14 research outputs found
On the Coordination Behaviour of the hmta Toward Alkali Metal Cations in Presence of Perchlorate Anions
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Peroxidase-like catalytic activities of ionic metalloporphyrins supported on functionalised polystyrene surface
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Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex
No full textPorphyrin−Cyclodextrin Conjugates as a Nanosystem for Versatile Drug Delivery and Multimodal Cancer Therapy
No full textAn Interdigitated Metalloporphyrin Framework: Two-Dimensional Tessellation, Framework Flexibility, and Selective Guest Accommodation
No full textA novel porphyrin-based metal???organic framework (MPF-3) was synthesized by the solvothermal reaction of Zn(NO3)2??6H2O and meso-tetra(3-pyridyl)porphine in N,N-dimethylformamide (DMF). Its structure was characterized by single crystal X-ray diffraction and found to be a two-dimensional (2D) interdigitated framework in which DMF solvent molecules reside between the interdigitated layers. The observed 2D topology can be related to the Cairo pentagonal tessellation. X-ray powder diffraction reveals that MPF-3 undergoes a phase transformation when the solvent molecules are removed by heating. Surprisingly, the original topologies are restored when the desolvated phase is immersed in DMF, thereby demonstrating the flexibility of the framework
Spectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II) Porphyrins
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