Entrepreneurial intentions among students: towards a re-focused research agenda

Purpose – This paper aims to address the need for a re-focused research agenda in relation to graduate entrepreneurship. An important theme for some years has been the effort to monitor attitudes and intentions of students towards starting up their own businesses. It is timely, however, to raise some questions about both the impact of this research and likewise the general approach it has taken in understanding the phenomenon of graduate entrepreneurship. Design/methodology/approach – The paper draws on a large data set (over 8,000 students) from one UK region. Specifically, it presents data from the 2007/2008 Entrepreneurial Intentions (EI) survey within the Yorkshire and Humberside region and reflects back over previous iterations of this research. Findings – The paper identifies three key outcomes. First, it establishes that across all years of the survey a substantial minority of students consistently hold relatively strong start-up intentions. Second, the paper highlights that, despite considerable efforts to increase the numbers moving to start-up, little impact is discernible. Third, the paper suggests that, although the EI survey is useful as a stock-taking exercise, it fails to address critical questions around the impact of higher education on entrepreneurship and the transition from entrepreneurial intent to the act of venture creation. Originality/value – The paper provides an important positioning perspective on the relationship between higher education and graduate entrepreneurship. While highlighting the importance of the EI research, the paper establishes the need for a re-focused research agenda; one that is conceptually robust and with a focus on the student journey from higher education to graduate entrepreneur

Extending electron orbital precession to the molecular case: Can orbital alignment be used to observe wavepacket dynamics?

The complexity of ultrafast molecular photoionization presents an obstacle to the modelling of pump-probe experiments. Here, a simple optimized model of atomic rubidium is combined with a molecular dynamics model to predict quantitatively the results of a pump-probe experiment in which long range rubidium dimers are first excited, then ionized after a variable delay. The method is illustrated by the outline of two proposed feasible experiments and the calculation of their outcomes. Both of these proposals use Feshbach 87Rb2 molecules. We show that long-range molecular pump-probe experiments should observe spin-orbit precession given a suitable pump-pulse, and that the associated high-frequency beat signal in the ionization probability decays after a few tens of picoseconds. If the molecule was to be excited to only a single fine structure state state, then a low-frequency oscillation in the internuclear separation would be detectable through the timedependent ionization cross section, giving a mechanism that would enable observation of coherent vibrational motion in this molecule.Comment: 9 pages, 10 figures, PRA submissio

Optimal experiment design revisited: fair, precise and minimal tomography

Given an experimental set-up and a fixed number of measurements, how should one take data in order to optimally reconstruct the state of a quantum system? The problem of optimal experiment design (OED) for quantum state tomography was first broached by Kosut et al. [arXiv:quant-ph/0411093v1]. Here we provide efficient numerical algorithms for finding the optimal design, and analytic results for the case of 'minimal tomography'. We also introduce the average OED, which is independent of the state to be reconstructed, and the optimal design for tomography (ODT), which minimizes tomographic bias. We find that these two designs are generally similar. Monte-Carlo simulations confirm the utility of our results for qubits. Finally, we adapt our approach to deal with constrained techniques such as maximum likelihood estimation. We find that these are less amenable to optimization than cruder reconstruction methods, such as linear inversion.Comment: 16 pages, 7 figure

Detection of FeO towards SgrB2

We have observed the J=5-4 ground state transition of FeO at a frequency of 153 GHz towards a selection of galactic sources. Towards the galactic center source SgrB2, we see weak absorption at approximately the velocity of other features towards this source (62 km s$^{-1}$ LSR). Towards other sources, the results were negative as they were also for MgOH(3-2) and FeC(6-5). We tentatively conclude that the absorption seen toward SgrB2 is due to FeO in the hot ($\sim$ 500 K) relatively low density absorbing gas known to be present in this line of sight. This is the first (albeit tentative) detection of FeO or any iron--containing molecule in the interstellar gas. Assuming the observed absorption to be due to FeO, we estimate [FeO]/[SiO] to be of order or less than 0.002 and [FeO]/[H$_{2}$] of order $3 10^{-11}$. This is compatible with our negative results in other sources. Our results suggest that the iron liberated from grains in the shocks associated with SgrB2 remains atomic and is not processed into molecular form.Comment: 1 postscrit figure,10 page

Umklapp scattering of pairs in BCS superconductivity theory

The BCS theory of superconductivity is extended to recognize pairing of electrons by both normal and umklapp scattering. Application of the variational approach shows that coexistence of normal and umklapp scattering frustrates superconductivity.Comment: 9 pages, 5 figures. to be published in Journal of Physics: Condensed Matte