Spectroscopic studies of non-transition organometallic compounds

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Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

Two chlorodiorganotin(IV) complexes of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (MPPDA) have been synthesized by 1:1 mole-ratio reactions of the parent acid (MPPDAH) with Me2SnCl2 or Et2SnCl2 in dry methanol. The products have been characterized by Raman and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy, elemental analysis, and mass spectrometry. Single-crystal X-ray diffraction studies indicate that both complexes have distorted trigonal bipyramidal geometries around the central Sn atom. (C) 2008 Elsevier B.V. All rights reserved

CCDC 664573: Experimental Crystal Structure Determination

Related Article: Zia-ur-Rehman, M.M.Barsan, I.Wharf, N.Muhammad, S.Ali, A.Meetsma, I.S.Butler|2008|Inorg.Chim.Acta|361|3322|doi:10.1016/j.ica.2008.05.006,An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.

CCDC 664574: Experimental Crystal Structure Determination

Related Article: Zia-ur-Rehman, M.M.Barsan, I.Wharf, N.Muhammad, S.Ali, A.Meetsma, I.S.Butler|2008|Inorg.Chim.Acta|361|3322|doi:10.1016/j.ica.2008.05.006,An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.