Spin Hall Effect and Spin Transfer in Disordered Rashba Model

Based on numerical study of the Rashba model, we show that the spin Hall conductance remains finite in the presence of disorder up to a characteristic length scale, beyond which it vanishes exponentially with the system size. We further perform a Laughlin's gauge experiment numerically and find that all energy levels cannot cross each other during an adiabatic insertion of the flux in accordance with the general level-repulsion rule. It results in zero spin transfer between two edges of the sample as each state always evolves back after the insertion of one flux quantum, in contrast to the quantum Hall effect. It implies that the topological spin Hall effect vanishes with the turn-on of disorder.Comment: 4 pages, 4 figures final versio

Quantum Spin Hall Effect and Topologically Invariant Chern Numbers

We present a topological description of quantum spin Hall effect (QSHE) in a two-dimensional electron system on honeycomb lattice with both intrinsic and Rashba spin-orbit couplings. We show that the topology of the band insulator can be characterized by a $2\times 2$ traceless matrix of first Chern integers. The nontrivial QSHE phase is identified by the nonzero diagonal matrix elements of the Chern number matrix (CNM). A spin Chern number is derived from the CNM, which is conserved in the presence of finite disorder scattering and spin nonconserving Rashba coupling. By using the Laughlin's gedanken experiment, we numerically calculate the spin polarization and spin transfer rate of the conducting edge states, and determine a phase diagram for the QSHE.Comment: 4 pages and 4 figure

Mott physics, sign structure, ground state wavefunction, and high-Tc superconductivity

In this article I give a pedagogical illustration of why the essential problem of high-Tc superconductivity in the cuprates is about how an antiferromagnetically ordered state can be turned into a short-range state by doping. I will start with half-filling where the antiferromagnetic ground state is accurately described by the Liang-Doucot-Anderson (LDA) wavefunction. Here the effect of the Fermi statistics becomes completely irrelevant due to the no double occupancy constraint. Upon doping, the statistical signs reemerge, albeit much reduced as compared to the original Fermi statistical signs. By precisely incorporating this altered statistical sign structure at finite doping, the LDA ground state can be recast into a short-range antiferromagnetic state. Superconducting phase coherence arises after the spin correlations become short-ranged, and the superconducting phase transition is controlled by spin excitations. I will stress that the pseudogap phenomenon naturally emerges as a crossover between the antiferromagnetic and superconducting phases. As a characteristic of non Fermi liquid, the mutual statistical interaction between the spin and charge degrees of freedom will reach a maximum in a high-temperature "strange metal phase" of the doped Mott insulator.Comment: 12 pages, 12 figure

Phase diagram of the frustrated, spatially anisotropic S=1 antiferromagnet on a square lattice

We study the S=1 square lattice Heisenberg antiferromagnet with spatially anisotropic nearest neighbor couplings $J_{1x}$, $J_{1y}$ frustrated by a next-nearest neighbor coupling $J_{2}$ numerically using the density-matrix renormalization group (DMRG) method and analytically employing the Schwinger-Boson mean-field theory (SBMFT). Up to relatively strong values of the anisotropy, within both methods we find quantum fluctuations to stabilize the N\'{e}el ordered state above the classically stable region. Whereas SBMFT suggests a fluctuation-induced first order transition between the N\'{e}el state and a stripe antiferromagnet for $1/3\leq J_{1x}/J_{1y}\leq 1$ and an intermediate paramagnetic region opening only for very strong anisotropy, the DMRG results clearly demonstrate that the two magnetically ordered phases are separated by a quantum disordered region for all values of the anisotropy with the remarkable implication that the quantum paramagnetic phase of the spatially isotropic $J_{1}$-$J_{2}$ model is continuously connected to the limit of decoupled Haldane spin chains. Our findings indicate that for S=1 quantum fluctuations in strongly frustrated antiferromagnets are crucial and not correctly treated on the semiclassical level.Comment: 10 pages, 10 figure

Mean-Field Description of Phase String Effect in the t−Jt-J Model

A mean-field treatment of the phase string effect in the $t-J$ model is presented. Such a theory is able to unite the antiferromagnetic (AF) phase at half-filling and metallic phase at finite doping within a single theoretical framework. We find that the low-temperature occurrence of the AF long range ordering (AFLRO) at half-filling and superconducting condensation in metallic phase are all due to Bose condensations of spinons and holons, respectively, on the top of a spin background described by bosonic resonating-valence-bond (RVB) pairing. The fact that both spinon and holon here are bosonic objects, as the result of the phase string effect, represents a crucial difference from the conventional slave-boson and slave-fermion approaches. This theory also allows an underdoped metallic regime where the Bose condensation of spinons can still exist. Even though the AFLRO is gone here, such a regime corresponds to a microscopic charge inhomogeneity with short-ranged spin ordering. We discuss some characteristic experimental consequences for those different metallic regimes. A perspective on broader issues based on the phase string theory is also discussed.Comment: 18 pages, five figure

Thermocatalytic syntheses of highly defective hybrid nano-catalysts for photocatalytic hydrogen evolution

Defects play important roles in many catalytic processes, particularly for photocatalytic processes in semiconductors as they can alter the band structures and affect the excited electron–hole recombination pathways/lifetimes of semiconductors. In this report, we described the development of a facile route to the production of highly defective photocatalysts. Firstly, organic species were bound onto the surface of a metal oxide semiconductor catalyst, followed by a relatively low temperature ageing in N2, to remove the organics and to attract oxygen molecules from the surface, generating oxygen vacancies. In particular, we introduced a co-catalyst during the syntheses, which acted as a thermocatalyst to promote full oxidation of the organics, leaving more oxygen vacancies at the surface and to form intimate heterojunctions with host-catalysts to further drive the photocatalytic hydrogen evolution. The hydrogen evolution rate for our developed NiO–TiO2 defective heterojunctions in a sacrificial system was measured at ca. 1.41 mmol g−1 h−1, which was much higher than those of comparable catalysts reported in the literature (that generally display hydrogen evolution rates <0.4 mmol g−1 h−1). Computational simulation, together with other analytical techniques, suggested that the generated surface oxygen vacancies could induce a series of impurity energy levels within the VBM and CBM of TiO2 that narrowed the electron transmission gap in the TiO2 and acted as active sites for the reaction between adsorbed H2O and photoinduced trapped electrons to produce H2

Magnetic Incommensurability in Doped Mott Insulator

In this paper we explore the incommensurate spatial modulation of spin-spin correlations as the intrinsic property of the doped Mott insulator, described by the $t-J$ model. We show that such an incommensurability is a direct manifestation of the phase string effect introduced by doped holes in both one- and two-dimensional cases. The magnetic incommensurate peaks of dynamic spin susceptibility in momentum space are in agreement with the neutron-scattering measurement of cuprate superconductors in both position and doping dependence. In particular, this incommensurate structure can naturally reconcile the neutron-scattering and NMR experiments of cuprates.Comment: 12 pages (RevTex), five postscript figure