112 research outputs found
The possible origin of the higher magnetic phase transition in RuSr2Eu1.5Ce0.5Cu2O10 (Ru-1222)
Two magnetic transitions are observed in the magneto-superconducting
RuEu2-xCexSr2Cu2O10 (Ru-1222), at TM 160 K and TM2~80 K. Below TM2 the Ru
moments are weak-ferromagnetically ordered and wide ferromagnetic hysteresis
loops are observed, they become narrow and disappear at ~ 60-70 K. Above TM2,
(i) small antiferromagnetic-like hysteresis loops reappear with a peak in the
coercive fields around 120 K. (ii) A small peak at ~120 K is also observed in
the dc and ac susceptibility curves. The two phenomena are absent in the non-SC
x=1 samples. For x<1, the decrease of the Ce4+ content, is compensated by
non-homogeneous oxygen depletion, which may induce a reduction of Ru5+ ions to
Ru4+. The higher ordering temperature, TM, which does not change with x, may
result from Ru4+ rich clusters, in which the Ru4+-Ru4+ exchange interactions
are stronger than the Ru5+-Ru5+ interactions. In the superconducting
Ru1-xMoxSr2Eu1.5Ce0.5Cu2O10 (x=0-0.4) system, TM2 shifts to low temperature
with x (14 K for x=0.4), whereas TM is not affected by the Mo content,
indicating again that TM may not correspond to the main phase. Two scenarios
are suggested to explain the magnetic phenomena at TM2<T< TM. (i) They are due
to a small fraction of nano-size islands inside the crystal grains, in which
the Ru4+ concentration is high and are magnetically ordered below TM. (ii) The
presence of nanoparticles of a foreign minor extra Ru4+ magnetic phase of
Sr-Cu-Ru-O3, which orders at TM, in which Cu is distributed inhomogeneously in
both the Ru and Sr sitesComment: 11 pages, 10 figure
Testing Einstein's time dilation under acceleration using M\"ossbauer spectroscopy
The Einstein time dilation formula was tested in several experiments. Many
trials have been made to measure the transverse second order Doppler shift by
M\"{o}ssbauer spectroscopy using a rotating absorber, to test the validity of
this formula. Such experiments are also able to test if the time dilation
depends only on the velocity of the absorber, as assumed by Einstein's clock
hypothesis, or the present centripetal acceleration contributes to the time
dilation. We show here that the fact that the experiment requires -ray
emission and detection slits of finite size, the absorption line is broadened;
by geometric longitudinal first order Doppler shifts immensely. Moreover, the
absorption line is non-Lorenzian. We obtain an explicit expression for the
absorption line for any angular velocity of the absorber.
The analysis of the experimental results, in all previous experiments which
did not observe the full absorption line itself, were wrong and the conclusions
doubtful. The only proper experiment was done by K\"{u}ndig (Phys. Rev. 129
(1963) 2371), who observed the broadening, but associated it to random
vibrations of the absorber. We establish necessary conditions for the
successful measurement of a transverse second order Doppler shift by
M\"{o}ssbauer spectroscopy. We indicate how the results of such an experiment
can be used to verify the existence of a Doppler shift due to acceleration and
to test the validity of Einstein's clock hypothesis.Comment: 11 pages, 4 figure
The combinatorics of the Baer-Specker group
Denote the integers by Z and the positive integers by N.
The groups Z^k (k a natural number) are discrete, and the classification up
to isomorphism of their (topological) subgroups is trivial. But already for the
countably infinite power Z^N of Z, the situation is different. Here the product
topology is nontrivial, and the subgroups of Z^N make a rich source of examples
of non-isomorphic topological groups. Z^N is the Baer-Specker group.
We study subgroups of the Baer-Specker group which possess group theoretic
properties analogous to properties introduced by Menger (1924), Hurewicz
(1925), Rothberger (1938), and Scheepers (1996). The studied properties were
introduced independently by Ko\v{c}inac and Okunev. We obtain purely
combinatorial characterizations of these properties, and combine them with
other techniques to solve several questions of Babinkostova, Ko\v{c}inac, and
Scheepers.Comment: To appear in IJ
57Fe Mossbauer spectroscopy and magnetic measurements of oxygen deficient LaFeAsO
We report on the magnetic behavior of oxygen deficient LaFeAsO1-x (x-0.10)
compound, prepared by one-step synthesis, which crystallizes in the tetragonal
(S.G. P4/nmm) structure at room temperature. Resistivity measurements show a
strong anomaly near 150 K, which is ascribed to the spin density wave (SDW)
instability. On the other hand, dc magnetization data shows paramagnetic-like
features down to 5 K, with an effective moment of 0.83 mB/Fe. 57Fe Mossbauer
studies (MS) have been performed at 95 and 200 K. The spectra at both
temperatures are composed of two sub-spectra. At 200 K the major one (88%), is
almost a singlet, and corresponds to those Fe nuclei, which have two oxygen
ions in their close vicinity. The minor one, with a large quadrupole splitting,
corresponds to Fe nuclei, which have vacancies in their immediate neighborhood.
