Wearable solid-state capacitors based on two-dimensional material all-textile heterostructures.

Two-dimensional (2D) materials are a rapidly growing area of interest for wearable electronics, due to their flexible and unique electrical properties. All-textile-based wearable electronic components are key to enable future wearable electronics. Single component electrical elements have been demonstrated; however heterostructure-based assemblies, combining electrically conductive and dielectric textiles such as all-textile capacitors are currently missing. Here we demonstrate a superhydrophobic conducting fabric with a sheet resistance Rs∼ 2.16 kΩ□-1, and a pinhole-free dielectric fabric with a relative permittivity εr∼ 2.35 enabled by graphene and hexagonal boron nitride inks, respectively. The different fabrics are then integrated to engineer the first example of an all-textile-based capacitive heterostructure with an effective capacitance C ∼ 26 pF cm-2 and a flexibility of ∼1 cm bending radius. The capacitor sustains 20 cycles of repeated washing and more than 100 cycles of repeated bending. Finally, an AC low-pass filter with a cut-off frequency of ∼15 kHz is integrated by combining the conductive polyester and the capacitor. These results pave the way toward all-textile vertically integrated electronic devices.Royal Academy of Engineering National Natural Science Foundation of China Isaac Newton Trust Graduate Students Innovation Project of Jiangsu Province in Chin

Fully inkjet-printed two-dimensional material field-effect heterojunctions for wearable and textile electronics.

Fully printed wearable electronics based on two-dimensional (2D) material heterojunction structures also known as heterostructures, such as field-effect transistors, require robust and reproducible printed multi-layer stacks consisting of active channel, dielectric and conductive contact layers. Solution processing of graphite and other layered materials provides low-cost inks enabling printed electronic devices, for example by inkjet printing. However, the limited quality of the 2D-material inks, the complexity of the layered arrangement, and the lack of a dielectric 2D-material ink able to operate at room temperature, under strain and after several washing cycles has impeded the fabrication of electronic devices on textile with fully printed 2D heterostructures. Here we demonstrate fully inkjet-printed 2D-material active heterostructures with graphene and hexagonal-boron nitride (h-BN) inks, and use them to fabricate all inkjet-printed flexible and washable field-effect transistors on textile, reaching a field-effect mobility of ~91 cm2 V-1 s-1, at low voltage (<5 V). This enables fully inkjet-printed electronic circuits, such as reprogrammable volatile memory cells, complementary inverters and OR logic gates

Thermal insulating property of an optically-active polyurethane-based silicon aerogel

Improving the mechanical property of the silicon aerogel while maintaining its excellent thermal insulation performance is still a big challenge in developing the next-generation thermal insulation materials. To solve this problem, the optically active polyurethane aerogel composite is developed via the sol-gel method to combine the advantages of the thermal insulation performance of the silicon aerogel and the mechanical property of the end-capped siloxane optically-active polyurethane. The prepared composite is characterized by the SEM, the Fourier transform infrared spectroscopy, the absorption-desorption curve, the thermal analysis, and the mechanical property. Results show that the composite has intact pores with high surface area and pore volume, leading to excellent thermal insulation and mechanical performance. Moreover, its thermal insulation performance is greatly enhanced due to the better distributed small pores and the thermal reflective effect of binaphthyl groups which collaboratively block heat loss from thermal conduction and thermal radiation. The thermal stability is similar to silicon aerogel and its heat resistance temperature is 445℃. The addition of macromolecular polymers increases the contact points between particles, the contact areas between particles of the network skeletons, and the supporting effect of the skeleton material, which ensures the stability of the material structure. The compressive modulus of prepared composite is up to 2.465 MPa, which is 600 times more than that of the pure SiO2 aerogels

Decolorization of Methylene Blue with TiO2 Sol via UV Irradiation Photocatalytic Degradation

