7,677 research outputs found
Signatures of fractal clustering of aerosols advected under gravity
Aerosols under chaotic advection often approach a strange attractor. They
move chaotically on this fractal set but, in the presence of gravity, they have
a net vertical motion downwards. In practical situations, observational data
may be available only at a given level, for example at the ground level. We
uncover two fractal signatures of chaotic advection of aerosols under the
action of gravity. Each one enables the computation of the fractal dimension
of the strange attractor governing the advection dynamics from data
obtained solely at a given level. We illustrate our theoretical findings with a
numerical experiment and discuss their possible relevance to meteorology.Comment: Accepted for publication in Phys. Rev. E (Rapid Communications
Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles
© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k
Geometry, stochastic calculus and quantum fields in a non-commutative space-time
The algebras of non-relativistic and of classical mechanics are unstable
algebraic structures. Their deformation towards stable structures leads,
respectively, to relativity and to quantum mechanics. Likewise, the combined
relativistic quantum mechanics algebra is also unstable. Its stabilization
requires the non-commutativity of the space-time coordinates and the existence
of a fundamental length constant. The new relativistic quantum mechanics
algebra has important consequences on the geometry of space-time, on quantum
stochastic calculus and on the construction of quantum fields. Some of these
effects are studied in this paper.Comment: 36 pages Latex, 1 eps figur
Evolução do número de pessoas ocupadas na agropecuária brasileira no período de 1990 a 2004.
O mercado de trabalho rural eliminou muitos postos de trabalho nos últimos 14 anos, principalmente em razão da ampliação do uso de tecnologia pelo setor. No caso do Brasil, o aumento das exportações e o crescimento da produção destinada ao mercado interno contribuíram positivamente para a geração de novos empregos, mas tais fatores foram insuficientes para compensar as vagas fechadas pela mudança tecnológica e pelas importações de produtos agrícolas. Na agropecuária, as importações tiveram impacto relativamente pequeno (235,7 mil postos de trabalho eliminados), apesar de terem afetado fortemente o emprego em alguns setores, tais como os do trigo, do arroz e do leite. Já o aumento das exportações, esse foi responsável por 30,2% do total de empregos gerados pelo setor, com o restante (69,8%) ficando a cargo do crescimento promovido pela demanda doméstica. Embora o processo de ajuste no mercado de trabalho da agropecuária nacional tenha, em decorrência da variável “mudança tecnológica”, aprofundado-se nos últimos anos, ainda assim o número de pessoas ocupadas no setor vem crescendo desde 2002, o que reforça a hipótese de que o aumento nas vendas internas e, sobretudo, das externas, gerou mais postos de trabalho que os eliminados pela adoção de novas tecnologias
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