Diversification and hybridization in firm knowledge bases in nanotechnologies

The paper investigates the linkages between the characteristics of technologies and the structure of a firms' knowledge base. Nanotechnologies have been defined as converging technologies that operate at the nanoscale, and which require integration to fulfill their economic promises. Based on a worldwide database of nanofirms, the paper analyses the degree of convergence and the convergence mechanisms within firms. It argues that the degree of convergence in a firm's nano-knowledge base is relatively independent from the size of the firm's nano-knowledge base. However, while firms with small nano-knowledge bases tend to exploit convergence in each of their patents/publications, firms with large nano-knowledge bases tend to separate their nano-R&D activities in the different established fields and achieve diversity through the juxtaposition of the output of these independent activities For more informations http://www.nanoeconomics.eu/

Heat Estimation from Infrared Measurement Compared to DSC for Austenite to R Phase Transformation in a NiTi Alloy

International audienceHeat sources estimations from temperature field measurements deduced from infrared imaging are increasingly used to study thermo-mechanical coupling during materials deformation. These estimations are based on approximations of the derivative terms with respect to time and space which are involved in the heat diffusion equation. This paper proposes a first experimental validation of this method by applying it to an experimental uniform air cooling of a NiTi Shape Memory Alloy thin plate. In the studied cooling temperate range, heat sources are due to Austenite to R phase transformation. Transformation temperatures, heat sources and energies are estimated from infrared temperature measurements and compared to differential scanning calorimetry results. The small 2 discrepancies are mainly explained by errors in DSC measurements due to thermal inertia and baseline determination

An original method to estimate local thermophysical properties and latent heat from Thermal Field Measurement (TFM)

International audienceThis paper presents an original method: (i) to estimate thermophysical properties (heat capacity C and thermal condictivity K) and (ii) to experimentally validate heat source estimations. The method, called Thermal Field Measurements (TFM), is based on infrared thermal observations during cooling experiments in a same experimental setup. Results obtained with this method are in good agreement with other resutls published in literature. Only the homogeneous case is presented in this paper but a 1D heterogeneous case will also be presented in the conference

Contributions à l'étude thermomécanique des alliages à mémoire de forme NiTi et à la réalisation par soudage de matériaux architecturés NiTi

Les alliages à mémoire de forme Nickel Titane sont des matériaux aux propriétés remarquablesdues à une transformation martensitique réversible et sont largement utiliséspar l industrie biomédicale et dans des dispositifs de type actionneurs. La première partiede cette étude porte sur une analyse de leur comportement thermomécanique basée surla réalisation de mesures de champs cinématiques (par corrélation d images visibles) etthermiques (par caméra infrarouge). Une part importante du travail présenté concernel amélioration des calculs de sources de chaleur à partir des champs de température. Pource faire, les capacités et conductivités thermiques des phases austénitique et martensitiqueont été estimées par différentes méthodes expérimentales. Ensuite, la méthode de calcul desource a été validée sur des données virtuelles obtenues numériquement et sur des donnéesexpérimentales obtenues lors d une transformation martensitique induite par un refroidissementnaturel. Cette première partie se conclut par l application des développements àdes mesures réalisées lors d un essai de cisaillement. La seconde partie est une contributionà la réalisation de matériaux architecturés constitués d empilement de tubes de NiTi liésentre eux ; notre étude concerne la réalisation et la caractérisation de liaisons de tubes deNiTi par soudage résistif.NiTi shape memory alloys have amazing properties due to a reversible martensitictransformation and are widely used by biomedical industries and as actuators. The firstpart of this study deals is a thermomechanical analysis of the material, based on kinematical(with digital image correlation) and thermal (with infrared camera) field measurements.An important part of this work deals with the improvement of the heat sources estimationfrom thermal fields. For this, thermal heat capacities and conductivities of austeniteand martensite were estimated with several experimental methods. Then, the heat sourceestimation method was validated from virtual data obtained numerically and from experimentaldata obtained during a martensitic transformation induced by natural cooling.This first part is concluded with the use of this technique to study shear tests. The secondpart of this study is a contribution to the realization of architectured materials composedof linked stacked tubes. Our study deals with the realization and the characterization ofthe NiTi link, realized by resistance welding.SAVOIE-SCD - Bib.électronique (730659901) / SudocGRENOBLE1/INP-Bib.électronique (384210012) / SudocGRENOBLE2/3-Bib.électronique (384219901) / SudocSudocFranceF

