179 research outputs found
Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands
Catalytic Chemoselective Sulfimidation with an Electrophilic [Co-<sup>III</sup>(TAML)]<sup>-</sup>-Nitrene Radical Complex**
Catalytic Chemoselective Sulfimidation with an Electrophilic [Co-<sup>III</sup>(TAML)]<sup>-</sup>-Nitrene Radical Complex**
Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis1,2,3-triazolylidene pyridine pincer complexes
Dinuclear Gold Complexes Supported by Wide Bite Angle Diphosphines for Preorganization-Induced Selective Dual-Gold Catalysis
Hydroformylation catalyst comprising a complex with ligands having a structure derived from bisphenol A
Ethylenically unsaturated compounds are hydroformylated in the presence of a hydroformylation catalyst comprising at least one complex of a metal of transition group VIII with at least one phosphorus-containing compound as ligand, where this compound contains two groups which contain P atoms and are bound to a molecular skeleton derived from bisphenol A
Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex: multiple reaction steps at a reactive ligand
Substrate activation by means of a reactive ligand is a topic of much interest. Herein we describe a stoichiometric anti-Markovnikov C-N bond formation involving ligand reactivity in multiple steps along the reaction coordinate, including ligand assisted substrate (de)protonation and C-N bond formation, as illustrated by a combined experimental, spectroscopic and computational study. This affords a highly unusual four-membered iridacycle bearing an exo-cyclic C=C double bond
Hydroformylation catalyst comprising a complex with ligands having a structure derived from bisphenol A
Ethylenically unsaturated compounds are hydroformylated in the presence of a hydroformylation catalyst comprising at least one complex of a metal of transition group VIII with at least one phosphorus-containing compound as ligand, where this compound contains two groups which contain P atoms and are bound to a molecular skeleton derived from bisphenol A
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