17,234 research outputs found

    Improved cosmological constraints on the curvature and equation of state of dark energy

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    We apply the Constitution compilation of 397 supernova Ia, the baryon acoustic oscillation measurements including the AA parameter, the distance ratio and the radial data, the five-year Wilkinson microwave anisotropy probe and the Hubble parameter data to study the geometry of the universe and the property of dark energy by using the popular Chevallier-Polarski-Linder and Jassal-Bagla-Padmanabhan parameterizations. We compare the simple χ2\chi^2 method of joined contour estimation and the Monte Carlo Markov chain method, and find that it is necessary to make the marginalized analysis on the error estimation. The probabilities of Ωk\Omega_k and waw_a in the Chevallier-Polarski-Linder model are skew distributions, and the marginalized 1σ1\sigma errors are Ωm=0.2790.008+0.015\Omega_m=0.279^{+0.015}_{-0.008}, Ωk=0.0050.011+0.006\Omega_k=0.005^{+0.006}_{-0.011}, w0=1.050.06+0.23w_0=-1.05^{+0.23}_{-0.06}, and wa=0.51.5+0.3w_a=0.5^{+0.3}_{-1.5}. For the Jassal-Bagla-Padmanabhan model, the marginalized 1σ1\sigma errors are Ωm=0.2810.01+0.015\Omega_m=0.281^{+0.015}_{-0.01}, Ωk=0.0000.006+0.007\Omega_k=0.000^{+0.007}_{-0.006}, w0=0.960.18+0.25w_0=-0.96^{+0.25}_{-0.18}, and wa=0.61.6+1.9w_a=-0.6^{+1.9}_{-1.6}. The equation of state parameter w(z)w(z) of dark energy is negative in the redshift range 0z20\le z\le 2 at more than 3σ3\sigma level. The flat Λ\LambdaCDM model is consistent with the current observational data at the 1σ1\sigma level.Comment: 10 figures, 12 pages, Classical and Quantum Gravity in press; v2 to match the pulished versio

    Oxygen reduction reaction activity in non-precious single-atom (M–N/C ) catalysts-contribution of metal and carbon/nitrogen framework-based sites.

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    We examine the performance of a number of single-atom M-N/C electrocatalysts with a common structure in order to deconvolute the activity of the framework N/C support from the metal M-N4 sites in M-N/Cs. The formation of the N/C framework with coordinating nitrogen sites is performed using zinc as a templating agent. After the formation of the electrically conducting carbon-nitrogen metal-coordinating network, we (trans)metalate with different metals producing a range of different catalysts (Fe-N/C, Co-N/C, Ni-N/C, Sn-N/C, Sb-N/C, and Bi-N/C) without the formation of any metal particles. In these materials, the structure of the carbon/nitrogen framework remains unchanged-only the coordinated metal is substituted. We assess the performance of the subsequent catalysts in acid, near-neutral, and alkaline environments toward the oxygen reduction reaction (ORR) and ascribe and quantify the performance to a combination of metal site activity and activity of the carbon/nitrogen framework. The ORR activity of the carbon/nitrogen framework is about 1000-fold higher in alkaline than it is in acid, suggesting a change in mechanism. At 0.80 VRHE, only Fe and Co contribute ORR activity significantly beyond that provided by the carbon/nitrogen framework at all pH values studied. In acid and near-neutral pH values (pH 0.3 and 5.2, respectively), Fe shows a 30-fold improvement and Co shows a 5-fold improvement, whereas in alkaline pH (pH 13), both Fe and Co show a 7-fold improvement beyond the baseline framework activity. The site density of the single metal atom sites is estimated using the nitrite adsorption and stripping method. This method allows us to deconvolute the framework sites and metal-based active sites. The framework site density of catalysts is estimated as 7.8 × 1018 sites g-1. The metal M-N4 site densities in Fe-N/C and Co-N/C are 9.4 × 1018 sites-1 and 4.8 × 1018 sites g-1, respectively

    Impact of elevated precipitation, nitrogen deposition and warming on soil respiration in a temperate desert

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    Abstract. Soil respiration (Rs) is the most important source of carbon dioxide emissions from soil to atmosphere. However, it is unclear what the interactive response of Rs would be to environmental changes such as elevated precipitation, nitrogen (N) deposition and warming, especially in unique temperate desert ecosystems. To investigate this an in situ field experiment was conducted in the Gurbantunggut Desert, northwest China, from September 2014 to October 2016. The results showed that precipitation and N deposition significantly increased Rs, but warming decreased Rs, except in extreme precipitation events, which was mainly through its impact on the variation of soil moisture at 5 cm depth. In addition, the interactive response of Rs to combinations of the factors was much less than that of any single-factor, and the main response was a positive effect, except for the response from the interaction of increased precipitation and high N deposition (60 kg N ha−1 yr−1). Although Rs was found to show a unimodal change pattern with the variation of soil moisture, soil temperature and soil NH4+-N content, and it was significantly positively correlated to soil dissolved organic carbon (DOC) and pH, a structural equation model found that soil temperature was the most important controlling factor. Those results indicated that Rs was mainly interactively controlled by the soil multi-environmental factors and soil nutrients, and was very sensitive to elevated precipitation, N deposition and warming. However, the interactions of multiple factors largely reduced between-year variation of Rs more than any single-factor, suggesting that the carbon cycle in temperate deserts could be profoundly influenced by positive carbon–climate feedback. </jats:p

    Phase Control of Nonadiabaticity-induced Quantum Chaos in An Optical Lattice

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    The qualitative nature (i.e. integrable vs. chaotic) of the translational dynamics of a three-level atom in an optical lattice is shown to be controllable by varying the relative laser phase of two standing wave lasers. Control is explained in terms of the nonadiabatic transition between optical potentials and the corresponding regular to chaotic transition in mixed classical-quantum dynamics. The results are of interest to both areas of coherent control and quantum chaos.Comment: 3 figures, 4 pages, to appear in Physical Review Letter
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