm BFKL approaches fail to describe
the same data in the whole kinematic range. We present a detailed analysis of
the NLL scheme and renormalization-scale dependences and also discuss the
photon impact factors.Comment: 15 pages, 9 figures, new title, NLL-BFKL saddle-point approximation
replaced by exact integratio
Six-minute walk distance after coronary artery bypass grafting compared with medical therapy in ischaemic cardiomyopathy
Background: In patients with ischaemic left ventricular dysfunction, coronary artery bypass surgery (CABG) may decrease mortality, but it is not known whether CABG improves functional capacity.
Objective: To determine whether CABG compared with medical therapy alone (MED) increases 6 min walk distance in patients with ischaemic left ventricular dysfunction and coronary artery disease amenable to revascularisation.
Methods: The Surgical Treatment in Ischemic Heart disease trial randomised 1212 patients with ischaemic left ventricular dysfunction to CABG or MED. A 6 min walk distance test was performed both at baseline and at least one follow-up assessment at 4, 12, 24 and/or 36 months in 409 patients randomised to CABG and 466 to MED. Change in 6 min walk distance between baseline and follow-up were compared by treatment allocation.
Results: 6 min walk distance at baseline for CABG was mean 340±117 m and for MED 339±118 m. Change in walk distance from baseline was similar for CABG and MED groups at 4 months (mean +38 vs +28 m), 12 months (+47 vs +36 m), 24 months (+31 vs +34 m) and 36 months (−7 vs +7 m), P>0.10 for all. Change in walk distance between CABG and MED groups over all assessments was also similar after adjusting for covariates and imputation for missing values (+8 m, 95% CI −7 to 23 m, P=0.29). Results were consistent for subgroups defined by angina, New York Heart Association class ≥3, left ventricular ejection fraction, baseline walk distance and geographic region.
Conclusion: In patients with ischaemic left ventricular dysfunction CABG compared with MED alone is known to reduce mortality but is unlikely to result in a clinically significant improvement in functional capacity
Electronic and Magnetic Properties of Nanographite Ribbons
Electronic and magnetic properties of ribbon-shaped nanographite systems with
zigzag and armchair edges in a magnetic field are investigated by using a tight
binding model. One of the most remarkable features of these systems is the
appearance of edge states, strongly localized near zigzag edges. The edge state
in magnetic field, generating a rational fraction of the magnetic flux (\phi=
p/q) in each hexagonal plaquette of the graphite plane, behaves like a
zero-field edge state with q internal degrees of freedom. The orbital
diamagnetic susceptibility strongly depends on the edge shapes. The reason is
found in the analysis of the ring currents, which are very sensitive to the
lattice topology near the edge. Moreover, the orbital diamagnetic
susceptibility is scaled as a function of the temperature, Fermi energy and
ribbon width. Because the edge states lead to a sharp peak in the density of
states at the Fermi level, the graphite ribbons with zigzag edges show
Curie-like temperature dependence of the Pauli paramagnetic susceptibility.
Hence, it is shown that the crossover from high-temperature diamagnetic to
low-temperature paramagnetic behavior of the magnetic susceptibility of
nanographite ribbons with zigzag edges.Comment: 13 pages including 19 figures, submitted to Physical Rev
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