The spectrum at 95 K, exhibits a broadened magnetic split major (84%)
sub-spectrum and a very small magnetic splitting in the minor subspectrum. The
relative intensities of the subspectra facilitate in estimating the actual
amount of oxygen vacancies in the compound to be 7.0(5)%, instead of the
nominal LaFeAsO0.90. These results, when compared with reported 57Fe MS of
non-superconducting LaFeAsO and superconducting LaFeAsO0.9F0.1, confirm that
the studied LaFeAsO0.93 is a superconductivity-magnetism crossover compound of
the newly discovered Fe based superconducting family.Comment: 7 pages text + Figs : Comments/suggestions welcome
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Polar and Magnetic Mn2FeMO6 (M = Nb, Ta) with LiNbO3-type Structure - High Pressure Synthesis
Polar oxides are of much interest in materials science and engineering. Their symmetry-dependent properties such as ferroelectricity/multiferroics, piezoelectricity, pyroelectricity, and second-order harmonic generation (SHG) effect are important for technological applications. However, polar crystal design and synthesis is challenging, because multiple effects, such as steric or dipole-dipole interactions, typically combine to form non-polar structures; so the number of known polar materials, especially polar magnetoelectric materials, is still severely restricted. Therefore, it is necessary for the material science community to develop new strategies to create these materials
Defining the roles of the threefold channels in iron uptake, iron oxidation and iron-core formation in ferritin: a study aided by site-directed mutagenesis
Synthesis and Magnetic Properties of Maghemite (γ-Fe2O3) Short-Nanotubes
We report a rational synthesis of maghemite (γ-Fe2O3) short-nanotubes (SNTs) by a convenient hydrothermal method and subsequent annealing process. The structure, shape, and magnetic properties of the SNTs were investigated. Room-temperature and low-temperature magnetic measurements show that the as-fabricated γ-Fe2O3 SNTs are ferromagnetic, and its coercivity is nonzero when the temperature above blocking temperature (TB). The hysteresis loop was operated to show that the magnetic properties of γ-Fe2O3 SNTs are strongly influenced by the morphology of the crystal. The unique magnetic behaviors were interpreted by the competition of the demagnetization energy of quasi-one-dimensional nanostructures and the magnetocrystalline anisotropy energy of particles in SNTs
HPLC-DAD and HPLC-ESI-Q-ToF characterisation of early 20th century lake and organic pigments from Lefranc archives
The characterisation of atelier materials and of the historical commercial formulation of paint materials has recently gained new interest in the field of conservation science applied to modern and contemporary art, since modern paint materials are subjected to peculiar and often unpredictable degradation and fading processes. Assessing the composition of the original materials purchased by artists can guide not only their identification in works of art, but also their restoration and conservation. Advances in characterisation methods and models for data interpretation are particularly important in studying organic coloring materials in the transition period corresponding to the late 19th-early 20th century, when many such variants or combinations were hypothetically possible in their formulations. There is thus a need for reliable databases of materials introduced in that period and for gaining chemical knowledge at a molecular level related to modern organic pigments, by state-of-the-art protocols. This paper reports on the results of a study on 44 samples of historical colorants in powder and paint tubes, containing both lake pigments and synthetic organic pigments dating from 1890 to 1926. The samples were collected at the Lefranc Archive in Le Mans (France) as a part of Project Futurahma "From Futurism to Classicism (1910-1922). Research, Art History and Material Analysis", (FIRB2012, Italian Ministry of University and Research), and were investigated using an analytical approach based on chromatographic and mass spectrometric techniques. The focus of the chemical analyses was to reveal the composition of the historical organic lake pigments including minor components, to discriminate between different recipes for the extraction of chromophore-containing molecules from the raw materials, and ultimately to distinguish between different formulations and recipes. High performance liquid chromatography (HPLC) with diode array detector (DAD) or electrospray-Quadrupole-Time of Flight tandem mass spectrometry detector (ESI-Q-ToF) were chosen given their considerable capacity to identify such complex and widespread organic materials. Although the inorganic components of the pigments were not taken into account in this survey, the specific molecular profiles provided invaluable information on the extraction procedures or synthetic strategy followed by the different producers, at different times. For instance, the use of Kopp's purpurin and garancine was highlighted, and synthetic by-products were identified. The results provided evidence that the addition of synthetic organic pigments to paint mixtures started from 1910 onwards, but they also suggest that in the formulation of high quality (surfin) colorants, natural products were still preferred. Moreover, in one of the samples the use of murexide as the colouring material was confirmed. This paper presents the first systematic and comprehensive survey on organic lakes and pigments belonging to an historical archive, by both HPLC-DAD and HPLC-ESI-Q-ToF. Specific by-products of synthetic production of pigments, which can act as specific molecular markers for dating or locating a work of art, were also identified for the first time
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