EXPERIMENTAL AND NUMERICAL STUDY OF NITI HOLEY PLATES LOADED IN TENSION

International audienceWe present results of experiments and numerical modeling of superelastic deformation of NiTi holey plates

One-year measurements of surface heat budget on the ablation zone of Antizana Glacier 15, Ecuadorian Andes

International audience[1] Meteorological variables were recorded (14 March 2002 to 14 March 2003) at 4890 m above sea level (asl) on the Antizana Glacier 15 (0.71 km 2 ; 0°28 0 S, 78°09 0 W) in the tropical Andes of Ecuador (inner tropics). These variables were used to compute the annual cycle of the local surface energy balance (SEB). The four radiative fluxes were directly measured, and the turbulent fluxes were calculated using the bulk aerodynamic approach, calibrating the roughness length by direct sublimation measurements. The meteorological conditions are relatively homogeneous throughout the year (air temperature and air humidity). There is a slight seasonality in precipitation with a more humid period between February and June. During June-September, wind velocity shows high values and is responsible for intense turbulent fluxes that cause reduction of melting. Considering the SEB over the whole year, it is dominated by net radiation, and albedo variations govern melting. During the period under consideration the net shortwave radiation S (123 W m À2) and the sensible turbulent heat flux H (21 W m À2) were energy sources at the glacier surface, whereas the net long-wave radiation L (À39 W m À2) and the latent turbulent heat flux LE (À27 W m À2) represented heat sinks. Since the O°C isotherm-glacier intersection always oscillates through the ablation zone and considering that the phase of precipitation depends on temperature, temperature indirectly controls the albedo values and thus the melting rates. This control is of major interest in understanding glacier response to climate change in the Ecuadorian Andes, which is related to global warming and ENSO variability

Validation expérimentale d'estimations de sources de chaleur-cas uniforme

Les couplages thermomécaniques sont étudiés depuis plusieurs années en estimant les sources de chaleur à partir de mesures de champs de températures obtenus par imagerie InfraRouge. Ces estimations sont basées sur l'approximation des dérivées temporelle et spatiales impliquées dans l'équation de la chaleur. Les travaux présentés concernent la validation expérimentale de l'estimation grâce à des mesures de refroidissement ou réchauffement naturel impliquant des transformations de phase. Les mesures sont faites sur un AMF NiTi, sur lequel les chaleurs latentes sont pré- estimées par DSC

Comparison of LASTIC (Light Aspiration device for in vivo Soft TIssue Characterization) with classic Tensile Tests.

International audienceLASTIC is a device estimating in vivo soft tissue elasticity. It uses negative pressure to deform the tissue surface and captures several deformation stages to trace the behavioral curve. Using Finite Element inverse analysis and a Neo Hookean constitutive law, the tissue's Young modulus is evaluated. This paper compares LASTIC capabilities with standard tensile tests on four samples with elastic properties ranging from 10 kPa to 100 kPa. Although LASTIC overestimates Young modulus by an average of 24 %, it allows a first estimation of the elastic modulus of different materials

Microsecond time-resolved X-ray diffraction for the investigation of fatigue behavior during ultrasonic fatigue loading

International audienceA new method based on time-resolved X-ray diffraction is proposed in order to measure the elastic strain and stress during ultrasonic fatigue loading experiments. Pure Cu was chosen as an example material for the experiments using a 20 kHz ultrasonic fatigue machine mounted on the six-circle diffractometer available at the DiffAbs beamline on the SOLEIL synchrotron facility in France. A two-dimensional hybrid pixel X-ray detector (XPAD3.2) was triggered by the strain gage signal in a synchronous data acquisition scheme (pump–probe-like). The method enables studying loading cycles with a period of 50 µs, achieving a temporal resolution of 1 µs. This allows a precise reconstruction of the diffraction patterns during the loading cycles. From the diffraction patterns, the position of the peaks, their shifts and their respective broadening can be deduced. The diffraction peak shift allows the elastic lattice strain to be estimated with a resolution of ∼10−5. Stress is calculated by the self-consistent scale-transition model through which the elastic response of the material is estimated. The amplitudes of the cyclic stresses range from 40 to 120 MPa and vary linearly with respect to the displacement applied by the ultrasonic machine. Moreover, the experimental results highlight an increase of the diffraction peak broadening with the number of applied cycles