食品加工廃棄物から効果的なアンモニア生産のための酵母の合成生物学的育種

京都大学新制・課程博士博士(農学)甲第23237号農博第2444号新制||農||1083(附属図書館)学位論文||R3||N5327京都大学大学院農学研究科応用生命科学専攻(主査)教授 植田 充美, 教授 小川 順, 教授 栗原 達夫学位規則第4条第1項該当Doctor of Agricultural ScienceKyoto UniversityDFA

Magnetic Structure of Umbral Dots Observed with Hinode Solar Optical Telescope

High resolution and seeing-free spectroscopic observation of a decaying sunspot was done with the Solar Optical Telescope aboard Hinode satellite. The target was NOAA 10944 located in the west side of the solar surface from March 2 to March 4, 2007. The umbra included many umbral dots (UDs) with size of ~300 km in continuum light. We report the magnetic structures and Doppler velocity fields around UDs, based on the Milne-Eddington inversion of the two iron absorption lines at 6302 angstrom. The histograms of magnetic field strength(B), inclination angle(i), and Doppler velocity(v) of UDs showed a center-to-limb variation. Observed at disk center, UDs had (1)slightly smaller field strength (Delta B=-17 Gauss) and (2)relative blue shifts (Delta v=28 m s-1) compared to their surroundings. When the sunspot got close to the limb, UDs and their surroundings showed almost no difference in the magnetic and Doppler values. This center-to-limb variation can be understood by the formation height difference in a cusp-shaped magnetized atmosphere around UDs, due to the weakly magnetized hot gas intrusion. In addition, some UDs showed oscillatory light curves with multiple peaks around 10 min, which may indicate the presence of the oscillatory convection. We discuss our results in the frameworks of two theoretical models, the monolithic model (Schussler & Vogler 2006) and the field-free intrusion model (Spruit & Scharmer 2006).Comment: 8 pages, 8 figures, accepted for publication in PAS

Sustainable Biological Ammonia Production towards a Carbon-Free Society

脱炭素・次世代エネルギーとしてのアンモニアの食品加工廃棄物からのバイオ生産プラットフォーム --脱炭素社会構築へのバイオテクノロジーによる貢献をめざして--. 京都大学プレスリリース. 2021-09-06.A sustainable society was proposed more than 50 years ago. However, it is yet to be realised. For example, the production of ammonia, an important chemical widely used in the agriculture, steel, chemical, textile, and pharmaceutical industries, still depends on fossil fuels. Recently, biological approaches to achieve sustainable ammonia production have been gaining attention. Moreover, unlike chemical methods, biological approaches have a lesser environmental impact because ammonia can be produced under mild conditions of normal temperature and pressure. Therefore, in previous studies, nitrogen fixation by nitrogenase, including enzymatic ammonia production using food waste, has been attempted. Additionally, the production of crops using nitrogen-fixing bacteria has been implemented in the industry as one of the most promising approaches to achieving a sustainable ammonia economy. Thus, in this review, we described previous studies on biological ammonia production and showed the prospects for realising a sustainable society

Static magnetic moments revealed by muon spin relaxation and thermodynamic measurements in quantum spin ice Yb2_2Ti2_2O7_7

We present muon spin relaxation ($\mu$SR) and specific-heat versus temperature $C(T)$ measurements on polycrystalline and single-crystal samples of the pyrochlore magnet Yb$_2$Ti$_2$O$_7$. $C(T)$ exhibits a sharp peak at a $T_\mathrm{C}$ of 0.21 and 0.26~K for the single-crystal and polycrystalline samples respectively. For both samples, the magnetic entropy released between 50~mK and 30~K amounts to $R\ln2$ per Yb. At temperatures below $T_\mathrm{C}$ we observe a steep drop in the asymmetry of the zero-field $\mu$SR time spectra at short time scales, as well as a decoupling of the muon spins from the internal field in longitudinal magnetic fields of $\leq0.25$~T for both the polycrystalline and single-crystal samples. These muon data are indicative of static magnetic moments. Our results are consistent with the onset of long-range magnetic order in both forms of Yb$_2$Ti$_2$O$_7$.Comment: 6 pages, 4 figures, accepted to PR

Magnetic order in pyrochlore iridate Nd2_2Ir2_2O7_7 probed by muon spin relaxation

Muon-spin relaxation results on the pyrochlore iridate Nd$_2$Ir$_2$O$_7$ are reported. Spontaneous coherent muon-spin precession below the metal-insulator transition (MIT) temperature of about 33 K is observed, indicating the appearance of a long-ranged magnetic ordering of Ir$^{4+}$ moments. With further decrease in temperature, the internal field at the muon site increases again below about 9 K. The second increase of internal field suggests the ordering of Nd$^{3+}$ moments, which is consistent with a previous neutron experiment. Our results suggest that the MIT and magnetic ordering of Ir$^{4+}$ moments have a close relationship and that the large spin-orbit coupling of Ir 5\textit{d} electrons plays a key role for both MIT and the mechanism of the magnetic ordering in pyrochlore iridates in the insulting ground state.Comment: 5 pages, 3 figures. Accepted by Physical Review B (rapid communications