Electrodeposition from supercritical fluids

Recent studies have shown that it is possible to electrodeposit a range of materials, such as Cu, Ag and Ge, from various supercritical fluids, including hydrofluorocarbons and mixtures of CO2 with suitable co-solvents. In this perspective we discuss the relatively new field of electrodeposition from supercritical fluids. The perspective focuses on some of the underlying physical chemistry and covers both practical and scientific aspects of electrodeposition from supercritical fluids. We also discuss possible applications for supercritical fluid electrodeposition and suggest some key developments that are required to take the field to the next stage

Comparison of Measured and Calculated Specific Resistances of Pd/Pt Interfaces

We compare specific resistances (AR equals area A times resistance R) of sputtered Pd/Pt interfaces measured in two different ways with no-free-parameter calculations. One way gives 2AR(Pd/Pt) of 0.29 (0.03) fohm-m(2) and the other 0.17 (0.13) fohm-m(2). From these we derive a best estimate of 2AR(Pd/Pt) of 0.28 (0.06) fohm-m(2), which overlaps with no-free-parameter calculations: 2AR(predicted) of 0.30 (0.04) fohm-m(2) for flat, perfect interfaces, or 0.33 (0.04) fohm-m(2) for interfaces composed of 2 monolayers of a 50percent-50percent PdPt alloy. These results support three prior examples of agreement between calculations and measurements for pairs of metals having the same crystal structure and the same lattice parameter to within 1 percent. We also estimate the spin-flipping probability at Pd/Pt interfaces as 0.13 (0.08).Comment: 3 pages, 3 figures, submitted for publication New version has corrected value of delta(Pd/Pt

One-dimensional vertical dust strings in a glass box

The oscillation spectrum of a one-dimensional vertical dust string formed inside a glass box on top of the lower electrode in a GEC reference cell was studied. A mechanism for creating a single vertical dust string is described. It is shown that the oscillation amplitudes, resonance frequencies, damping coefficients, and oscillation phases of the dust particles separate into two distinct groups. One group exhibits low damping coefficients, increasing amplitudes and decreasing resonance frequencies for dust particles closer to the lower electrode. The other group shows high damping coefficients but anomalous resonance frequencies and amplitudes. At low oscillation frequencies, the two groups are also separated by a {\pi}-phase difference. One possible cause for the difference in behavior between the two groups is discussed

Saturation Dislocation Microstructures In A Copper Single Crystal During Fatigue In HClO4 Aqueous Solution

A copper single crystal was tested at room temperature in air and in a 0.1M HClO4 solution under the symmetric tension-compression load mode, with loading axis parallel to the [013] direction. The dislocation structures were characterised using the electron channeling contrast (ECC) technique of scanning electron microscopy (SEM) and using transmission electron microscopy (TEM). The results show that the saturation dislocation structures in samples subjected to corrosion fatigue in the 0.1M HClO4 aqueous solution manly had the form of cells, dislocation wall-like and veins, which differ from the dislocation structures of dislocation wall-like and veins in the air environment

Exchange interactions and temperature dependence of the magnetization in half--metallic Heusler alloys

We study the exchange interactions in half-metallic Heusler alloys using first-principles calculations in conjunction with the frozen-magnon approximation. The Curie temperature is estimated within both mean-field (MF) and random-phase-approximation (RPA) approaches. For the half-Heusler alloys NiMnSb and CoMnSb the dominant interaction is between the nearest Mn atoms. In this case the MF and RPA estimations differ strongly. The RPA approach provides better agreement with experiment. The exchange interactions are more complex in the case of full-Heusler alloys Co$_2$MnSi and Co$_2$CrAl where the dominant effects are the inter-sublattice interactions between the Mn(Cr) and Co atoms and between Co atoms at different sublattices. For these compounds we find that both MF and RPA give very close values of the Curie temperature slightly underestimating experimental quantities. We study the influence of the lattice compression on the magnetic properties. The temperature dependence of the magnetization is calculated using the RPA method within both quantum mechanical and classical approaches.Comment: New figures and discussio

Sensitivity of Ag/Al Interface Specific Resistances to Interfacial Intermixing

We have measured an Ag/Al interface specific resistance, 2AR(Ag/Al)(111) = 1.4 fOhm-m^2, that is twice that predicted for a perfect interface, 50% larger than for a 2 ML 50%-50% alloy, and even larger than our newly predicted 1.3 fOhmm^2 for a 4 ML 50%-50% alloy. Such a large value of 2ARAg/Al(111) confirms a predicted sensitivity to interfacial disorder and suggests an interface greater than or equal to 4 ML thick. From our calculations, a predicted anisotropy ratio, 2AR(Ag/Al)(001)/2AR(Ag/Al)(111), of more then 4 for a perfect interface, should be reduced to less than 2 for a 4 ML interface, making it harder to detect any such anisotropy.Comment: 3 pages, 2 figures, 1 table. In Press: Journal of Applied Physic

Large magnetothermal conductivity of HoMnO_3 single crystals and its relation to the magnetic-field induced transitions of magnetic structure

We study the low-temperature heat transport of HoMnO_3 single crystals to probe the magnetic structures and their transitions induced by magnetic field. It is found that the low-T thermal conductivity (\kappa) shows very strong magnetic-field dependence, with the strongest suppression of nearly 90% and the biggest increase of 20 times of \kappa compared to its zero-field value. In particular, some ``dip"-like features show up in \kappa(H) isotherms for field along both the ab plane and the c axis. These behaviors are found to shed new light on the complex H-T phase diagram and the field-induced re-orientations of Mn^{3+} and Ho^{3+} spin structures. The results also demonstrate a significant spin-phonon coupling in this multiferroic compound.Comment: 5 pages, 4 figures, accepted for publication in Phys. Rev.