203,341 research outputs found

    Random Isotropic Structures and Possible Glass Transitions in Diblock Copolymer Melts

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    We study the microstructural glass transitions in diblock-copolymer melts using a thermodynamic replica approach. Our approach performs an expansion in terms of the natural smallness parameter -- the inverse of the scaled degree of polymerization, which allows us to systematically study the approach to mean-field behavior as the degree of polymerization increases. We find that in the limit of infinite long polymer chains, both the onset of glassiness and the vitrification transition (Kauzmann temperature) collapse to the mean-field spinodal, suggesting that the spinodal can be regarded as the mean-field signature for glass transitions in this class of systems. We also study the order-disorder transitions (ODT) within the same theoretical framework; in particular, we include the leading-order fluctuation corrections due to the cubic interaction in the coarse-grained Hamiltonian, which has been ignored in previous works on the ODT in block copolymers. We find that the cubic term stabilizes both the ordered (body-centered-cubic) phase and the glassy state relative to the disordered phase. While in melts of symmetric copolymers the glass transition always occurs after the order-disorder transition (below the ODT temperature), for asymmetric copolymers, it is possible that the glass transition precedes the ordering transition.Comment: An error corrected in the referenc

    Further results on independent Metropolis-Hastings-Klein sampling

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    Sampling from a lattice Gaussian distribution is emerging as an important problem in coding and cryptography. This paper gives a further analysis of the independent Metropolis-Hastings-Klein (MHK) algorithm we presented at ISIT 2015. We derive the exact spectral gap of the induced Markov chain, which dictates the convergence rate of the independent MHK algorithm. Then, we apply the independent MHK algorithm to lattice decoding and obtained the decoding complexity for solving the CVP as Õ(e∥Bx-c∥2 / mini ∥b̂i∥2). Finally, the tradeoff between decoding radius and complexity is also established

    Quantum storage and information transfer with superconducting qubits

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    We design theoretically a new device to realize the general quantum storage based on dcSQUID charge qubits. The distinct advantages of our scheme are analyzed in comparison with existing storage scenarios. More arrestingly, the controllable XY-model spin interaction has been realized for the first time in superconducting qubits, which may have more potential applications besides those in quantum information processing. The experimental feasibility is also elaborated.Comment: 4 pages, 2 figure

    Electron-hydrogen scattering in Faddeev-Merkuriev integral equation approach

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    Electron-hydrogen scattering is studied in the Faddeev-Merkuriev integral equation approach. The equations are solved by using the Coulomb-Sturmian separable expansion technique. We present SS- and PP-wave scattering and reactions cross sections up to the H(n=4)H(n=4) threshold.Comment: 2 eps figure
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