75 research outputs found
Prospects in Analytical Atomic Spectrometry
Tendencies in five main branches of atomic spectrometry (absorption,
emission, mass, fluorescence and ionization spectrometry) are considered. The
first three techniques are the most widespread and universal, with the best
sensitivity attributed to atomic mass spectrometry. In the direct elemental
analysis of solid samples, the leading roles are now conquered by laser-induced
breakdown and laser ablation mass spectrometry, and the related techniques with
transfer of the laser ablation products into inductively-coupled plasma.
Advances in design of diode lasers and optical parametric oscillators promote
developments in fluorescence and ionization spectrometry and also in absorption
techniques where uses of optical cavities for increased effective absorption
pathlength are expected to expand. Prospects for analytical instrumentation are
seen in higher productivity, portability, miniaturization, incorporation of
advanced software, automated sample preparation and transition to the
multifunctional modular architecture. Steady progress and growth in
applications of plasma- and laser-based methods are observed. An interest
towards the absolute (standardless) analysis has revived, particularly in the
emission spectrometry.Comment: Proofread copy with an added full reference list of 279 citations. A
pdf version of the final published review may be requested from Alexander
Bol'shakov <[email protected]
Visualization of temperature-induced structural rearrangements in oriented amorphous polymers
Visualization of structural rearrangements responsible for temperature-induced shrinkage of amorphous polycarbonate after its deformation at different conditions
Π‘ΡΠ°Π²Π½ΠΈΡΠ΅Π»ΡΠ½Π°Ρ Ρ Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠ° Π΅Π΄ΠΈΠ½ΠΈΡ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠΈ ΠΏΡΠΈΠΌΠ΅Π½ΠΈΡΠ΅Π»ΡΠ½ΠΎ ΠΊ ΡΡΠ°Π½Π΄Π°ΡΡΠ½ΡΠΌ ΠΎΠ±ΡΠ°Π·ΡΠ°ΠΌ Π΄Π»Ρ Π³Π°Π·ΠΎΡ ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ Π°Π½Π°Π»ΠΈΠ·Π° ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Π½ΡΡ ΠΏΡΠΎΠ±
Application of a method of absolute calibration relating to gas chromatography analysis of liquid hydrocarbon samples is considered. It is shown for this task that both from theoretical, and practical points of view the optimum concentration unit is mass (not molar) fraction. Information on average molar mass of the analyzed sample is necessary for the determination of analytes in liquid hydrocarbon samples in terms of mole fraction. Meanwhile, the normative documents of rather high rank (ASTM, ISO, GOST, GOST R) concerning methods of the determination of average molar weight of samples of such a kind are absent.Π Π°ΡΡΠΌΠΎΡΡΠ΅Π½ΠΎ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΠΌΠ΅ΡΠΎΠ΄Π° Π°Π±ΡΠΎΠ»ΡΡΠ½ΠΎΠΉ Π³ΡΠ°Π΄ΡΠΈΡΠΎΠ²ΠΊΠΈ ΠΏΡΠΈΠΌΠ΅Π½ΠΈΡΠ΅Π»ΡΠ½ΠΎ ΠΊ Π°Π½Π°Π»ΠΈΠ·Ρ ΠΆΠΈΠ΄ΠΊΠΎΠ³ΠΎ ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Π½ΠΎΠ³ΠΎ ΡΡΡΡΡ ΠΈ ΠΏΡΠΎΠ΄ΡΠΊΡΠΈΠΈ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ Π³Π°Π·ΠΎΠ²ΠΎΠΉ Ρ
ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΠΈ. ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΠΊΠ°ΠΊ Ρ ΡΠ΅ΠΎΡΠ΅ΡΠΈΡΠ΅ΡΠΊΠΎΠΉ, ΡΠ°ΠΊ ΠΈ Ρ ΠΏΡΠ°ΠΊΡΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΠΎΡΠΊΠΈ Π·ΡΠ΅Π½ΠΈΡ ΠΏΡΠΈ ΡΠ΅ΡΠ΅Π½ΠΈΠΈ Π΄Π°Π½Π½ΠΎΠΉ Π·Π°Π΄Π°ΡΠΈ ΠΎΠΏΡΠΈΠΌΠ°Π»ΡΠ½ΡΠΌΠΈ Π΅Π΄ΠΈΠ½ΠΈΡΠ°ΠΌΠΈ ΠΊΠΎΠ½ΡΠ΅Π½ΡΡΠ°ΡΠΈΠΉ ΡΠ²Π»ΡΡΡΡΡ ΠΌΠ°ΡΡΠΎΠ²ΡΠ΅ (Π° Π½Π΅ ΠΌΠΎΠ»ΡΡΠ½ΡΠ΅) Π΄ΠΎΠ»ΠΈ. ΠΠ»Ρ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ ΡΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΡ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠΎΠ² Π² ΠΆΠΈΠ΄ΠΊΠΎΠΌ ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄Π½ΠΎΠΌ ΡΡΡΡΠ΅ ΠΈ ΠΏΡΠΎΠ΄ΡΠΊΡΠΈΠΈ Π² Π΅Π΄ΠΈΠ½ΠΈΡΠ°Ρ
ΠΌΠΎΠ»ΡΡΠ½ΠΎΠΉ Π΄ΠΎΠ»ΠΈ Π½Π΅ΠΎΠ±Ρ
ΠΎΠ΄ΠΈΠΌΠ° ΠΈΠ½ΡΠΎΡΠΌΠ°ΡΠΈΡ ΠΎ ΡΡΠ΅Π΄Π½Π΅ΠΉ ΠΌΠΎΠ»ΡΡΠ½ΠΎΠΉ ΠΌΠ°ΡΡΠ΅ Π°Π½Π°Π»ΠΈΠ·ΠΈΡΡΠ΅ΠΌΠΎΠ³ΠΎ ΠΎΠ±ΡΠ°Π·ΡΠ°. ΠΠ΅ΠΆΠ΄Ρ ΡΠ΅ΠΌ Π½ΠΎΡΠΌΠ°ΡΠΈΠ²Π½ΡΠ΅ Π΄ΠΎΠΊΡΠΌΠ΅Π½ΡΡ Π΄ΠΎΡΡΠ°ΡΠΎΡΠ½ΠΎ Π²ΡΡΠΎΠΊΠΎΠ³ΠΎ ΡΠ°Π½Π³Π° (ASTM, ISO, ΠΠΠ‘Π’, ΠΠΠ‘Π’ Π ), ΡΠ΅Π³Π»Π°ΠΌΠ΅Π½ΡΠΈΡΡΡΡΠΈΠ΅ ΠΌΠ΅ΡΠΎΠ΄ΠΈΠΊΠΈ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ ΡΡΠ΅Π΄Π½Π΅ΠΉ ΠΌΠΎΠ»ΡΡΠ½ΠΎΠΉ ΠΌΠ°ΡΡΡ, ΠΎΡΡΡΡΡΡΠ²ΡΡΡ
Analogues for the solution of boundary-value problems
Analogues for the Solution of Boundary-Value Problem
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