Synthesized polyimide membranes for pervaporation separations of toluene/iso-octane mixtures

textSeparation of aromatic/aliphatic hydrocarbon mixtures by pervaporation has been of increasing interest in recent decades. Dozens of polymer materials have been reported for separations of benzene/cyclohexane and toluene/iso-ocatne mixtures. However, fundamental understanding of material structure and transport relations is not adequate to generalize guidelines for materials screening. The goals of this study are to tailor the structure of the polyimide materials, correlate the structure and transport relations, and establish guidelines for future materials. The 3, 5-Diaminobenzoic acid (DABA) containing polyimides were synthesized by both chemical and thermal solution imidization. The synthesized polyimides were formed into dense films by solution casting. The physical properties of the polyimides synthesized with monomers: 2, 2-bis (3, 4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA), 4, 6-trimethyl-1, 3-phenylendiamine (DAM) and DABA, were characterized by DSC, WAXD, GPC and density. The chemical structures were assessed by FTIR and NMR. The pervaporation and sorption of the synthesized polyimide membranes were tested in toluene/iso-octane mixtures at 100°C. The structure- transport property relations were established for the 6FDA-DAM/DABA membranes. The 6FDA-DAM/DABA polyimides were crosslinked by ethylene glycol. The pervaporation and sorption of the crosslinked membranes were tested in toluene/iso-octane mixtures at 100°C. Thermal imidization was found to give a higher imidization degree than chemical imidization. As a result, the polyimides made by chemical imidization contain a higher percentage of carboxylic acid groups than those made by thermal imidization. Chemical imidization gives higher film density, glass transition temperature and lower flux and higher selectivity for the toluene/iso-octane pervaporation than the thermally imidized membranes because of the higher carboxylic acid concentration. The chemically imidized membranes are slightly brittle after the crosslinking. Only the thermal imidization membranes have good flexibility and its pervaporation selectivity improves significantly after the crosslinking. Solubility selectivity and diffusivity selectivity of the 6FDA-DAM/DABA membranes were correlated with solubility parameters and fractional free volume, respectively. The structure-mass transport relations show that for the 6FDA-DAM/DABA membranes, both solubility selectivity and diffusivity selectivity contribute to the pervaporation selectivity. For the chemically imidized membranes, increased DABA concentration has a positive effect on solubility selectivity and diffusivity selectivity. For the thermally imidized membranes, increased DABA concentration has a significant effect on diffusivity selectivity only.Chemical Engineerin

Morphological Dependence of Star Formation Properties for the Galaxies in the Merging Galaxy Cluster A2255

The merging cluster of galaxies A2255 is covered by the Sloan Digital Sky Survey (SDSS) survey. In this paper we perform a morphological classification on the basis of the SDSS imaging and spectral data, and investigate the morphological dependence of the star formation rates (SFRs) for these member galaxies. As we expect, a tight correlation between the normalized SFR by stellar mass (SFR/M$_*$) and the H$\alpha$ equivalent width is found for the late-type galaxies in A2255. The correlation of SFR/M$_*$ with the continuum break strength at 4000 \AA is also confirmed. The SFR/M$_*$ - M$_*$ correlation is found for both the early- and late-type galaxies, indicating that the star formation activity tends to be suppressed when the assembled stellar mass M$_*$) increases, and this correlation is tighter and steeper for the late-type cluster galaxies. Compared with the mass range of field spiral galaxies, only two massive late-type galaxies with M$_*>10^{11}$ M$_{\odot}$ are survived in A2255, suggesting that the gas disks of massive spiral galaxies could have been tidally stripped during cluster formation. Additionally, the SFR variation with the projected radial distance are found to be heavily dependent upon galaxy morphology: the early-type galaxies have a very weak inner decrease in SFR/M$_*$, while the inner late-type galaxies tend to have higher SFR/M$_*$ values than the outer late-types. This may suggest that the galaxy-scale turbulence stimulated by the merging of subclusters might have played different roles on early- and late-type galaxies, which leads to a suppression of the star formation activity for E/S0 galaxies and a SFR enhancement for spiral and irregular galaxies.Comment: 21 pages, including 7 EPS figures and 1 tables, uses aastex.cls, Accepted by the A

Ultrafast magnetization enhancement and spin current injection in magnetic multilayers by exciting the nonmagnetic metal

A systematic investigation of spin injection behavior in Au/FM (FM = Fe and Ni) multilayers is performed using the superdiffusive spin transport theory. By exciting the nonmagnetic layer, the laser-induced hot electrons may transfer spin angular momentum into the adjacent ferromagnetic (FM) metals resulting in ultrafast demagnetization or enhancement. We find that these experimental phenomena sensitively depend on the particular interface reflectivity of hot electrons and may reconcile the different observations in experiment. Stimulated by the ultrafast spin currents carried by the hot electrons, we propose the multilayer structures to generate highly spin polarized currents for development of future ultrafast spintronics devices. The spin polarization of the electric currents carried by the hot electrons can be significantly enhanced by the joint effects of bulk and interfacial spin filtering. Meanwhile the intensity of the generated spin current can be optimized by varying the number of repeated stacking units and the thickness of each metallic layer.Comment: 11 pages, 6 figure

Isolation and characterization of 13 new microsatellite markers in the triangle mussel (Hyriopsis cumingii)

Microsatellite enriched library of Hyriopsis cumingii was constructed according to the strong affinity between biotin and streptavidin. One hundred clones with foreign inserts were sequenced and 65 clones were screened for usable microsatellites, of which 36 were deemed unique, of sufficient length (more than 8 repeats) and possessed adequate flanking regions for primer designment. Among 36 primer pairs designed, 25 yielded scorable amplification products. Upon testing 30 individuals were sampled using the 25 pair primers from Dongting Lake of Hunan Province, China. Then thirteen polymorphic microsatellite markers were isolated and characterized. These loci exhibited high levels of genetic polymorphism, so the observed number of alleles per locus ranged from 4 to 9. The ranges of observed and expected heterozygosity were 0.2543 to 0.8913 and 0.3629 to 0.8217, respectively, and the average polymorphic information content was 0.5198. Two microsatellite loci were significantly deviated from Hardy-Weinberg equilibrium due to the presence of null alleles, and no linkage disequilibrium found. These microsatellite loci will be useful for assessing the genetic diversity and population structure of H. cumingii

5-Methyl­isoxazole-4-carboxylic acid

In the title compound, C5H5NO3, the mol­ecule lies on a crystallographic mirror plane with one half-mol­ecule in the asymmetric unit. An intramolecular C—H⋯O inter­action is present. In the crystal, strong inter­molecular O—H⋯N hydrogen bonds result in the formation of a linear chain structure along [100], and there are also weak C—H⋯O hydrogen bonds between the chains which help to stabilize the crystal packing