51 research outputs found
A 1,1-dithiocarboxylate ligand with an easily derivatizable group. Synthesis and structure of tris[2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato]bismuth(III)
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Ruthenium(II) chloride complexes of the mesocyclic ligand 1,5-dithiacyclooctane 1-oxide. Preparation and structure of the "all-trans" complex
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Structure of a novel neutral lead(II) complex with dipropyldithiocarbamate
The synthesis and X-ray structure of a novel tetramer of Pb(II) with the dipropyldithiocarbamato ligand is described. The compound crystallizes in the triclinic space group P ̅1with a=9.576(2), b= 14.151(4), c=16.175(4) Å , α =104.84(2), β = 102.26(2), γ =90.62(2)ۥ , V=2065(1) Å 3. Unit cell dimensions and data collection were done at 130(1) K using graphite-monochromated Mo Kα radiation. The conventional R factor is 0.030 for 5323 unique observed reflections with the goodness- of-fit parameter = 1.35. The structure consists of a sulfur-bridged neutral tetrameric species where each Pb(II) ion is pentacoordinated
Neighboring group participation in organic redox reactions. 12. Effect of the transannular amide on thioether oxidation. Structure of the 6-oxo-1-thionia-5-azabicyclo[4.3.0]nonane cation
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Cu(II) AND Cu(I) COMPLEXES OF A MACROCYCLIC TETRATHIOETHER-INFLUENCE OF THE ANION ON STRUCTURE
Synthesis and structure of the mesocyclic compounds, 5-phenyl-l-thia-5-phosphacyclooctane, Cis-and trans-1,5-Diphenyl-1,5-diphosphacyclooctane and their phosphine oxides
Three 1.5-disubstituted eight-membered ring meSocycles, 5-phenyl-l-thia-5-phosphacyclooctane, 2, cis-and trans-1,5-diphenyl-1,5-diphosphacyclooctane. 5a and 5b, have been synthesized. The diastereomers 5a and 5b were separated by preparative HPLC and the stereochemical assignments confirmed by an X-ray crystal structure of 5b. The X-ray crystal structures of 5-phenyl-1-thia-5-phosphacyclooctane 5-oxide, 1, and trans-l,5-diphenyl-l,5-diphosphacyclooctane 1.5-dioxide, 3b, are also reported. MeSocycles 1, 3b and 5b are in the boat-chair conformation and are devoid of any indications of transannular interactions
Decomposition pathways of an alkaline fuel cell membrane material component via evolved gas analysis
Evidence of Transannular Bonding Interaction between Two Sulfur Atoms on Photolysis of Naphtho[1,8- ef
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