TiO2 sol was prepared for the degradation of methylene blue (MB) solution under ultraviolet (UV) irradiation. The absorption spectra of MB indicated that the maximum wavelength, 663 nm, almost kept the same. The performance of 92.3% for color removal was reached after 160 min. The particle size of TiO2 sol was about 22.5 nm. X-ray diffraction showed that TiO2 consisted of a single anatase phase. The small size and anatase phase probably resulted in high photocatalytic activity of TiO2 sol. The degradation ratio decreased as the initial concentration of MB increased. The photodegradation efficiency decreased in the order of pH 2>pH 9>pH 7. Regarding catalyst load, the degradation increased with the mass of catalyst up to an amount of 1.5 g⋅L−1 then decreased as the mass continued to increase. The addition of H2O2 to TiO2 sol resulted in an increase on the degradation ratio

SURFACE TREATMENT OF ANTI-CREASE FINISHED COTTON FABRIC BASED ON SOL–GEL TECHNOLOGY

The silica sol was applied onto 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) finished cotton fabrics with the attempt to improve the physical properties especially the tensile strength which had a big loss in the previous anti-crease finishing processing. The parameters including the dosage of the coupling agent, the concentration and pH of the sol and the processing methods were studied in detail. Compared to the sample finished with BTCA, 11.8% of the increase in the crease recovery angle and 18.6% of the enhancement in the tensile strength of the cotton fabric also treated with silica sol in the better selected conditions were obtained. The abrasion resistance was also improved.Sol–gel, cotton fabric, anti-crease finishing, strength loss

Thermoplastic Polyurethane Based on the 3d Printing Fashion Clothing- Conceptual Model of The Fashion Industry

The application of 3D printing technology has been relatively slow in the fashion industry. Both in the fashion industry and in 3D printing, the material used plays a very important role. In this direction, thermoplastic polyurethane (TPU) is one material that has started to grab the attention of researchers, producers, and customers. While many have studied 3D printing technology using thermoplastic polyurethane material in the fashion industry from different perspectives, fewer researchers have addressed the actual adoption of thermoplastic polyurethane based 3D printing in the fashion industry. Thus, the present research has been focused to propose an adoption model for thermoplastic polyurethane based 3D-printed fashion clothes. Factor analysis was conducted to find and analyse the most relevant factors. Further exploratory factor analysis was conducted to test the proposed model. The study proposed a model for adoption based on four factors: motivation to buy, customer attitude, and the challenges and benefits associated with the adoption of thermoplastic polyurethane based 3-D printed fashion clothes

Wearable solid-state capacitors based on two-dimensional material all-textile heterostructures.

Two-dimensional (2D) materials are a rapidly growing area of interest for wearable electronics, due to their flexible and unique electrical properties. All-textile-based wearable electronic components are key to enable future wearable electronics. Single component electrical elements have been demonstrated; however heterostructure-based assemblies, combining electrically conductive and dielectric textiles such as all-textile capacitors are currently missing. Here we demonstrate a superhydrophobic conducting fabric with a sheet resistance Rs∼ 2.16 kΩ□-1, and a pinhole-free dielectric fabric with a relative permittivity εr∼ 2.35 enabled by graphene and hexagonal boron nitride inks, respectively. The different fabrics are then integrated to engineer the first example of an all-textile-based capacitive heterostructure with an effective capacitance C ∼ 26 pF cm-2 and a flexibility of ∼1 cm bending radius. The capacitor sustains 20 cycles of repeated washing and more than 100 cycles of repeated bending. Finally, an AC low-pass filter with a cut-off frequency of ∼15 kHz is integrated by combining the conductive polyester and the capacitor. These results pave the way toward all-textile vertically integrated electronic devices.Royal Academy of Engineering National Natural Science Foundation of China Isaac Newton Trust Graduate Students Innovation Project of Jiangsu Province in Chin

Optimization of Natural Dye Extracted from Phytolaccaceae Berries and Its Mordant Dyeing Properties on Natural Silk Fabric

A moderate approach was used to extract natural dye from wild Phytolaccaceae berries, and the stability and dyeing properties on the silk fabric of the exacted Phytolaccaceae natural dye was investigated. Via stability analysis, the natural dye had excellent stability during heating, pH or adding Metal ions. When the dyeing temperature was 30ºC, the K/S value of the dyed silk fabric was 6.3, and with SnCl2 mordant, the K/S value was increased 14.3%. The rubbing and washing fastness via metal mordant were increased by 0.5–1.5 grade compared to the fastness of fabric treated with direct dyeing method